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12,160 result(s) for "light-emitting diode (LED)"
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Organic–Inorganic Hybrid Cuprous‐Based Metal Halides for Warm White Light‐Emitting Diodes
Single‐component emitters with stable and bright warm white‐light emission are highly desirable for high‐efficacy warm white light‐emitting diodes (warm‐WLEDs), however, materials with such luminescence properties are extremely rare. Low­dimensional lead (Pb) halide perovskites can achieve warm white photoluminescence (PL), yet they suffer from low stability and PL quantum yield (PLQY). While Pb‐free air‐stable perovskites such as Cs2AgInCl6 emit desirable warm white light, sophisticated doping strategies are typically required to increase their PL intensity. Moreover, the use of rare metal‐bearing compounds along with the typically required vacuum‐based thin‐film processing may greatly increase their production cost. Herein, organic–inorganic hybrid cuprous (Cu+)‐based metal halide MA2CuCl3 (MA = CH3NH3+) that meets the requirements of i) nontoxicity, ii) high PLQY, and iii) dopant‐free is presented. Both single crystals and thin films of MA2CuCl3 can be facilely prepared by a low‐cost solution method, which demonstrate bright warm white‐light emission with intrinsically high PLQYs of 90–97%. Prototype electroluminescence devices and down‐conversion LEDs are fabricated with MA2CuCl3 thin films and single crystals, respectively, which show bright luminescence with decent efficiencies and operational stability. These findings suggest that MA2CuCl3 has a great potential for the single‐component indoor lighting and display applications. The newly developed hybrid MA2CuCl3 meets the requirements of i) broadband warm white‐light emission, ii) nontoxicity, iii) high photoluminescence quantum yield, iv) dopant‐free, v) low‐cost, and vi) excellent film‐forming ability. Besides, the first successful electroluminescence application of MA2CuCl3 opens a new avenue toward single‐component warm white light‐emitting diodes.
Optical Wireless Power Transfer for Implanted and Wearable Devices
Optical wireless power transfer (OWPT) has been employed in the literature as a wireless powering approach for implanted and wearable devices. However, most of the existing studies on this topic have not studied the performances of OWPT systems when light is transmitted through clothing. This research therefore contributes to investigate the effects of clothing on OWPT performances from both theoretical and experimental perspectives. An obtained experimental result indicates that a single light-emitting diode (LED) transmitter is able to perform the OWPT through white cotton clothing, but failed with another dark cotton clothing, even at a small transmitting distance. Hence, this research proposes to employ LED arrays as optical transmitters to improve the OWPT system capability in terms of the wirelessly transmitted power, transmitting distance and system tolerance to misalignments, whilst keeping the system safety, low cost and simplicity. Consequently, a theoretical formula for the power transmission efficiency made by an LED array through clothing is proposed and then is verified with experimental results. Furthermore, the important role of multiple light reflections at the surfaces of clothing and the LED array transmitter is pointed out.
Advances in Quantum-Dot-Based Displays
In terms of their use in displays, quantum dots (QDs) exhibit several advantages, including high illumination efficiency and color rendering, low-cost, and capacity for mass production. Furthermore, they are environmentally friendly. Excellent luminescence and charge transport properties of QDs led to their application in QD-based light-emitting diodes (LEDs), which have attracted considerable attention in display and solid-state lighting applications. In this review, we discuss the applications of QDs which are used on color conversion filter that exhibit high efficiency in white LEDs, full-color micro-LED devices, and liquid-type structure devices, among others. Furthermore, we discuss different QD printing processes and coating methods to achieve the full-color micro-LED. With the rise in popularity of wearable and see-through red, green, and blue (RGB) full-color displays, the flexible substrate is considered as a good potential candidate. The anisotropic conductive film method provides a small controllable linewidth of electrically conductive particles. Finally, we discuss the advanced application for flexible full-color and highly efficient QD micro-LEDs. The general conclusion of this study also involves the demand for a more straightforward QD deposition technique, whose breakthrough is expected.
