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We report the application of an infrared dual‐wavelength laser absorption spectroscopy system, which combines tunable diode laser absorption spectroscopy and wavelength modulation integrated cavity output spectroscopy technologies based on two spectroscopic sources operating at 6,029 and 2,310 cm−1, to simultaneously measure the gas concentrations (CH4 and CO2) and carbon isotopic signatures (13C and 12C) in coalbed methane. The Allan variance is used to analyze the optimum mean time (t) and the standard deviation (SD), with t = 450 s, SD = 0.41‰ for 13CH4 monitoring and t = 70 s, SD = 0.17‰ for 13CO2 monitoring. Furthermore, 47 groups of coalbed methane samples collected from the Huaibei‐Qidong coal mine seam are analyzed based on the measured results for carbon isotopes and geophysical geochemistry. The δ13CH4 values of the Qidong coal mine fall between −44.57‰ and −61.57‰, and the δ13CO2 values fall between −21.65‰ and −17.06‰. The genetic types of methane may be divided into biogenic gas, thermogenic gas, and mixture gas. Carbon dioxide may be derived from coal pyrolysis, and it also has the characteristics of carbon‐isotope changes of organic genetic gas. The new approach for analyzing rapid genetic types, methane migration pathways, gas disaster source warning, and coal chemistry studies is expected to be further studied in the future. Plain Language Summary In coal mine research, the measurement of carbon isotopic characteristics and the geochemical method have been found to be some of the most effective methods to identify the genesis, transport process, and source of coalbed methane (CBM). However, the application of carbon isotope measurement to gas outburst and transport in coal mines is still rare. Conventionally, the isotope has been determined by isotope ratio mass spectrometer measurements because of their high sensitivity and high accuracy, but its application range and frequency of sample analysis are severely limited because of its size, complex structure, high time consumption, sample collection, and complex preparation. In this paper, we introduce an infrared dual‐wavelength laser absorption spectroscopy system, which combines tunable diode laser absorption spectroscopy and wavelength modulation integrated cavity output spectroscopy technologies based on two spectroscopic sources operating at 6,029 and 2,310 cm−1, to simultaneously measure the gas concentrations (CH4 and CO2) and carbon isotopic signatures (13C and 12C) in CBM. Furthermore, 47 groups of CBM samples collected from the Huaibei‐Qidong coal mine seam are analyzed based on the measured results for carbon isotopes and geophysical geochemistry. The measurement results show good agreement with reference isotope ratio mass spectrometer measurements, confirming the accuracy of the proposed system. Key Points Novel infrared dual‐wavelength laser absorption spectroscopy system is reported, to measure the gas concentrations and carbon isotopic The CH4 was divided into biogenic gas, thermogenic gas, and mixture gas; CO2 derived from coal pyrolysis has the features of organic genetic gas This new approach can also be used to rapid analyze the genetic types, migration pathways, disaster source warning, and coal chemistry

Dual-comb spectroscopy has become a powerful spectroscopic technique in applications that rely on its broad spectral coverage combined with high frequency resolution capabilities. Experiments to date have primarily focused on detection and analysis of multiple gas species under semi-static conditions, with applications ranging from environmental monitoring of greenhouse gases to high-resolution molecular spectroscopy. Here, we utilize dual-comb spectroscopy to demonstrate broadband, high-resolution, and time-resolved measurements in a laser-induced plasma. As a demonstration, we simultaneously detect trace amounts of Rb and K in solid samples with a single laser ablation shot, with transitions separated by over 6 THz (13 nm) and spectral resolution sufficient to resolve isotopic and ground state hyperfine splittings of the Rb D 2 line. This new spectroscopic approach offers the broad spectral coverage found in the powerful techniques of laser-induced breakdown spectroscopy (LIBS) while providing the high-resolution and accuracy of cw laser-based spectroscopies. Dual-comb spectroscopy has become a valuable tool for broadband high-resolution measurements. Here Bergevin et al. apply this technique to a laser-induced plasma detecting different species in a solid sample with a spectral resolution sufficient to resolve hyperfine splitting of the Rb D 2 line.

