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result(s) for
"etching modification method"
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Biomimetic superhydrophobic metal/nonmetal surface manufactured by etching methods: A mini review
by
Yang, Hong
,
Mu, Hongbo
,
Ni, Haiming
in
Bioengineering and Biotechnology
,
bionic modification
,
chemical etching method
2022
As an emerging fringe science, bionics integrates the understanding of nature, imitation of nature, and surpassing nature in one aspect, and it organically combines the synergistic complementarity of function and structure–function integrated materials which is of great scientific interest. By imitating the microstructure of a natural biological surface, the bionic superhydrophobic surface prepared by human beings has the properties of self-cleaning, anti-icing, water collection, anti-corrosion and oil–water separation, and the preparation research methods are increasing. The preparation methods of superhydrophobic surface include vapor deposition, etching modification, sol–gel, template, electrostatic spinning, and electrostatic spraying, which can be applied to fields such as medical care, military industry, ship industry, and textile. The etching modification method can directly modify the substrate, so there is no need to worry about the adhesion between the coating and the substrate. The most obvious advantage of this method is that the obtained superhydrophobic surface is integrated with the substrate and has good stability and corrosion resistance. In this article, the different preparation methods of bionic superhydrophobic materials were summarized, especially the etching modification methods, we discussed the detailed classification, advantages, and disadvantages of these methods, and the future development direction of the field was prospected.
Journal Article
Wire Electrochemical Etching of Superhydrophobic Nickel Surfaces with Enhanced Corrosion Protection
by
Lin, Junyi
,
Yan, Defeng
,
Wu, Binghan
in
Abrasion resistance
,
Chemical inhibitors
,
Comparative analysis
2023
Superhydrophobic nickel surfaces have significant advantages in the field of corrosion protection compared with traditional nickel corrosion protection methods which need a toxic chemical corrosion inhibitor. Electrochemical etching, an ideal method for fabricating superhydrophobic nickel surfaces, was also limited by low current density, resulting in low processing efficiency. To overcome this limitation, we proposed a new method to fabricate a superhydrophobic nickel surface using a wire electrochemical etching method. The wire electrochemical etching method accomplished the etching process by sweeping a controlled wire cathode across the surface of the anode nickel plate in an environmentally friendly neutral electrolyte, NaCl. The superhydrophobic nickel sample with a contact angle of 153° and a rolling angle of 10° could be fabricated by wire electrochemical etching and modification. Additionally, the optimal parameters of the wire electrochemical etching and the principle of superhydrophobic surface formation had also been systematically investigated, respectively. Moreover, the superhydrophobic nickel surface had self-cleaning performance, antifouling performance, corrosion protection, and abrasion resistance. Wire electrochemical etching improves the current density of processing, which means that this method improves the processing efficiency for fabricating a superhydrophobic nickel surface. This work is expected to enrich the theory and technology for fabricating superhydrophobic nickel surfaces to improve the corrosion protection of nickel.
Journal Article
Graphene: Preparation, tailoring, and modification
2023
Graphene is a 2D material with fruitful electrical properties, which can be efficiently prepared, tailored, and modified for a variety of applications, particularly in the field of optoelectronic devices thanks to its planar hexagonal lattice structure. To date, graphene has been prepared using a variety of bottom–up growth and top–down exfoliation techniques. To prepare high‐quality graphene with high yield, a variety of physical exfoliation methods, such as mechanical exfoliation, anode bonding exfoliation, and metal‐assisted exfoliation, have been developed. To adjust the properties of graphene, different tailoring processes have been emerged to precisely pattern graphene, such as gas etching and electron beam lithography. Due to the differences in reactivity and thermal stability of different regions, anisotropic tailoring of graphene can be achieved by using gases as the etchant. To meet practical requirements, further chemical functionalization at the edge and basal plane of graphene has been extensively utilized to modify its properties. The integration and application of graphene devices is facilitated by the combination of graphene preparation, tailoring, and modification. This review focuses on several important strategies for graphene preparation, tailoring, and modification that have recently been developed, providing a foundation for its potential applications.
Graphene is a key material for a new generation of electronic devices with unique electrical properties. In this review, current advances in the preparation, tailoring, and modification of graphene to obtain high‐quality graphene with precisely controlled patterning and specific functional groups are summarized.