Blue LED causes autophagic cell death in human osteosarcoma by increasing ROS generation and dephosphorylating EGFR
Osteosarcoma (OS) is the most common primary malignant bone tumour in adolescence. Lately, light‐emitting diodes (LED)‐based therapy has emerged as a new promising approach for several diseases. However, it remains unknown in human OS. Here, we found that the blue LED irradiation significantly suppressed the proliferation, migration and invasion of human OS cells, while we observed blue LED irradiation increased ROS production through increased NADPH oxidase enzymes NOX2 and NOX4, as well as decreased Catalase (CAT) expression levels. Furthermore, we revealed blue LED irradiation‐induced autophagy characterized by alterations in autophagy protein markers including Beclin‐1, LC3‐II/LC3‐I and P62. Moreover, we demonstrated an enhanced autophagic flux. The blockage of autophagy displayed a remarkable attenuation of anti‐tumour activities of blue LED irradiation. Next, ROS scavenger N‐acetyl‐L‐cysteine (NAC) and NOX inhibitor diphenyleneiodonium (DPI) blocked suppression of OS cell growth, indicating that ROS accumulation might play an essential role in blue LED‐induced autophagic OS cell death. Additionally, we observed blue LED irradiation decreased EGFR activation (phosphorylation), which in turn led to Beclin‐1 release and subsequent autophagy activation in OS cells. Analysis of EGFR colocalization with Beclin‐1 and EGFR‐immunoprecipitation (IP) assay further revealed the decreased interaction of EGFR and Beclin‐1 upon blue LED irradiation in OS cells. In addition, Beclin‐1 down‐regulation abolished the effects of blue LED irradiation on OS cells. Collectively, we concluded that blue LED irradiation exhibited anti‐tumour effects on OS by triggering ROS and EGFR/Beclin‐1‐mediated autophagy signalling pathway, representing a potential approach for human OS treatment.
Strategies for Designing Antithermal‐Quenching Red Phosphors
Nowadays, red phosphor plays a key role in improving the lighting quality and color rendering index of phosphor‐converted white light emitting diodes (w‐LEDs). However, the development of thermally stable and highly efficient red phosphor is still a pivotal challenge. Herein, a new strategy to design antithermal‐quenching red emission in Eu3+, Mn4+‐codoped phosphors is proposed. The photoluminescence intensity of Mg3Y2(1−y)Ge3O12:yEu3+, Mn4+ (0 ≤ y ≤ 1) phosphors continuously enhances with rising temperature from 298 to 523 K based on Eu3+ → Mn4+ energy transfer. For Mg3Eu2Ge3O12:Mn4+ sample, the integrated intensity at 523 K remarkably reaches 120% of that at 298 K. Interestingly, through codoping Eu3+ and Mn4+ in Mg3Y2Ge3O12, the photoluminescence color is controllably tuned from orangish‐red (610 nm) to deep‐red (660 nm) light by changing Eu3+ concentration. The fabricated w‐LEDs exhibit superior warm white light with low corrected color temperature (CCT = 4848 K) and high color rendering index (Ra = 96.2), indicating the promising red component for w‐LED applications. Based on the abnormal increase in antistokes peaks of Mn4+ with temperatures, Mg3Eu2Ge3O12:Mn4+ phosphor also presents a potential application in optical thermometry sensors. This work initiates a new insight to construct thermally stable and spectra‐tunable red phosphors for various optical applications. A proposal for designing antithermal‐quenching red phosphors with consecutive emission enhancement (beyond 120%) up to 523 K and controllably luminescence color adjustment from orange to deep red light based on Eu3+ → Mn4+ energy transfer for potential application in white light emitting diodes and optical low‐temperature thermometry sensors is presented.
Effect of irradiating the leaf abaxial surface with supplemental light‐emitting diode lights on grape photosynthesis
Background and Aims In southern China, where the solar radiation is insufficient for optimised grapevine growth, supplemental light sources are being used. The aim of the present study was to assess the practicability of light‐emitting diode (LED) light as a supplemental light source to improve grape photosynthesis and berry composition. Methods and Results The leaf abaxial surface (Ab) of cv. Summer Black grapevines was illuminated by red, blue and compound LED light strips. In most cases, the net photosynthetic rate (Pn) of the light‐treated plants was typically higher than that of the untreated Control (CK) on sunny and rainy days in all stages. Blue light promoted the Pn of the leaf adaxial surface (Ad), whereas red light promoted the Pn of Ab, and the effect of compound light was moderate. The light response curve on the Ad showed that blue and compound light can facilitate the use of high light by the grape leaf. The CO2 response curve indicated that leaves supplemented with blue light have a significantly advantageous CO2 assimilation. Grapes supplemented with compound and red light had a berry mass higher than that of the Control, whereas grapes supplemented with blue and compound light had improved berry composition. Conclusions Blue and compound LED irradiation increased leaf photosynthetic capacity and improved fruit composition, whereas red and compound LED irradiation increased berry mass. Significance of the Study The supplemental LED lights significantly optimised the light environment and improved photosynthesis and the composition of grape in southern China.
