Explore the vast range of titles available.

The interaction between soil organic carbon (SOC) and clay minerals is a critical mechanism for retaining SOC and protecting soil fertility and long-term agricultural sustainability. The SOC composition and minerals speciation in clay fractions (<2 μm) within soil aggregates under straw removed (T) and straw incorporation (TS) conditions were analyzed by X-ray diffraction, Fourier transform infrared spectra and X-ray photoelectron spectroscopy. The TS treatment promoted enrichment of clay in aggregates. The TS increased the contents of SOC (27.0–86.6%), poorly crystalline Fe oxide (Feo), and activity of Fe oxides (Feo/Fed); whereas, it reduced the concentrations of free Fe oxide (Fed) in the clay fractions within aggregates. Straw incorporation promoted the accumulation of aromatic-C and carboxylic-C in the clay fraction within aggregates. The relative amount of hydroxy-interlayered vermiculite, aliphatic-C, and alcohol-C in the clay fractions within the macroaggregates was higher than that microaggregates, whereas the relative amounts of illite, kaolinite, Fe(III), and aromatic-C had a reverse tendency. The hydroxy-interlayered vermiculite in clay fractions showed positive correlation with the amounts of C–C(H) (r = 0.93) and C–O (r = 0.96 *, p < 0.05). The concentration of Feo and Feo/Fed ratio was positively correlated with the amounts of C=C and C(O)O content in clay within aggregates. Long-term straw incorporation induced transformation of clay minerals and Fe oxide, which was selectively stabilized straw-derived organic compounds in clay fractions within soil aggregates.

This study investigated the effects of surface functional groups, cation exchange capacity (CEC), surface charge, sesquioxides and specific surface area (SSA) of three soil clay fractions (SCFs) (kaolinite–illite, smectite and allophane) on the retention of dissolved organic carbon (DOC) in soils. Physico-chemical properties of the SCFs before and after removing native carbon and/or sesquioxides were characterised, and the DOC adsorption–desorption tests were conducted by a batch method. Native organic carbon (OC)/sesquioxide removal treatments led to a small change in the CEC values of kaolinite–illite, but significant changes in those of smectite and allophane. The net negative surface charge increased in all samples with an increase in pH indicating their variable charge characteristics. The removal of native OC resulted in a slight increase in the net positive charge on soil clay surfaces, while sesquioxide removal increased the negative charge. Changes in the functional groups on the SCF surfaces contributed to the changes in CEC and zeta potential values. There was a strong relationship ( R 2  = 0.93, p  < 0.05) between the Langmuir maximum DOC adsorption capacity ( Q max ) and SSA. The Q max value also showed a moderately strong relationship ( R 2  = 0.55, p  < 0.05) with zeta potential (at pH 7). Q max was only poorly correlated with CEC and native OC content. Therefore, along with SSA, the surface charge and functional groups of SCFs played the key role in determining the adsorption affinity and hence retention of DOC in soils.

Correlations between organic carbon (OC) and fine mineral particles corroborate the important role of the abundance of soil minerals with reactive surfaces to bind and increase the persistence of organic matter (OM). The storage of OM broadly consists of particulate and mineral-associated forms. Correlative studies on the impact of fine mineral soil particles on OM storage mostly combined data from differing sites potentially confounded by other environmental factors. Here, we analyzed OM storage in a soil clay content gradient of 5–37% with similar farm management and mineral composition. Throughout the clay gradient, soils contained 14 mg OC g⁻¹ on average in the bulk soil without showing any systematic increase. Density fractionation revealed that a greater proportion of OC was stored as occluded particulate OM in the high clay soils (18–37% clay). In low clay soils (5–18% clay), the fine mineral-associated fractions had up to two times higher OC contents than high clay soils. Specific surface area measurements revealed that more mineral-associated OM was related to higher OC loading. This suggests that there is a potentially thicker accrual of more OM at the same mineral surface area within fine fractions of the low clay soils. With increasing clay content, OM storage forms contained more particulate OC and mineral-associated OC with a lower surface loading. This implies that fine mineral-associated OC storage in the studied agricultural soils was driven by thicker accrual of OM and decoupled from clay content limitations.

