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The achievement of global climate targets outlined in the Paris Agreement represents a critical challenge in the coming decades. Certain industry sectors cannot completely avoid all emissions from their processes. In this context, the term unavoidable or Hard-to-abate emissions is used. Carbon Capture and Utilization (CCU) and Carbon Capture and Storage (CCS) are recognized as essential components for addressing those emissions to achieve Net Zero Emissions. To identify effective Carbon Management Strategies, balancing future CO2 sources and possible sinks for achieving long-term climate targets is essential. Especially in Austria hardly any comprehensive studies have been carried out. This work presents a comprehensive analysis of Austria’s CO2 point sources as well as their projected development until 2050 based on technology-based scenarios. Geological CO2 storage in Austria is primarily feasible in former hydrocarbon reservoirs and saline aquifers. Future demands for CO2 as CCU feedstock will arise in the chemical industry. By 2050, industry will emit approximately 4 Mt of unavoidable CO2 annually. These emissions must be stored in the long term and correspond to the minimum demand for CCS. Fugitive emissions from agriculture, for example, cannot be captured. Thus, they are not subject of CCU/S measures. Negative emissions are therefore necessary to achieve the climate targets. These negative emissions and the possible use of CO2 as feedstock are covered by biogenic CO2.

Due to the increase of carbon dioxide emissions, a target for their reduction has been defined in the Paris Agreement for 2030. This topic is extremely important, and urgent actions are required so that the attention of the scientific community is mainly focused on emission reduction. In this context, carbon supply chains have an important role because they can help in carbon dioxide mitigation. In fact, in these systems, carbon dioxide is captured to be stored or used to produce valuable products. However, carbon supply chains involve many energy consumptions during the operation (causing carbon dioxide emissions and resource depletion), and an analysis of the environmental impact of the system is required. Different green metrics exist but the most effective is the life cycle assessment. The methodology of the life cycle assessment is presented in this work, with particular considerations for its application to carbon supply chains. An overview of the research presented in the literature is also considered here, with suggestions for future analyses.

Chemical production is set to become the single largest driver of global oil consumption by 2030. To reduce oil consumption and resulting greenhouse gas (GHG) emissions, carbon dioxide can be captured from stacks or air and utilized as alternative carbon source for chemicals. Here, we show that carbon capture and utilization (CCU) has the technical potential to decouple chemical production from fossil resources, reducing annual GHG emissions by up to 3.5 Gt CO₂-eq in 2030. Exploiting this potential, however, requires more than 18.1 PWh of low-carbon electricity, corresponding to 55% of the projected global electricity production in 2030. Most large-scale CCU technologies are found to be less efficient in reducing GHG emissions per unit low-carbon electricity when benchmarked to power-to-X efficiencies reported for other large-scale applications including electro-mobility (e-mobility) and heat pumps. Once and where these other demands are satisfied, CCU in the chemical industry could efficiently contribute to climate change mitigation.

Lately, the technical research on carbon dioxide capture and utilization (CCU) has achieved important breakthroughs. While single CO 2 -based innovations are entering the markets, the possible economic effects of a large-scale CO 2 utilization still remain unclear to policy makers and the public. Hence, this paper reviews the literature on CCU and provides insights on the motivations and potential of making use of recovered CO 2 emissions as a commodity in the industrial production of materials and fuels. By analyzing data on current global CO 2 supply from industrial sources, best practice benchmark capture costs and the demand potential of CO 2 utilization and storage scenarios with comparative statics, conclusions can be drawn on the role of different CO 2 sources. For near-term scenarios the demand for the commodity CO 2 can be covered from industrial processes, that emit CO 2 at a high purity and low benchmark capture cost of approximately 33 €/t. In the long-term, with synthetic fuel production and large-scale CO 2 utilization, CO 2 is likely to be available from a variety of processes at benchmark costs of approx. 65 €/t. Even if fossil-fired power generation is phased out, the CO 2 emissions of current industrial processes would suffice for ambitious CCU demand scenarios. At current economic conditions, the business case for CO 2 utilization is technology specific and depends on whether efficiency gains or substitution of volatile priced raw materials can be achieved. Overall, it is argued that CCU should be advanced complementary to mitigation technologies and can unfold its potential in creating local circular economy solutions.

