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Smart cement : development, testing, modeling and real-time monitoring
\"Smart cement is a chemo-thermo-piezoresistive material that functions as a highly sensing 3-dimensional bulk sensor. It can be used for monitoring changes oflectrical resistivity in concrete by the addition of 0.03% of selected conductive or semi-conductive fibers are added to the bulk cement\"-- Provided by publisher.
BOOK
Lea's chemistry of cement and concrete
Lea's Chemistry of Cement and Concrete deals with the chemical and physical properties of cements and concretes and their relation to the practical problems that arise in manufacture and use. As such it is addressed not only to the chemist and those concerned with the science and technology of silicate materials, but also to those interested in the use of concrete in building and civil engineering construction. Much attention is given to the suitability of materials, to the conditions under which concrete can excel and those where it may deteriorate and to the precautionary or remedial measures that can be adopted.First published in 1935, this is the fourth edition and the first to appear since the death of Sir Frederick Lea, the original author. Over the life of the first three editions, this book has become the authority on its subject. The fourth edition is edited by Professor Peter C. Hewlett, Director of the British Board of Agrement and visiting Industrial Professor in the Department of Civil Engineering at the University of Dundee. Professor Hewlett has brought together a distinguished body of international contributors to produce an edition which is a worthy successor to the previous editions.
eBook
Eco-Efficient Cement-Based Materials Using Biomass Bottom Ash: A Review
In recent years the use of biomass for electricity generation in thermal and cogeneration plants has increased worldwide because it is an environmentally clean fuel whose impact measured in greenhouse gas emissions is practically zero. However, biomass bottom ash, a waste produced during combustion, has also increased considerably, which has both a negative economic and environmental impact, due to landfill transport and management of this by-product. Although biomass bottom ash has potential characteristics for application in the manufacture of construction materials, its full-scale application is difficult because of the wide range in physicochemical properties, depending on the type of biomass burned, such as wood residue, olive waste, waste paper sludge, cocoa shell, etc., and the type of combustion process in the plant. This study reviews the influence on the physicochemical properties, mechanical behavior, and durability of different cement-based materials, such as mortars, concrete, and cement-treated granular material, manufactured from biomass bottom ash. The previous studies demonstrate the feasibility of substituting natural materials for biomass bottom ash in cement-based materials, presenting adequate mechanical behavior and durability properties to comply with the required technical specifications in different building materials.
Journal Article
Application of Carrier Materials in Self-Healing Cement-Based Materials Based on Microbial-Induced Mineralization
Microbially induced calcium carbonate precipitation (MICP) technology has attracted widespread research attention owing to its application in crack healing for cement-based materials in an intelligent and environmentally friendly manner. However, the high internal alkalinity, low nutrient content, and dense structure of cement-based materials have restricted its application in self-healing cement-based materials. Various carrier materials have been widely used for the immobilization of microorganisms in recent years. Carrier materials have significantly increased the ability of microorganisms to withstand extreme conditions (high temperature, high alkali, etc.) and have provided new ideas for the compatibility of microorganisms with cement-based materials. In this study, the basic principles of microbial self-healing technology in cement-based materials and microbial immobilization methods and the influencing factors are introduced, followed by a review of the research progress and application effects of different types of carrier materials, such as aggregate, low-alkali cementitious materials, organic materials, and microcapsules. Finally, the current problems and promising development directions of microbial carrier materials are summarized to provide useful references for the future development of microbial carriers and self-healing cement-based materials.
Journal Article
Mechanical Properties of Cement-Based Materials and Effect of Elevated Temperature on Three-Dimensional (3-D) Printed Mortar Specimens in Inkjet 3-D Printing
Three-dimensional (3-D) printers have the potential to print samples that can be used as a scaffold for a variety of applications in different industries. In this paper, cement-based materials including ordinary portland cement, calcium aluminate cement (passing 150 /[micro]m [0.0059 in.] size sieve), and fine sand were investigated as the cement-based materials in inkjet 3-D printing. Prism specimens were printed for the three-point bending test; and cubic specimens were printed for the uniaxial compressive strength test. Prism samples were printed along different directional axes (X, Y, and Z). The tests were conducted at different saturation levels (water-cement ratio [w/c]) as represented by S100C200, S125C250, S150C300, and S170C340. The prism specimens were cured in water for 7 and 28 days while cubic specimens were cured in Ca[(OH).sub.2] and water for 7 and 28 days at the same ambient temperatures. In general, the results changed according to the directional axes of the prisms. However, following water curing, the cubic samples were heated up to 40[degrees]C (104[degrees]F) in an oven and a higher compressive strength was evident compared to the samples which were only cured in the room-temperature water. The wettability test for both powders has been conducted in the presented study. Keywords: cement-based materials; mechanical properties; three-dimensional (3-D) printing; variable temperature and direction (X, Y, Z).
