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1-Butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF(6)) was synthesized and purified to be used as a ionic liquid solvent. Its physicochemical properties were studied. The ionic liquid/water (P(il/water)) and ionic liquid/heptane (P(il/heptane)) distribution coefficients of a set of 40 compounds with various functionalities, including organic acids, organic bases, amino acids, antioxidants, and neutral compounds, were measured using liquid chromatography. For ionizable compounds, the P(il/water) values measured at pH 2, 5.1, and 10 were very different. These allowed the determination of both the molecular P(o)il(/water) values and the ion P(-)il(/water) value for each compound. These coefficients were compared to the corresponding P(oct/water) coefficients. Marked differences in the partitioning behavior of basic, acidic, and neutral compounds were observed. The relationship between P(il/water) and P(oct/water) is different from that reported previously. By using the linear free energy solvation approach and the descriptors found for 12 solutes, the BMIM-PF(6) solvent parameters were calculated for the ionic liquid/water and ionic liquid/heptane biphasic systems. The regression parameters show a low basicity of the BMIM-PF(6) solvent compared to octanol. The high cohesion of the ions in the ionic liquid phase is also indicated by the regression equations obtained. Ionized phenols (phenoxide ions) associate more strongly with BMIM-PF(6) than most other ionized molecules. Amino acids were not soluble in ionic liquid; however, it is possible to extract them partially by adding a crown ether to the ionic liquid phase and working at pH 1. The positive form of amino acids is complexed by the crown ether and the complex is extracted in the ionic liquid phase.

Recently, the purification technology for high-purity aluminum (Al) has become the focus and difficulty of the majority of researchers. In this study, a novel approach for removing iron (Fe) impurities from pure Al via combining the supergravity field and semi-solid refining was proposed. Various separation temperatures (T), holding times (th), and separation times (ts) were applied within a gravitational field to explore their impact on the purification process and its underlying mechanisms. The optimal conditions were achieved at T = 653 °C, th = 40 min, ts = 3 min, and a gravity coefficient G = 1000, with the loss rate of purified Al reaching up to 4.1% and the removal rate of Fe reaching 81.9%. The Fe content in pure Al was reduced from 0.32 wt.% to 0.06 wt.%. Moreover, the purified mechanism of supergravity in a semi-solid method was reported for the first time. It was concluded that supergravity could decrease the value of the effective distribution coefficient (ke), thereby promoting the continuous migration of Fe impurities at the solidification interface into the liquid phase. The Fe-rich phase in the Al melt was completely filtered to the lower part of the crucible in the supergravity field, completing the further purification of the pure Al.

This article reviews the pollution status of anticancer drugs present in the Yodo River basin located in the Kansai district of Japan, covering both the soluble and insoluble (adsorbed on the river sediments and suspended solids) levels. Procedures ranging from sampling in the field and instrumental analytical methods to the data processing for mass balance estimation of the target basin are also described. All anticancer drugs concerned with this article were detected in sewage and river waters, where the presence of bicalutamide (BLT) was identified at considerably high concentrations (maximum 254 ng/L in the main stream, 151 ng/L in tributaries, and 1032 ng/L in sewage treatment plant (STP) effluents). In addition, sorption distribution coefficient (logKd) values showed a tendency to become higher in the silty sediments at Suita Bridge than in the sandy sediments at Hirakata Bridge; these trends were supported by the results of the laboratory-scale sorption experiment. STPs were concluded to be the main sources of the anticancer drug load in the river, and a mass flux evaluation revealed that the effect of attenuation in the river environment was small. The effectiveness of ozonation in the sewage treatment process for removal of these anticancer drugs was further confirmed. The present article should be of value for facilitating the environmental risk assessment of a wide range of drugs in a broader geographical area.