Journal Article
Surface Terminations of MXene: Synthesis, Characterization, and Properties
2022
MXene, 2D transition metal carbides, nitrides, and carbonitrides with a unique 2D structure, inspired a series of function applications related to energy storage and conversion, biometrics and sensing, lighting, purification, and separation. Its surface terminations are confined by the adjacent MXene layers, and form the 2D planar space with symmetrical surfaces, which is similar to a 2D nanoreactor that can be utilized and determined MXene’s function. Based on the working principle, surface and interface play critical roles in the ion intercalation, physical/chemical adsorption, and chemical reaction process, and show significant effects on MXene’s properties and functions. Although there have been some reviews on MXene, less attention has been paid to the underlying principle of the involved surface chemistry, controllable design, and resultant properties. Herein, the regulation methods, characterization techniques, and the effects on properties of MXene surface terminations were summarized to understand the surface effects, and the relationship between the terminations and properties. We expected this review can offer the route for a series of ongoing studies to address the MXene surface environment and the guidelines for MXene’s application.
Journal Article
Multi-Scale Surface Treatments of Titanium Implants for Rapid Osseointegration: A Review
by
Attarilar, Shokouh
,
Liu, Shifeng
,
Wang, Qingge
in
Biocompatibility
,
Biological activity
,
Bionics
2020
The propose of this review was to summarize the advances in multi-scale surface technology of titanium implants to accelerate the osseointegration process. The several multi-scaled methods used for improving wettability, roughness, and bioactivity of implant surfaces are reviewed. In addition, macro-scale methods (e.g., 3D printing (3DP) and laser surface texturing (LST)), micro-scale (e.g., grit-blasting, acid-etching, and Sand-blasted, Large-grit, and Acid-etching (SLA)) and nano-scale methods (e.g., plasma-spraying and anodization) are also discussed, and these surfaces are known to have favorable properties in clinical applications. Functionalized coatings with organic and non-organic loadings suggest good prospects for the future of modern biotechnology. Nevertheless, because of high cost and low clinical validation, these partial coatings have not been commercially available so far. A large number of in vitro and in vivo investigations are necessary in order to obtain in-depth exploration about the efficiency of functional implant surfaces. The prospective titanium implants should possess the optimum chemistry, bionic characteristics, and standardized modern topographies to achieve rapid osseointegration.
Journal Article
Cold Plasma-Induced Modulation of Protein and Lipid Macromolecules: A Review
by
Rout, Srutee
,
Hsieh, Chien-Te
,
Panda, Pradeep Kumar
in
Amino acids
,
Animal behavior
,
Atmospheric pressure
2025
Nowadays, the food industry is prioritizing many innovative processing technologies that can produce minimally processed foods with superior and higher quality, lower costs, and faster operations. Among these advancements, cold plasma (CP) processing stands out for its remarkable capabilities in food preservation and extending the shelf life. Beyond its established role in microbial inactivation, CP has emerged as a transformative tool for modifying food biomolecules through reactive plasma species, addressing the versatile requirements of food industries for various applications. This review focuses on the interactions between reactive plasma species and essential food macromolecules, including proteins, lipids, and polysaccharides. The novelty lies in its detailed examination of how CP technology triggers structural, functional, and biochemical changes in proteins and lipids and explains the mechanisms involved. It connects fundamental molecular transformations to practical applications, such as enhanced protein functionality, lipid stabilization, and improved oxidative resistance. CP induces alterations in protein structure, especially in amino acid configurations, that can be applicable to the formulation of advanced gel, 3D printing, thermostable emulsions, enhanced solubility, and sensory materials. This review explores the ability of CP to modify protein allergenicity, its different effects on the mechanical and interfacial properties of proteins, and its role in the production of trans-fat-free oils. Despite its potential, a detailed understanding of the mechanism of CP’s interactions with food macromolecules is also discussed. Furthermore, this review addresses key challenges and outlines future research opportunities, positioning CP as a sustainable and adaptable approach for innovating next-generation food systems. Further research is crucial to fully understand the potential of CP for food processing, followed by product development.