Improved quantification of the factors controlling soil organic matter (SOM) stabilization at continental to global scales is needed to inform projections of the largest actively cycling terrestrial carbon pool on Earth, and its response to environmental change. Biogeochemical models rely almost exclusively on clay content to modify rates of SOM turnover and fluxes of climate-active CO₂ to the atmosphere. Emerging conceptual understanding, however, suggests other soil physicochemical properties may predict SOM stabilization better than clay content. We addressed this discrepancy by synthesizing data from over 5,500 soil profiles spanning continental scale environmental gradients. Here, we demonstrate that other physicochemical parameters are much stronger predictors of SOM content, with clay content having relatively little explanatory power. We show that exchangeable calcium strongly predicted SOM content in water-limited, alkaline soils, whereas with increasing moisture availability and acidity, iron- and aluminum-oxyhydroxides emerged as better predictors, demonstrating that the relative importance of SOM stabilization mechanisms scales with climate and acidity. These results highlight the urgent need to modify biogeochemical models to better reflect the role of soil physicochemical properties in SOM cycling.

Increasing the quantity and quality of plant biomass production in space and time can improve the capacity of agroecosystems to capture and store atmospheric carbon (C) in the soil. Cover cropping is a key practice to increase system net primary productivity (NPP) and increase the quantity of high-quality plant residues available for integration into soil organic matter (SOM). Cover crop management and local environmental conditions, however, influence the magnitude of soil C stock change. Here, we used a comprehensive meta-analysis approach to quantify the effect of cover crops on soil C stocks from the 0–30 cm soil depth in temperate climates and to identify key management and ecological factors that impact variation in this response. A total of 40 publications with 181 observations were included in the meta-analysis representing six countries across three different continents. Overall, cover crops had a strong positive effect on soil C stocks (P < 0.0001) leading to a 12% increase, averaging 1.11 Mg C/ha more soil C relative to a no cover crop control. The strongest predictors of SOC response to cover cropping were planting and termination date (i.e., growing window), annual cover crop biomass production, and soil clay content. Cover crops planted as continuous cover or autumn planted and terminated led to 20–30% greater total soil C stocks relative to other cover crop growing windows. Likewise, high annual cover crop biomass production (>7 Mg·ha−1·yr−1) resulted in 30% higher total soil C stocks than lower levels of biomass production. Managing for greater NPP by improving synchronization in cover crop growing windows and climate will enhance the capacity of this practice to drawdown carbon dioxide (CO₂) from the atmosphere across agroecosystems. The integration of growing window (potentially as a proxy for biomass growth), climate, and soil factors in decision-support tools are relevant for improving the quantification of soil C stock change under cover crops, particularly with the expansion of terrestrial soil C markets.

There is a growing need for spatially continuous and quantitative soil information for environmental modeling and management, especially at the national scale. This study was aimed at predicting soil particle‐size fractions (PSF) for Nigeria using random forest model (RFM). Equal‐area quadratic splines were fitted to Nigerian legacy soil profile data to estimate PSFs at six standard soil depths (0–5, 5–15, 15–30, 30–60, 60–100, and 100–200 cm) using the GlobalSoilMap project specification. We applied an additive log‐ratio (ALR) transformation of the PSFs. There was a better prediction performance (based on 33% model validation) in the upper depth intervals than the lower depth intervals (e.g., R2 of 0.53; RMSE of 13.59 g kg−1 for clay at 0–5 cm and R2 of 0.16; RMSE of 15.60 g kg−1 at 100–200 cm). Overall, the PSFs show marked variations across the entire Nigeria region with a higher sand content compared with silt and clay contents and increasing clay content with soil depth. The variation in soil texture (ST) shows a progressive transition from a coarse texture (sand) along the fringes of northern Nigeria (e.g., upper part of Maiduguri and Sokoto), to finer texture (loam to clay loam) toward the western part of the Niger Delta region in the south. The inclusion of depth as a predictor variable significantly improved the prediction accuracy of RFM especially at lower depth intervals. These results could be used for producing soil function maps for national agricultural planning and in assessments of environmental sustainability.