Remote chemical detection in the atmosphere or some specific space has always been of great interest in many applications for environmental protection and safety. Laser absorption spectroscopy (LAS) is a highly desirable technology, benefiting from high measurement sensitivity, improved spectral selectivity or resolution, fast response and capability of good spatial resolution, multi-species and standoff detection with a non-cooperative target. Numerous LAS-based standoff detection techniques have seen rapid development recently and are reviewed herein, including differential absorption LiDAR, tunable laser absorption spectroscopy, laser photoacoustic spectroscopy, dual comb spectroscopy, laser heterodyne radiometry and active coherent laser absorption spectroscopy. An update of the current status of these various methods is presented, covering their principles, system compositions, features, developments and applications for standoff chemical detection over the last decade. In addition, a performance comparison together with the challenges and opportunities analysis is presented that describes the broad LAS-based techniques within the framework of remote sensing research and their directions of development for meeting potential practical use.

The rapidly changing and wide dynamic range of combustion temperature in scramjet engines presents a major challenge to existing test techniques. Tunable diode laser absorption spectroscopy (TDLAS) based temperature measurement has the advantages of high sensitivity, fast response, and compact structure. In this invited paper, a temperature measurement method based on the TDLAS technique with a single diode laser was demonstrated. A continuous-wave (CW), distributed feedback (DFB) diode laser with an emission wavelength near 1.4 ?m was used for temperature measurement, which could cover two water vapor (H2O) absorption lines located at 7153.749 cm?1 and 7154.354 cm?1 simultaneously. The output wavelength of the diode laser was calibrated according to the two absorption peaks in the time domain. Using this strategy, the TDLAS system has the advantageous of immunization to laser wavelength shift, simple system structure, reduced cost, and increased system robustness. The line intensity of the two target absorption lines under room temperature was about one-thousandth of that under high temperature, which avoided the measuring error caused by H2O in the environment. The system was tested on a McKenna flat flame burner and a scramjet model engine, respectively. It was found that, compared to the results measured by CARS technique and theoretical calculation, this TDLAS system had less than 4% temperature error when the McKenna flat flame burner was used. When a scramjet model engine was adopted, the measured results showed that such TDLAS system had an excellent dynamic range and fast response. The TDLAS system reported here could be used in real engine in the future.

The present numerical study proposes a technique to extend the sensing range of tunable diode laser absorption spectroscopy (TDLAS) for flame measurement by involving physics constraints on both gas condition and spectroscopic parameters in the interpretation of spectra from multiple bands. A total of 24 major spectral lines for 2 spectral segments 4029–4031 cm−1 and 7185–7186 cm−1 are determined by specially designed detection function and contribution filtering. Numerical tests on uniform and complicated combustion fields prove the high accuracy, strong robustness to noise, wide sensing range, and good compatibility with tomography. The present study provides a strong technique for future complex combustion detection with advanced laser sources of broad spectrum.

Antiresonant Hollow-Core Fibers (ARHCFs), thanks to the excellent capability of guiding light in an air core with low loss over a very broad spectral range, have attracted significant attention of researchers worldwide who especially focus their work on laser-based spectroscopy of gaseous substances. It was shown that the ARHCFs can be used as low-volume, non-complex, and versatile gas absorption cells forming the sensing path length in the sensor, thus serving as a promising alternative to commonly used bulk optics-based configurations. The ARHCF-aided sensors proved to deliver high sensitivity and long-term stability, which justifies their suitability for this particular application. In this review, the recent progress in laser-based gas sensors aided with ARHCFs combined with various laser-based spectroscopy techniques is discussed and summarized.