Journal Article
Research Progress on Surface Modification of Titanium Implants
2025
Implants made of titanium and its alloys are currently widely used in the human body. A series of surface modification methods developed nowadays enable titanium alloy implants to serve effectively in the human body for a long time. This paper reviews three different types of surface modification technologies for biomedical titanium alloys: physical, chemical, and biological, with particular attention to the assistance of these three technologies on the biological properties of titanium alloys. The physical method can change the surface morphology of titanium implants and prepare specific coatings for the implants, such as oxide films, bioactive molecules, drugs, etc. Chemical and biological surface modification technologies can minimize bacterial adhesion on the implant surface, improve the integration of soft tissue around the implant, prevent the occurrence of peri-implantitis, and accelerate the process of damage repair. An ideal titanium implant surface should balance the optimal surface morphology, chemical properties, and bionic characteristics to accelerate bone integration, enhance stability, and reduce peri-implant inflammation. Future research should focus on combining technologies, exploring interactions at the cellular and molecular levels, and conducting extensive in vitro and in vivo studies to verify the effectiveness and safety of modified surfaces. The progress in these fields will help overcome the existing limitations, improve the performance of implants, and obtain better clinical results.
Journal Article
Chromogenic Mechanisms of Colorimetric Sensors Based on Gold Nanoparticles
2023
The colorimetric signal readout method is widely used in visualized analyses for its advantages, including visualization of test results, simple and fast operations, low detection cost and fast response time. Gold nanoparticles (Au NPs), which not only exhibit enzyme-like activity but also have the advantages of tunable localized surface plasmon resonance (LSPR), high stability, good biocompatibility and easily modified properties, provide excellent platforms for the construction of colorimetric sensors. They are widely used in environmental monitoring, biomedicine, the food industry and other fields. This review focuses on the chromogenic mechanisms of colorimetric sensors based on Au NPs adopting two different sensing strategies and summarizes significant advances in Au NP-based colorimetric sensing with enzyme-like activity and tunable LSPR characteristics. In addition, the sensing strategies based on the LSPR properties of Au NPs are classified into four modulation methods: aggregation, surface modification, deposition and etching, and the current status of visual detection of various analytes is discussed. Finally, the review further discusses the limitations of current Au NP-based detection strategies and the promising prospects of Au NPs as colorimetric sensors, guiding the design of novel colorimetric sensors.
Journal Article
MXene Surface Architectonics: Bridging Molecular Design to Multifunctional Applications
2025
This review delves into the surface modification of MXenes, underscoring its pivotal role in improving their diverse physicochemical properties, including tailor MXenes’ electrical conductivity, mechanical strength, and wettability. It outlines various surface modification strategies and principles, highlighting their contributions to performance enhancements across diverse applications, including energy storage and conversion, materials mechanics, electronic devices, biomedical sciences, environmental monitoring, and fire-resistant materials. While significant advancements have been made, the review also identifies challenges and future research directions, emphasizing the continued development of innovative materials, methods, and applications to further expand MXenes’ utility and potential.
Journal Article
Hydrophobisation of lignocellulosic materials part I: physical modification
by
Syverud, Kristin
,
Rodríguez-Fabià, Sandra
,
Johansson, Lars
in
Adsorption
,
Adsorption method
,
Alkanes
2022
This review is the first part of a comprehensive review of hydrophobisation of lignocellulosic materials. The purpose of this review has been to compare physical hydrophobisation methods of lignocellulosic materials. We have compared molecular physical adsorption with plasma etching and grafting. Adsorption methods are facile and rely upon the simple mixing or coating of the substrate with the hydrophobing agent. However, none of the surfactant-based methods reviewed here reach contact angles above 90°, making them unsuitable for applications where a high degree of hydrophobisation is required. Nevertheless, surfactant based methods are well suited for compatibilising the lignocellulosic material with a hydrophobic matrix/polymer in cases where only a slight decrease in the hydrophilicity of the lignocellulosic substrate is required. On the other hand, wax- and lignin-based coatings can provide high hydrophobicity to the substrates. Plasma etching requires a more complex set-up but is relatively cheap. By physically etching the surface with or without the deposition of a hydrophobic coating, the material is rendered hydrophobic, reaching contact angles well above 120°. A major drawback of this method is the need for a plasma etching set-up, and some researchers co-deposit fluorine-based layers, which have a negative environmental impact. An alternative is plasma grafting, where single molecules are grafted on, initiated by radicals formed in the plasma. This method also requires a plasma set-up, but the vast majority of hydrophobic species can be grafted on. Examples include fatty acids, silanes and alkanes. Contact angles well above 110° are achieved by this method, and both fluorine and non-toxic species may be used for grafting.
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Journal Article