Significance Geologic carbon storage remains a safe option to mitigate anthropogenic climate change. Properly sited and managed storage sites are unlikely to induce felt seismicity because ( i ) sedimentary formations, which are softer than the crystalline basement, are rarely critically stressed; ( ii ) the least stable situation occurs at the beginning of injection, which makes it easy to control; ( iii ) CO ₂ will dissolve into brine at a significant rate, reducing overpressure; and ( iv ) CO ₂ will not flow across the caprock because of capillarity, but brine will, which will reduce overpressure further. Furthermore, CO ₂ leakage through fault reactivation is unlikely because the high clay content of caprocks ensures a reduced permeability and increased entry pressure along localized deformation zones. Zoback and Gorelick [(2012) Proc Natl Acad Sci USA 109(26):10164–10168] have claimed that geologic carbon storage in deep saline formations is very likely to trigger large induced seismicity, which may damage the caprock and ruin the objective of keeping CO ₂ stored deep underground. We argue that felt induced earthquakes due to geologic CO ₂ storage are unlikely because ( i ) sedimentary formations, which are softer than the crystalline basement, are rarely critically stressed; ( ii ) the least stable situation occurs at the beginning of injection, which makes it easy to control; ( iii ) CO ₂ dissolution into brine may help in reducing overpressure; and ( iv ) CO ₂ will not flow across the caprock because of capillarity, but brine will, which will reduce overpressure further. The latter two mechanisms ensure that overpressures caused by CO ₂ injection will dissipate in a moderate time after injection stops, hindering the occurrence of postinjection induced seismicity. Furthermore, even if microseismicity were induced, CO ₂ leakage through fault reactivation would be unlikely because the high clay content of caprocks ensures a reduced permeability and increased entry pressure along the localized deformation zone. For these reasons, we contend that properly sited and managed geologic carbon storage in deep saline formations remains a safe option to mitigate anthropogenic climate change.

Abstract We investigated the effects of substrate (cellulose or starch) and different clay contents on the production of microbial extracellular polymeric substances (EPS) and concomitant development of stable soil aggregates. Soils were incubated with different amounts of montmorillonite (+ 0.1%, + 1%, + 10%) both with and without two substrates of contrasting quality (starch and cellulose). Microbial respiration (CO2), biomass carbon (C), EPS-protein, and EPS-polysaccharide were determined over the experimental period. The diversity and compositional shifts of microbial communities (bacteria/archaea) were analysed by sequencing 16S rRNA gene fragments amplified from soil DNA. Soil aggregate size distribution was determined and geometric mean diameter calculated for aggregate formation. Aggregate stabilities were compared among 1–2-mm size fraction. Starch amendment supported a faster increase than cellulose in both respiration and microbial biomass. Microbial community structure and composition differed depending on the C substrate added. However, clay addition had a more pronounced effect on alpha diversity compared to the addition of starch or cellulose. Substrate addition resulted in an increased EPS concentration only if combined with clay addition. At high clay addition, starch resulted in higher EPS concentrations than cellulose. Where additional substrate was not provided, EPS-protein was only weakly correlated with aggregate formation and stability. The relationship became stronger with addition of substrate. Labile organic C thus clearly plays a role in aggregate formation, but increasing clay content was found to enhance aggregate stability and additionally resulted in the development of distinct microbial communities and increased EPS production.

Cadmium is a toxic heavy metal that may be detected in soils and plants. Wheat, as a food consumed by 60% of the world’s population, may uptake a high quantity of Cd through its roots and translocate Cd to the shoots and grains thus posing risks to human health. Therefore, we tried to explore the journey of Cd in wheat via a review of several papers. Cadmium may reach the root cells by some transporters (such as zinc-regulated transporter/iron-regulated transporter-like protein, low-affinity calcium transporters, and natural resistance-associated macrophages), and some cation channels or Cd chelates via yellow stripe 1-like proteins. In addition, some of the effective factors regarding Cd uptake into wheat, such as pH, organic matter, cation exchange capacity (CEC), Fe and Mn oxide content, and soil texture (clay content), were investigated in this paper. Increasing Fe and Mn oxide content and clay minerals may decrease the Cd uptake by plants, whereas reducing pH and CEC may increase it. In addition, the feasibility of methods to diminish Cd accumulation in wheat was studied. Amongst agronomic approaches for decreasing the uptake of Cd by wheat, using organic amendments is most effective. Using biochar might reduce the Cd accumulation in wheat grains by up to 97.8%.

This paper discusses the combined use of remotely sensed optical and radar data for the estimation and mapping of soil texture. The study is based on Sentinel-1 (S-1) and Sentinel-2 (S-2) data acquired between July and early December 2017, on a semi-arid area about 3000 km2 in central Tunisia. In addition to satellite acquisitions, texture measurement samples were taken in several agricultural fields, characterized by a large range of clay contents (between 13% and 60%). For the period between July and August, various optical indicators of clay content Short-Wave Infrared (SWIR) bands and soil indices) were tested over bare soils. Satellite moisture products, derived from combined S-1 and S-2 data, were also tested as an indicator of soil texture. Algorithms based on the support vector machine (SVM) and random forest (RF) methods are proposed for the classification and mapping of clay content and a three-fold cross-validation is used to evaluate both approaches. The classifications with the best performance are achieved using the soil moisture indicator derived from combined S-1 and S-2 data, with overall accuracy (OA) of 63% and 65% for the SVM and RF classifications, respectively.