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The aim of this study is to compare alternative treatments on solvent-free extraction of high added value components from fermented grape pomace. Ultrasounds (US), pulsed electric fields (PEF) and high voltage electric discharges (HVED), which are physical treatments able to induce cell damages, were applied on aqueous suspensions of grape pomace. The efficiency of these technologies for phenolic compounds extraction, and particularly for anthocyanins recovery, was evaluated throughout the treatments at equivalent cell disintegration indexes (Z). HVED proved to be the most interesting technique to achieve higher phenolic compounds recovery with lower energy requirement than PEF and US at the same values of Z. However, HVED was less selective than PEF and US regarding the amount of anthocyanins recovered. At equivalent cell disintegration of Z  = 0.8, PEF remarkably increased the extraction yield of total anthocyanins up to 22 and 55 % in comparison with US and HVED-assisted extractions. At this Z value, the ratio of total anthocyanins to TPC extracted reaches the respective values of 41.7, 34.9 and 14.1 % for PEF, US and HVED, thus demonstrating interesting differences of selectivity of the treatments.

The study was aimed at improvement of recovery of intracellular valuable compounds from olive kernels (Olea europaea). High voltage electrical discharges (HVED), pulsed electric field (PEF), and ultrasound (US) were applied as pretreatments before extraction. The influence of HVED energy input (0–109 kJ/kg), pH (2.5–12), and ethanol (0–50 %) on the efficiency of the extraction was studied. The extracts obtained immediately after pretreatments were analyzed for total phenolic compounds, antioxidant activity, proteins, and pigments. HVED treatment was demonstrated to be more effective than ultrasound and pulsed electric field in terms of energy input and effective treatment time to extract phenolic compounds and proteins. Moreover, the application of HVED increased significantly the aqueous and hydro-ethanolic extractions of total phenolic content (TPC), and proteins of the recovered extracts when energy input was augmented. pH and ethanol percentage had also a significant influence in TPC, protein, and antioxidant recovery. The interesting observation is that pH 2.5 resulted in the optimum conditions to recover TPC and antioxidant capacity. However, the higher protein content was found when pH 12 was used. Multiple response optimization showed that TPC, content of proteins, and antioxidant capacity (Trolox equivalent antioxidant capacity (TEAC) and 1,1-diphenyl-2-picrylhydrazyl (DPPH) values) of the sample were further maximized after HVED pretreatment at energy input 66 kJ/kg at pH 2.5 followed by extraction in 49 % ethanol. TPC, content of proteins, TEAC, and DPPH values under such conditions of extraction were 626.6 mg GAE/L, 0.225 mg/mL, 9.80 mM TE, and 7.61 mM TE, respectively.

High permittivity materials are currently in use for mitigation of electrical stress in high-voltage apparatus and energy storage systems. In this work, epoxy-based high permittivity nanocomposites with Barium titanate (BaTiO3) nanofillers are considered, for the purpose of stress mitigation. Uniform dispersion of the fillers in the polymer up to 10% by volume is achieved. Apart from the use of as-received fillers, the effect of using surface-functionalised nanoparticles (with 3-glycidoxypropyltrimethoxy-silane) before use is also investigated. The nanocomposite is characterised in terms of its complex permittivity, DC conductivity, short-term AC breakdown strength and space charge accumulation, to gauge its suitability for use in high-voltage insulation. Complex permittivity is measured using broadband dielectric spectroscopy over a broad frequency range of 1 mHz to 1 MHz. DC conductivity is studied from polarisation–depolarisation current measurements. Short-term AC breakdown strength tests are performed at power frequency (50 Hz). Space charge density along the sample thickness is obtained using pulsed electro-acoustic technique. A computational case-study is presented to show the feasibility of using the high permittivity nanocomposite for electric stress control in high-voltage equipment (viz., at mounting flanges of 69 kV bushings).

The key to enabling long-term cycling stability of high-voltage lithium (Li) metal batteries is the development of functional electrolytes that are stable against both Li anodes and high-voltage (above 4 V versus Li/Li + ) cathodes. Due to their limited oxidative stability ( <4 V), ethers have so far been excluded from being used in high-voltage batteries, in spite of their superior reductive stability against Li metal compared to conventional carbonate electrolytes. Here, we design a concentrated dual-salt/ether electrolyte that induces the formation of stable interfacial layers on both a high-voltage LiNi 1/3 Mn 1/3 Co 1/3 O 2 cathode and the Li metal anode, thus realizing a capacity retention of >90% over 300 cycles and ~80% over 500 cycles with a charge cut-off voltage of 4.3 V. This study offers a promising approach to enable ether-based electrolytes for high-voltage Li metal battery applications. Ether-based electrolytes offer many advantages compared to other electrolyte systems, but they are not stable in Li metal batteries when operating at high voltages. Here, the authors develop a concentrated ether electrolyte that enables long-term cycling stability of high-voltage Li metal batteries.

LiNi 0.5 Mn 1.5 O 4 (LNMO) with a spinel crystal structure presents a compelling avenue towards the development of economic cobalt-free and high voltage (∼ 5 V) lithium-ion batteries. Nevertheless, the elevated operational voltage of LNMO gives rise to pronounced interfacial interactions between the distorted surface lattices characterized by Jahn–Teller (J–T) distortions and the electrolyte constituents. Herein, a localized crystallized coherent LaNiO 3 and surface passivated Li 3 PO 4 layer is deposited on LNMO via a one-step calcination process. As evidenced by transmission electron microscopy (TEM), time-of-flight secondary ion mass spectrometry (ToF-SIMS) and density functional theory (DFT) calculation, the epitaxial growth of LaNiO 3 along the LNMO lattice can effectively stabilize the structure and inhibit irreversible phase transitions, and the Li 3 PO 4 surface coating can prevent the chemical reaction between HF and transition metals without sacrificing the electrochemical activity. In addition, the ionic conductive Li 3 PO 4 and atomic wetting inter-layer enables fast charge transfer transport property. Consequently, the LNMO material enabled by the lattice bonding and surface passivating features, demonstrates high performance at high current densities and good capacity retention during long-term test. The rational design of interface coherent engineering and surface coating layers of the LNMO cathode material offers a new perspective for the practical application of high-voltage lithium-ion batteries.