We designed a tunable diode laser absorption spectroscopy (TDLAS) sensor for the online monitoring of CO2 and H2O concentrations. It comprised a small self-design multi-pass cell, home-made laser drive circuits, and a data acquisition circuit. The optical and electrical parts and the gas circuit were integrated into a portable carrying case (height = 134 mm, length = 388 mm, and width = 290 mm). A TDLAS drive module (size: 90 mm × 45 mm) was designed to realize the function of laser current and temperature control with a temperature control accuracy of ±1.4 mK and a current control accuracy of ±0.5 μA, and signal acquisition and demodulation. The weight and power consumption of the TDLAS system were only 5 kg and 10 W, respectively. Distributed feedback lasers (2004 nm and 1392 nm) were employed to target CO2 and H2O absorption lines, respectively. According to Allan analysis, the detection limits of CO2 and H2O were 0.13 ppm and 3.7 ppm at an average time of 18 s and 35 s, respectively. The system response time was approximately 10 s. Sensor performance was verified by measuring atmospheric CO2 and H2O concentrations for 240 h. Experimental results were compared with those obtained using a commercial instrument LI-7500, which uses non-dispersive infrared technology. Measurements of the developed gas analyzer were in good agreement with those of the commercial instrument, and its accuracy was comparable. Therefore, the TDLAS sensor has strong application prospects in atmospheric CO2 and H2O concentration detection and ecological soil flux monitoring.

The development of an efficient, portable, real-time, and high-precision ammonia (NH3) remote sensor system is of great significance for environmental protection and citizens’ health. We developed a NH3 remote sensor system based on tunable diode laser absorption spectroscopy (TDLAS) technique to measure the NH3 leakage. In order to eliminate the interference of water vapor on NH3 detection, the wavelength-locked wavelength modulation spectroscopy technique was adopted to stabilize the output wavelength of the laser at 6612.7 cm−1, which significantly increased the sampling frequency of the sensor system. To solve the problem in that the light intensity received by the detector keeps changing, the 2f/1f signal processing technique was adopted. The practical application results proved that the 2f/1f signal processing technique had a satisfactory suppression effect on the signal fluctuation caused by distance changing. Using Allan deviation analysis, we determined the stability and limit of detection (LoD). The system could reach a LoD of 16.6 ppm·m at an average time of 2.8 s, and a LoD of 0.5 ppm·m at an optimum averaging time of 778.4 s. Finally, the measurement result of simulated ammonia leakage verified that the ammonia remote sensor system could meet the need for ammonia leakage detection in the industrial production process.

The application of oxygen sensors based on Tunable Diode Laser Absorption Spectroscopy (TDLAS) in the industrial field has received extensive attention. However, most of the existing studies construct detection systems using discrete devices, making it difficult to apply them in the industrial field. In this work, through the optimization of the sensor circuit, the size of the core components of the sensor is reduced to 7.8 × 7.8 × 11.8 cm3, integrating the laser, photodetector, and system control circuit. A novel integrated optical path design is proposed for the optical mechanical structure, which enhances the structural integration and long-term optical path stability while reducing the system assembly complexity. The interlocking design of the laser-driven digital-to-analog converter (DAC) and photocurrent acquisition analog-to-digital converter (ADC) reduces the requirements of the harmonic signal extraction for the system hardware. By adopting a high-precision ADC and a high-resolution pulse-width modulation (PWM), the peak-to-peak value of the laser temperature control noise is reduced to 2 m°C, thereby reducing the detection noise of the sensor. This oxygen detection system has a minimum response time of 0.1 s. Under the condition of a 0.5 m detection optical path, the Allan variance shows that when the integration time is 5.6 s, the detection limit reaches 53.4 ppm, which is ahead of the detection accuracy of similar equipment under the very small system size.

The vast majority of gaseous chemical substances exhibit fundamental rovibrational absorption bands in the mid-infrared spectral region (2.5–25 μm), and the absorption of light by these fundamental bands provides a nearly universal means for their detection. A main feature of optical techniques is the non-intrusive in situ detection of trace gases. We reviewed primarily mid-infrared tunable laser-based broadband absorption spectroscopy for trace gas detection, focusing on 2008–2018. The scope of this paper is to discuss recent developments of system configuration, tunable lasers, detectors, broadband spectroscopic techniques, and their applications for sensitive, selective, and quantitative trace gas detection.