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This paper presents an analysis of data on the cross sections of elastic and inelastic collisions of electrons with noble gases, alkali and other atoms. For the selected sets of experimental and theoretical data, optimal analytical formulas are found, and approximation coefficients are calculated. The obtained semi-empirical formulas reproduce the values of the transport (diffusion), excitation and ionization cross sections for noble gases. Much attention is paid to the ionization cross sections of metal atoms, which are often present as an impurity in gas-discharge plasma. The approximation formulas reproduce the values of the ionization cross sections for hydrogen, metal and other elements in a wide range of energies with accurate orders of errors of the available theoretical and experimental data. For some elements with a two-hump plot of the dependence of the ionization cross section on the collision energy, it is proposed to use a two-term formula that takes into account ionization from both external and internal shells.

The ionization data of a neutral molecule are crucial to model the energy deposition and dissociative ionization process. We study theoretically the electron impact ionization process and report on the dissociative ionization cross sections of the tungsten hexafluoride cations invoking the modified-binary-encounter-Bethe model. In this model, the binary-encounter-Bethe model is modified by applying the transformation to the binding energies of the molecular orbitals and then normalizing the partial ionization cross sections of the cations using the branching ratios. The normalization is performed at a particular energy and ensures that the branching ratios of different fragments are summed to unity. The model yielded satisfactory results for both the singly and doubly ionized ions. The approach validates the results of Basner et al. The advantages and limitations of this model are also discussed. This work corroborates the importance of mass spectrometry data in the proper understanding of the ionization process.

In an effort to measure electron-impact ionization (EII) cross-sections of He-like Fe24+ at the electron beam ion trap (EBIT) facility of the National Institute of Standards and Technology (NIST), we have experimentally determined the corrections to the nominal beam energy determined by the voltages applied to the EBIT. High-resolution X-ray spectra were recorded at nominal electron beam energies between 6660 eV and 6750 eV using X-ray microcalorimetry based upon an array of 192 transition-edge sensors (TES). A large-scale collisional-radiative simulation of the non-Maxwellian EBIT plasma using relevant atomic data calculated with Flexible Atomic Code allowed us to determine the space-charge correction due to the electron beam including the neutralization factor by the ion cloud of the EBIT.

In the current work, we study the intense laser pulse influences on the behaviors of the first excitonic transition in a core/shell quantum dot submitted to an electric field. Therefore, the exciton binding energy and the mean distance between the correlated electron–hole pair are discussed, considering the electric field and laser strength. Our calculations show that both external fields play significant repulsive effects. Through their effects, they oppose the attractive nature of the Coulomb potential between the correlated pair, which decreases the excitonic binding energy. We also analyze the dissociation process by determining the photo-ionization cross-section (PICS). Our findings show that the peaks of the PICS redshift when the shell thickness b−a increases. For a given core radius, the laser and electric field induce a shift toward the low-energy region for the PICS; this displacement is more pronounced for the laser case. Our study also compares simple quantum dots and core/shell quantum dots to show the effect of the inner radius on the obtained results. Our theoretical results can lead to promising applications of exciton-based devices controlled by sizes and external fields.

In the present investigation, the plane-wave Born approximation was employed to calculate the total ionization cross sections by electron impact of methanol, ethanol and 1-propanol from the threshold of ionization to 10 MeV. This method requires continuum generalized oscillator strengths (CGOSs). The two different semi-phenomenological expressions of CGOS, given by Mayol and Salvat and Weizsacker and Williams, along with approximated form of the continuum optical oscillator strength (COOS) by Khare et al. were used. Furthermore, the average of the above two CGOSs was also used. The calculated ionization cross sections were compared to the available previous theoretical results and experimental data. Out of three CGOSs, the present results with the average CGOS were found in good agreement with the available experimental results for all the considered molecules. Collision parameters CRP were also calculated from 0.1 to 100 MeV and the calculations were found to be in excellent agreement with the experimental results of Reike and Prepejchal.

The paper presents an analysis of data on the cross sections of electron impact ionization of atoms of alkali metals, hydrogen, noble gases, some transition metals and Al, Fe, Ni, W, Au, Hg, U. For the selected sets of experimental and theoretical data, an optimal analytical formula is found and approximation coefficients are calculated. The obtained semi-empirical formula reproduces the values of the ionization cross sections in a wide range of energies with an accuracy of the order of error of the available theoretical and experimental data.

An analytical expression for the amplitude of ionization of the hydrogen molecule by electron impact in the first Born approximation with a one-center Coulomb continuum wave function is derived. The case where the incident electron energy is much greater than the ejected electron energy is considered. The molecular wave functions were constructed in the approximation of linear combination of atomic orbitals with overlapping configurations. The role of the orthogonalization of the initial and final wave functions of the active electron of the target is elucidated. The triple differential ionization cross sections for the different orientations of the molecular axis and that averaged over all orientations are calculated. The secondary electron angular distribution is represented in the form of three-dimensional images. A comparison with the results of other theoretical calculations and experimental data is performed.

The electron impact partial ionization cross-sections of molecules such as methane, water and nitromethane are computed using a modified form of the binary encounter Bethe (BEB) formula. The modified form of the BEB model works on rescaling the molecular binding energies of the orbitals and the scaling of cross-sections using the electron ionization mass spectrometry data. The computed partial ionization cross-sections are consistent with the recommended data and are better than several experimental and theoretical results. The summed partial ionization cross-sections of different fragments also agree with the total ionization cross-sections obtained from BEB and the experimental data. This work highlights the utility of mass spectrometry in the modeling and interpretation of the ionization cross-section data. The limitations and the advantages of the modified form of the BEB model are also discussed.

Abstract An elaborate theoretical study of electron scattering with benzene over a broad impact energy range is reported in this article. Integrated cross sections such as the electronic excitation cross section, momentum transfer cross section, ionization cross section and the total collision cross section along with the differential elastic cross section are computed at low energy (0.01–20 eV) using ab initio R-matrix employing Quantemol-N. Beyond ionization threshold, the calculations are also carried out using spherical complex optical potential (SCOP) formalism up to 5000 eV. A smooth crossover of the total cross section data is obtained through the two formalisms at the incident energy equal to 13 eV and hence we are able to study the cross sections over a wide energy range. The scattering rate coefficients using the computed elastic cross sections for this target are reported for the first time. Graphical abstract

In this manuscript, we present our calculations of detailed electron-impact single ionization cross-sections for tungsten ions, spanning charge states W38+− W45+. The level-to-level distorted-wave method implemented in the flexible atomic code (FAC) was used for calculation. Comparison between the present level-to-level distorted wave treatment and previous configuration-averaged calculations has been performed for the W45+ ion, and we explore the possible reason for the difference observed between two calculations. We demonstrate the importance of radiative damping on the total electron-impact ionization cross-section for the W43+ ion. Present calculations provide missing cross-sections for W38+− W45+. The data obtained are expected to be useful for modeling plasmas for fusion applications, especially for the ITER community.