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Accurate solar background noise modeling in island-reef LiDAR surveys is hindered by anisotropic coastal reflectivity and dynamic light paths, which isotropic models fail to address. We propose BNR-B, a bidirectional reflectance distribution function (BRDF)-based noise model that integrates solar-receiver geometry with micro-facet scattering dynamics. Validated via single-photon LiDAR field tests on diverse coastal terrains at Jiajing Island, China, BNR-B reveals the following: (1) Solar zenith/azimuth angles non-uniformly modulate noise fields—higher solar zenith angles reduce noise intensity and homogenize spatial distribution; (2) surface reflectivity linearly correlates with noise rate (R2 > 0.99), while roughness governs scattering directionality through micro-facet redistribution. BNR-B achieves 28.6% higher noise calculation accuracy than Lambertian models, with a relative phase error < 2% against empirical data. As the first BRDF-derived solar noise correction framework for coastal LiDAR, it addresses critical limitations of isotropic assumptions by resolving directional noise modulation. The model’s adaptability to marine–terrestrial interfaces enhances precision in coastal monitoring and submarine mapping, offering transformative potential for geospatial applications requiring photon-counting LiDAR in complex environments. Key innovations include dynamic coupling of geometric optics and surface scattering physics, enabling robust spatiotemporal noise quantification, critical for high-resolution terrain reconstruction.