To drive electronic devices for a long range, the energy density of Li‐ion batteries must be further enhanced, and high‐energy cathode materials are required. Among the cathode materials, LiCoO2 (LCO) is one of the most promising candidates when charged to higher voltages over 4.3 V. However, high‐voltage LCO materials are confronted with severe surface and bulk issues inducing poor cyclic stability. To completely unleash the potential of LCO cathodes, a more comprehensive theoretical understanding of the underlying issues is necessary, along with active exploration of previous modifications. This paper mainly presents the degradation mechanisms of LCO under high voltage, the formation and evolution mechanisms of the cathode electrolyte interface, and the surface engineering strategies employed to enhance the cell performance. By organizing and summarizing these modifications, this work aims to establish associations among common research issues and to suggest future research priorities, thus facilitating the rapid development of high‐voltage LCO. As a crucial cathode material in lithium‐ion batteries, when charged to higher voltages, LiCoO2 faces challenges in maintaining stability while delivering more capacity, the specific mechanisms of which in LiCoO2 at the bulk and the interface need to be further investigated. Consequently, this review starts with the failure mechanisms of LiCoO2 under high voltages and especially summarizes current modifications, endeavoring to deepen the cognition of interface and facilitate the development of the Li battery industry.

High voltage (HV) test environments require dependable visual status indicators to maintain operator safety; however, directly supplying these indicators from HV sources introduces substantial electrical and operational hazards. This work addresses these challenges through the design and implementation of a compact Flyback DC–DC converter that provides galvanic isolation and a stable low-power output specifically intended for LED-based safety beacons. While utilizing Discontinuous Conduction Mode (DCM) and valley-switching to minimize thermal stress, the primary innovation of this design lies in the rigorous optimization of the isolation barrier and PCB architecture to meet HV safety standards (such as IEC 60950-1) within a minimal physical footprint. Transformer parameters were determined using analytical design procedures and subsequently verified by circuit-level simulations, which confirmed correct DCM operation as well as rapid startup behavior without output overshoot. A two-layer PCB was designed in accordance with IPC-2221B standard, with particular emphasis on minimizing parasitic effects and thereby improving overall performance. Experimental characterization demonstrated stable output regulation and a strong correlation between measured and simulated waveforms. The proposed system enhances safety in HV laboratory settings while achieving a compact form factor and supporting a wide input voltage range.

As Europe integrates more renewable energy resources, notably offshore wind power, into its super meshed grid, the demand for reliable long-distance High Voltage Direct Current (HVDC) transmission systems has surged. This paper addresses the intricacies of HVDC systems built upon Modular Multi-Level Converters (MMCs), especially concerning the rapid rise of DC fault currents. We propose a novel fault identification and classification for DC transmission lines only by employing Long Short-Term Memory (LSTM) networks integrated with Discrete Wavelet Transform (DWT) for feature extraction. Our LSTM-based algorithm operates effectively under challenging environmental conditions, ensuring high fault resistance detection. A unique three-level relay system with multiple time windows (1 ms, 1.5 ms, and 2 ms) ensures accurate fault detection over large distances. Bayesian Optimization is employed for hyperparameter tuning, streamlining the model’s training process. The study shows that our proposed framework exhibits 100% resilience against external faults and disturbances, achieving an average recognition accuracy rate of 99.04% in diverse testing scenarios. Unlike traditional schemes that rely on multiple manual thresholds, our approach utilizes a single intelligently tuned model to detect faults up to 480 ohms, enhancing the efficiency and robustness of DC grid protection.

High-voltage capacitors are key components for circuit breakers and monitoring and protection devices, and are important elements used to improve the efficiency and reliability of the grid. Different technologies are used in high-voltage capacitor manufacturing process, and at all stages of this process polymeric films must be used, along with an encapsulating material, which can be either liquid, solid or gaseous. These materials play major roles in the lifespan and reliability of components. In this paper, we present a review of the different technologies used to manufacture high-voltage capacitors, as well as the different materials used in fabricating high-voltage film capacitors, with a view to establishing a bibliographic database that will allow a comparison of the different technologies

Large-scale renewable energy plants, flexible AC (alternating current) and high voltage DC (direct current) transmission systems, and modern consumer devices utilize power electronics that tend to increase harmonic emissions. Furthermore, such emissions are nowadays known to exceed the traditional 2 kHz range typically considered for harmonic analysis. However, the accuracy of such harmonic measurements in medium and high voltage networks is questionable due to the lack of accuracy specifications for the respective instrument transformers that are being used in the measurement chain. Therefore, the motivation of this study is to review the existing techniques for measuring high-frequency voltage harmonics, i.e., those in the range 2–9 kHz, in medium-, high-, and extra high-voltage electricity networks, where most large-scale power electronic converters are being connected. Different transducer types are compared in terms of measurement accuracy. The reviewed literature indicates that some transducers can introduce errors due to their nonlinearities. The study also identifies the limitations of calibrating these transducers at frequencies above 2 kHz due to the unavailability of suitable sources capable of generating the required test waveforms. Furthermore, the study emphasizes the necessity for establishing accuracy limits for harmonic measurements above 2 kHz.