The increasing trend in global energy demand has led to an extensive use of fossil fuels and subsequently in a marked increase in atmospheric CO2 content, which is the main culprit for the greenhouse effect. In order to successfully reverse this trend, many schemes for CO2 mitigation have been proposed, taking into consideration that large-scale decarbonization is still infeasible. At the same time, the projected increase in the share of variable renewables in the future energy mix will necessitate large-scale curtailment of excess energy. Collectively, the above crucial problems can be addressed by the general scheme of CO2 hydrogenation. This refers to the conversion of both captured CO2 and green H2 produced by RES-powered water electrolysis for the production of added-value chemicals and fuels, which are a great alternative to CO2 sequestration and the use of green H2 as a standalone fuel. Indeed, direct utilization of both CO2 and H2 via CO2 hydrogenation offers, on the one hand, the advantage of CO2 valorization instead of its permanent storage, and the direct transformation of otherwise curtailed excess electricity to stable and reliable carriers such as methane and methanol on the other, thereby bypassing the inherent complexities associated with the transformation towards a H2-based economy. In light of the above, herein an overview of the two main CO2 abatement schemes, Carbon Capture and Storage (CCS) and Carbon Capture and Utilization (CCU), is firstly presented, focusing on the route of CO2 hydrogenation by green electrolytic hydrogen. Next, the integration of large-scale RES-based H2 production with CO2 capture units on-site industrial point sources for the production of added-value chemicals and energy carriers is contextualized and highlighted. In this regard, a specific reference is made to the so-called Power-to-X schemes, exemplified by the production of synthetic natural gas via the Power-to-Gas route. Lastly, several outlooks towards the future of CO2 hydrogenation are presented.

Corporate image, European Emission Trading System and Environmental Regulations, encourage pulp industry to reduce carbon dioxide (CO2) emissions. Kraft pulp mills produce CO2 mainly in combustion processes. The largest sources are the recovery boiler, the biomass boiler, and the lime kiln. Due to utilizing mostly biomass-based fuels, the CO2 is largely biogenic. Capture and storage of CO2 (CCS) could offer pulp and paper industry the possibility to act as site for negative CO2 emissions. In addition, captured biogenic CO2 can be used as a raw material for bioproducts. Possibilities for CO2 utilization include tall oil manufacturing, lignin extraction, and production of precipitated calcium carbonate (PCC), depending on local conditions and mill-specific details. In this study, total biomass-based CO2 capture and storage potential (BECCS) and potential to implement capture and utilization of biomass-based CO2 (BECCU) in kraft pulp mills were estimated by analyzing the impacts of the processes on the operation of two modern reference mills, a Nordic softwood kraft pulp mill with integrated paper production and a Southern eucalyptus kraft pulp mill. CO2 capture is energy-intensive, and thus the effects on the energy balances of the mills were estimated. When papermaking is integrated in the mill operations, energy adequacy can be a limiting factor for carbon capture implementation. Global carbon capture potential was estimated based on pulp production data. Kraft pulp mills have notable CO2 capture potential, while the on-site utilization potential using currently available technologies is lower. The future of these processes depends on technology development, desire to reuse CO2, and prospective changes in legislation.

Currently, a progressively different approach to the generation of power and the production of fuels for the automotive sector as well as for domestic applications is being taken. As a result, research on the feasibility of applying renewable energy sources to the present energy scenario has been progressively growing, aiming to reduce greenhouse gas emissions. Following more than one approach, the integration of renewables mainly involves the utilization of biomass-derived raw material and the combination of power generated via clean sources with conventional power generation systems. The aim of this review article is to provide a satisfactory overview of the most recent progress in the catalysis of hydrogen production through sustainable reforming and CO2 utilization. In particular, attention is focused on the route that, starting from bioethanol reforming for H2 production, leads to the use of the produced CO2 for different purposes and by means of different catalytic processes, passing through the water–gas shift stage. The newest approaches reported in the literature are reviewed, showing that it is possible to successfully produce “green” and sustainable hydrogen, which can represent a power storage technology, and its utilization is a strategy for the integration of renewables into the power generation scenario. Moreover, this hydrogen may be used for CO2 catalytic conversion to hydrocarbons, thus giving CO2 added value.