The recovery of acetic acid from aqueous sodium acetate using traditional methods is costly and energy-intensive. The current study focuses on exploring a synergetic reactive extraction methodology to extract acetic acid from aqueous sodium acetate waste. Physical extraction experiments demonstrated that methyl isobutyl ketone (MIBK) and xylene are effective diluents among MIBK, xylene, octanol, and toluene. The extraction efficiency was further enhanced by adding Aliquat 336 as an extractant and MIBK and xylene diluents in independent runs. Parameters such as the initial acid concentration in the aqueous phase, Aliquat 336 concentration in the organic phase, and temperature of the reaction mixture were investigated to optimize the operating conditions. Under all conditions, MIBK yielded better results than the other solvents. For a high acid concentration in the aqueous phase (0.5 moL.L-1), a 60% extraction efficiency was observed in the physical extraction experiment. The addition of Aliquat 336 as an extractant (0.729 moL.L-1) to the mixture under identical experimental conditions resulted in a 73% extraction efficiency. Average extraction improved by 10% for 0.2-0.5 moL.L-1 of initial acid concentration using reactive extraction technology. Such a recovery from aqueous sodium acetate using reactive extraction has rarely been reported, and hence, it is presented in this paper.

Grinding is a crucial process in machining workpieces because it plays a vital role in achieving the desired precision and surface quality. However, a significant technical challenge in grinding is the potential increase in temperature due to high specific energy, which can lead to surface thermal damage. Therefore, ensuring control over the surface integrity of workpieces during grinding becomes a critical concern. This necessitates the development of temperature field models that consider various parameters, such as workpiece materials, grinding wheels, grinding parameters, cooling methods, and media, to guide industrial production. This study thoroughly analyzes and summarizes grinding temperature field models. First, the theory of the grinding temperature field is investigated, classifying it into traditional models based on a continuous belt heat source and those based on a discrete heat source, depending on whether the heat source is uniform and continuous. Through this examination, a more accurate grinding temperature model that closely aligns with practical grinding conditions is derived. Subsequently, various grinding thermal models are summarized, including models for the heat source distribution, energy distribution proportional coefficient, and convective heat transfer coefficient. Through comprehensive research, the most widely recognized, utilized, and accurate model for each category is identified. The application of these grinding thermal models is reviewed, shedding light on the governing laws that dictate the influence of the heat source distribution, heat distribution, and convective heat transfer in the grinding arc zone on the grinding temperature field. Finally, considering the current issues in the field of grinding temperature, potential future research directions are proposed. The aim of this study is to provide theoretical guidance and technical support for predicting workpiece temperature and improving surface integrity. The temperature field is divided into uniform continuous segment and nonuniform discontinuous counterpart. The heat source distribution model is summarized for different cutting depths. The energy proportional coefficient and convective heat transfer coefficient models are summarized. The application and implementation of temperature field and grinding thermal mode are summarized.

In this study, sorption distribution coefficients were determined for 71 pharmaceuticals, aiming to describe their sorption behavior to powder activated carbon (PAC). The data are expected to be applied when designing and upgrading wastewater treatment plants (WWTP) for improved removal of pharmaceuticals by applying sorption to PAC as an additional removal technique. Sorption isotherms were determined for the pharmaceuticals over a concentration interval covering a wide range from 0.08 to 10 µg/L using PAC at a concentration of 10 mg/L. The best fitted sorption isotherms were used to calculate the distribution coefficients (Kd) and these were applied to estimate that the PAC doses needed to achieve a target concentration of 10 ng/L in the effluent. A target concentration was used since neither discharge limit values nor environmental quality standards in general have been defined for these compounds. Using a %-removal approach does not guarantee achievement of concentrations low enough to protect the water ecosystems. Some of the pharmaceuticals will be reduced by the addition of small amounts of PAC. Examples are atenolol, carbamazepine, citalopram, codeine, fluoxetine and ibuprofen. For others, e.g., oxazepam, an alternative treatment has to be considered since the requested dose is too high to be realistic for a target concentration of 10 ng/L.

The challenge of meeting growing food and energy demand while also mitigating climate change drives the development and adoption of renewable technologies ad approaches. Agrivoltaic systems are an approach that allows for both agricultural and electrical production on the same land area. These systems have the potential to reduced water demand and increase the overall water productivity of certain crops. We observed the microclimate and growth characteristics of Tomato plants (Solanum lycopersicon var. Legend) grown within three locations on an Agrivoltaic field (control, interrow, and below panels) and with two different irrigation treatments (full and deficit). Total crop yield was highest in the control fully irrigated areas a, b (88.42 kg/row, 68.13 kg/row), and decreased as shading increased, row full irrigated areas a, b had 53.59 kg/row, 32.76 kg/row, panel full irrigated areas a, b had (33.61 kg/row, 21.64 kg/row). Water productivity in the interrow deficit treatments was 53.98 kg/m3 greater than the control deficit, and 24.21 kg/m3 greater than the panel deficit, respectively. These results indicate the potential of Agrivoltaic systems to improve water productivity even for crops that are traditionally considered shade-intolerant.