Journal Article
Cements based on kaolinite waste
The cement industry involves high-energy consumption that generates high CO2 emissions into the atmosphere. Environmental concerns can be addressed by replacing parts of Portland cement clinkers with pozzolanic materials in mortars and concrete. Slag, fly ash and silica fume are materials considered for the planned replacement. Research studies on clay minerals, such as kaolinite, are being followed with special attention by the scientific community and the cement industry. It is well known that these minerals require an activation process to transform kaolinite (K) into metakaolinite (MK). MK is an amorphous material from the transformation of K with high pozzolanic activity, which is its capacity to react with the portlandite released during the hydration of Portland cement, generating compounds such as C–S–H gels and some aluminum-phase hydrates. One of the MK production methods is heat treatment controlled by kaolinite at temperatures in the range of 600–900 ∘C. Different residues have been used (coal mining, paper sludge and waste from a drinking water treatment plant) activated at 600 ∘C for 2 h to elaborate blended cements. Due to their good behaviour as future eco-efficient additions, this research is a study by x-ray fluorescence (XRF), x-ray diffraction (XRD) and scanning electron microscopy (SEM) of their influence on the performances of blended cement mixtures (binary and ternary one), with substitutions of pozzolan ratio at 28 days of hydration. The porosity of pozzolanic cements decreases because of the formation of hydrated phases during pozzolanic reaction.
Journal Article
Flexural Strength Prediction Models for Soil–Cement from Unconfined Compressive Strength at Seven Days
Soil–cement is an environmentally friendly road construction technique for base and subbase materials, which allows employing soils placed in the right-of-way of the road or in the surroundings, by improving its engineering properties. With this technique, it is possible to reduce the over-exploitation of quarries, the necessity of landfills and the pollutant gas emission due to the reduction of aggregate fabrication and transport. The manufacturing of soil–cement is generally controlled by means of the Uniaxial Compressive Strength (UCS) test at seven days, according to the regulations of each country. Nonetheless, one of the properties that best defines the performance of soil–cement is the Flexural Strength (FS) at long term, usually at 90 days. The aim of this paper is to develop new equations to correlate the UCS and the FS at long term and the UCS at seven days and at 90 days. Obtained results validate the proposed models and, hence, the flexural strength can be predicted from the Uniaxial Compressive Strength at seven days, allowing, if necessary, correcting measures (recalculation or rejection) in early stages of the curing time to be taken.
Journal Article
Strategies for Developing Superhydrophobic Surfaces on Cement‐Based Materials Using Stearic Acid: A Review
This paper provides a comprehensive review of recent advancements in the use of stearic acid to develop superhydrophobic surfaces on cement‐based materials. Stearic acid is a widely used hydrophobic agent owing to its low cost, simple preparation, and broad applicability. The mechanism of stearic acid hydrophobic modification and its impact on material strength are systematically analyzed. The paper critically examines advanced strategies for constructing superhydrophobic concrete using stearic acid, particularly through external coating and internal mixing. The advantages and limitations of each approach are summarized. Stearic acid disrupts the hydration of cement‐based materials, potentially reducing their strength. The surface hydrophobic modification method faces the challenge of layer detachment. Finally, the challenges and future potential of applying stearic acid in superhydrophobic cement‐based materials are explored. The paper critically examines advanced strategies for constructing superhydrophobic concrete using stearic acid, particularly through external coating and internal mixing. The advantages and limitations of both approaches are summarized.
Journal Article
Influence of cementation level on the strength behaviour of bio-cemented sand
Microbially induced calcite precipitation (MICP) is used increasingly to improve the engineering properties of granular soils that are unsuitable for construction. This shows MICP technique significant advantages such as low energy consumption and environmentally friendly feature. The objective of the present study is to assess the strength behaviour of bio-cemented sand with varying cementation levels, and to provide an insight into the mechanism of MICP treatment. A series of isotropic consolidated undrained compression tests, calcite mass measurement and scanning electron microscopy tests were conducted. The experimental results show that the strength of bio-cemented sand depends heavily on the cementation level (or calcite content). The variations of strength parameters, i.e. effective friction angle
φ
′ and effective cohesion
c
′, with the increase in calcite content can be well evaluated by a linear function and an exponential function, respectively. Based on the precipitation mechanism of calcite crystals, bio-clogging and bio-cementation of calcite crystals are correlated to the amount of total calcite crystals and effective calcite crystals, respectively, and contributed to the improvement in the effective friction angle and effective cohesion of bio-cemented sand, separately.
Journal Article
Mechanical characteristics and deformation control of surrounding rock in weakly cemented siltstone
The roof of coal seams are mostly soft rock with weak cementation. To further study the mechanical characteristics and deformation control scheme of the roadway with weakly cemented siltstone as roof, this paper took Linchang coal mine as the research background and adopted field investigation methods, laboratory experiments, and theoretical analysis. Using a scanning electron microscope, it is found that the weakly cemented siltstone is composed of coarse-grained minerals with a high degree of pore development. According to the analysis, the instability factors of weakly cemented siltstone roadway include the late diagenetic age of rock, the low mechanical strength of rock, and the change of surrounding rock properties by pouring water. The selection of grouting reinforcement materials was studied in detail. The test results show that cement-bonded specimens’ strength is lower than that of Marithan polyurethane cement specimens in general. The combined support scheme based on grouting reinforcement is put forward. Field monitoring data show that the designed support scheme can effectively control the surrounding rock deformation of weakly cemented siltstone roadway.
Journal Article