As the unique source of carbon in the atmosphere, carbon dioxide (CO 2 ) exerts a strong impact on crop yield and quality. However, CO 2 deficiency in greenhouses during the daytime often limits crop productivity. Crucially, climate warming, caused by increased atmospheric CO 2 , urges global efforts to implement carbon reduction and neutrality, which also bring challenges to current CO 2 enrichment systems applied in greenhouses. Thus, there is a timely need to develop cost-effective and environmentally friendly CO 2 enrichment technologies as a sustainable approach to promoting agricultural production and alleviating environmental burdens simultaneously. Here we review several common technologies of CO 2 enrichment in greenhouse production, and their characteristics and limitations. Some control strategies of CO 2 enrichment in distribution, period, and concentration are also discussed. We further introduce promising directions for future CO 2 enrichment including 1) agro-industrial symbiosis system (AIS); 2) interdisciplinary application of carbon capture and utilization (CCU); and 3) optimization of CO 2 assimilation in C 3 crops via biotechnologies. This review aims to provide perspectives on efficient CO 2 utilization in greenhouse production.

Achieving net-zero emissions by 2050 will require tackling both energy-related and non-energy-related GHG emissions, which can be achieved through the transition to a circular economy (CE). The focus of climate change crisis reversal has been on the energy-related continuum over the years through promoting renewable energy uptake and efficiency in energy use. Clean energy transition and efficiency gains in energy use alone will not be sufficient to achieve net-zero emissions in 2050 without paying attention to non-energy-related CO2 emissions. This study systematically reviews the CE literature across different themes, sectors, approaches, and tools to identify accelerators in transitioning to a CE. The study aims to understand and explore how technology, finance, ecosystem, and behavioral studies in the CE paradigm can be integrated as a decision-making tool for CE transition. The material analysis was carried out by identifying the main characteristics of the literature on CE implementation in the agriculture, industry, energy, water, and tourism sectors. Results of the literature survey are synthesized to engender clarity in the literature and identify research gaps to inform future research. Findings show that many studies focused on technology as an accelerator for CE transition, and more studies are needed regarding the CE ecosystem, financing, and behavioral aspects. Also, results show that CE principles are applied at the micro-, meso-, and macro- (national, regional, and global) levels across sectors with the dominance of the industrial sector. The agriculture, water, and energy sectors are at the initial stages of implementation. Additionally, the use of carbon capture and utilization or storage, conceptualized as a circular carbon economy, needs attention in tackling CE implementation in the energy sector, especially in hydrocarbon-endowed economies. The major implication of these findings is that for CE to contribute to accelerated net-zero emission by 2050, coordinated policies should be promoted to influence the amount of financing available to innovative circular businesses and technologies within an ecosystem that engenders behavioral change towards circularity.

This study investigates a novel method of utilizing Direct Air Capture (DAC) technology for fertilizer production. Unlike traditional Direct Air Carbon Capture and Utilization (DACCU) technologies, Direct Air Carbon Capture for Fertilizers (FDAC) has the potential to produce fertilizers directly. This study aims to assess the feasibility of FDAC-based fertilizer production by examining the current state of traditional DAC technologies, evaluating the CO2 fixation potential of FDAC, and analyzing the decarbonization effect of producing fertilizers using FDAC. Our evaluation results indicate that CO2 emissions from producing 1 ton of conventional chemical fertilizer, FDAC fertilizer (current status), FDAC fertilizer with ingredient adjustment (sodium hydroxide), and FDAC fertilizer with ingredient adjustment (magnesium hydroxide) are 1.69, 1.12, 1.04, and 1.06 tons of CO2, respectively. The FDAC fertilizer (current status) emits 0.57 tons of CO2 per ton less than commercial fertilizers. FDAC fertilizers also have the potential to reduce CO2 emissions further when the fertilizer composition is adjusted, offering a promising solution for lowering the environmental impact of fertilizer production. Significant CO2 reduction can be expected by replacing conventional low-intensity chemical fertilizers with FDAC-produced fertilizers.