Per- and polyfluoroalkyl substances (PFAS) are ever-present pollutants in the environment. They are persistent and bio-accumulative with deleterious health effects on biota. This study assesses the levels of PFAS in environmental matrices along the Nairobi River, Kenya. An aggregate of 30 PFAS were determined in water, while 28 PFAS were detected in sediments and plants using solid phase extraction then liquid chromatography–mass spectrometric techniques. In water, higher levels of perfluoroundecanoic acids of up to 39.2 ng L−1 were observed. Sediment and plant samples obtained in the midstream and downstream contained higher levels of perfluorooctanoic acid of up to 39.62 and 29.33 ng g−1, respectively. Comparably, levels of long-chain PFAS were higher in water and sediments than in plants. Sediment/water log distribution of selected PFAS ranged between 2.5 (perfluoroundecanoic acid) and 4.9 (perfluorooctane sulfonate). The level of perfluorooctane sulfonate (1.83 ng L−1) in water is above the acceptable level in surface water posing high human health and ecological risks. The observed PFAS concentrations and distribution were attributed mainly to multi-industries located along the river, among other sources. The knowledge of PFAS occurrence and distribution in Nairobi River, Kenya, provides important information to local regulatory agencies for PFAS pollution control.

The microalgae Haematococcus pluvialis are the main source of the natural antioxidant astaxanthin. However, the effective extraction of astaxanthin from these microalgae remains a significant challenge due to the rigid, non-hydrolyzable cell walls. Energy savings and high-efficiency cell disruption are essential steps in the recovery of the antioxidant astaxanthin from the cysts of H. pluvialis . In the present study, H. pluvialis microalgae were first cultured in Bold's Basal medium under certain conditions to reach the maximum biomass concentration, and then light shock was applied for astaxanthin accumulation. The cells were initially green and oval, with two flagella. As the induction time increases, the motile cells lose their flagellum and become red cysts with thick cell walls. Pre-treatment of aqueous two-phase systems based on deep eutectic solvents was used to decompose the cell wall. These systems included dipotassium hydrogen phosphate salt, water, and two types of deep eutectic solvents (choline chloride–urea and choline chloride–glucose). The results of pre-treatment of Haematococcus cells by the studied systems showed that intact, healthy cysts were significantly ruptured, disrupted, and facilitated the release of cytoplasmic components, thus facilitating the subsequent separation of astaxanthin by liquid–liquid extraction. The system containing the deep eutectic solvent of choline chloride–urea was the most effective system for cell wall degradation, which resulted in the highest ability to extract astaxanthin. More than 99% of astaxanthin was extracted from Haematococcus under mild conditions (35% deep eutectic solvent, 30% dipotassium hydrogen phosphate at 50 °C, pH = 7.5, followed by liquid–liquid extraction at 25 °C). The present study shows that the pre-treatment of two-phase systems based on deep eutectic solvent and, thus, liquid–liquid extraction is an efficient and environmentally friendly process to improve astaxanthin from the microalgae H. pluvialis .

Research was conducted to determine picloram and aminopyralid sorption in five soils and three clay minerals and to determine if the potential for off-target movement of aminopyralid in soil is less than that of picloram. Nearly all sorption of picloram and aminopyralid occurred between 0 and 8 h, and the maximum theoretical sorption of picloram and aminopyralid were 10.3 and 15.2%, respectively. Freundlich distribution coefficients (Kf) for picloram ranged from 0.12 in a Cecil sandy loam to 0.81 in an Arredondo fine sand, while Kf values for aminopyralid ranged from 0.35 in a Cecil sandy loam to 0.96 in an Arredondo fine sand. Furthermore, Kf values of aminopyralid were higher than those of picloram in all soils tested. Kf values of picloram in clay minerals were 0.25 (kaolinite), 1.17 (bentonite), and 1,016.4 (montmorillonite), and those of aminopyralid were 5.63 (kaolinite), 2.29 (bentonite), and 608.90 (montmorillonite). It was concluded that soil sorption of aminopyralid was greater than that of picloram and that the potential for off-target movement of aminopyralid is less than that of picloram. Nomenclature: Aminopyralid; picloram.