Effect of Artificial LED Light and Far Infrared Irradiation on Phenolic Compound, Isoflavones and Antioxidant Capacity in Soybean (Glycine max L.) Sprout
The effect of light emitting diode (LED) light and far infrared irradiation (FIR) on total phenol, isoflavones and antioxidant activity were investigated in soybean (Glycine max L.) sprout. Artificial blue (470 nm), green (530 nm) LED and florescent light (control) were applied on soybean sprout, from three to seven days after sowing (DAS) in growth chamber. The photosynthetic photon flux density (PPFD) and photoperiod was 150 ± 5 μmol m−2s−1 and 16 h, respectively. The FIR was applied for 30, 60 and 120 min at 90, 110 and 130 °C on harvested sprout. Total phenolic content (TP) (59.81 mg/g), antioxidant capacity (AA: 75%, Ferric Reduction Antioxidant Power (FRAP): 1357 µM Fe2+) and total isoflavones content (TIC) (51.1 mg/g) were higher in blue LED compared to control (38.02 mg/g, 58%, 632 µM Fe2+ and 30.24 mg/g, respectively). On the other hand, TP (64.23 mg/g), AA (87%), FRAP (1568 µM Fe2+) and TIC (58.98 mg/g) were significantly increased by FIR at 110 °C for 120 min among the treatments. Result suggests that blue LED is the most suitable light to steady accumulation of secondary metabolites (SM) in growing soybean sprout. On the other hand, FIR at 110 °C for 120 min is the best ailment to induce SM in proceed soybean sprout.
Antioxidative and Mitochondrial Protection in Retinal Pigment Epithelium: New Light Source in Action
Low-color-temperature light-emitting diodes (LEDs) (called 1900 K LEDs for short) have the potential to become a healthy light source due to their blue-free property. Our previous research demonstrated that these LEDs posed no harm to retinal cells and even protected the ocular surface. Treatment targeting the retinal pigment epithelium (RPE) is a promising direction for age-related macular degeneration (AMD). Nevertheless, no study has evaluated the protective effects of these LEDs on RPE. Therefore, we used the ARPE-19 cell line and zebrafish to explore the protective effects of 1900 K LEDs. Our results showed that the 1900 K LEDs could increase the cell vitality of ARPE-19 cells at different irradiances, with the most pronounced effect at 10 W/m2. Moreover, the protective effect increased with time. Pretreatment with 1900 K LEDs could protect the RPE from death after hydrogen peroxide (H2O2) damage by reducing reactive oxygen species (ROS) generation and mitochondrial damage caused by H2O2. In addition, we preliminarily demonstrated that irradiation with 1900 K LEDs in zebrafish did not cause retinal damage. To sum up, we provide evidence for the protective effects of 1900 K LEDs on the RPE, laying the foundation for future light therapy using these LEDs.
Light-Emitting-Diode-Assisted, Fungal-Pigment-Mediated Biosynthesis of Silver Nanoparticles and Their Antibacterial Activity
Nanoparticle synthesis, such as green synthesis of silver nanoparticles (AgNPs) using biogenic extracts, is affected by light, which changes the characteristics of particles. However, the effect of light-emitting diodes (LEDs) on AgNP biosynthesis using fungal pigment has not been examined. In this study, LEDs of different wavelengths were used in conjunction with Talaromyces purpurogenus extracellular pigment for AgNP biosynthesis. AgNPs were synthesized by mixing 10 mL of fungal pigment with AgNO3, followed by 24 h exposure to LEDs of different wavelengths, such as blue, green, orange, red, and infrared. All treatments increased the yield of AgNPs. The solutions exposed to blue, green, and infrared LEDs exhibited a significant increase in AgNP synthesis. All AgNPs were then synthesized to determine the optimum precursor (AgNO3) concentration and reaction rate. The results indicated 5 mM AgNO3 as the optimum precursor concentration; furthermore, AgNPs-blue LED had the highest reaction rate. Dynamic light scattering analysis, zeta potential measurement, transmission electron microscopy, and Fourier transform infrared spectroscopy were used to characterize the AgNPs. All LED-synthesized AgNPs exhibited an antimicrobial potential against Escherichia coli and Staphylococcus aureus. The combination of LED-synthesized AgNPs and the antibiotic streptomycin demonstrated a synergistic antimicrobial activity against both bacterial species.
Synthesis and optical properties of GdVO4: Eu3+ phosphor
In the present work, we have synthesized GdVO4 doped Eu3+ using a facile sol-gel method and analysed the effect of concentration variation and annealing temperature on the optical properties. Tetragonal (I41/amd) zircon type crystal structure of the material was confirmed by x-ray diffraction (XRD) study. The photoluminescence (PL) spectra were recorded with an ultraviolet (UV) excitation of wavelength 325 nm. GdVO4 doped Eu3+ (1 mol%) gives prominent red emission. This optimized sample was annealed at different temperature and as annealing temperature raises, the crystallinity of the material increases resulting in the improved emission intensity. The emission spectra of this phosphor exhibit intense peaks at wavelengths 593 nm (orange) and 618 nm (red) which corresponds to 5D0-7F1, 5D0 -7F2 transitions of Eu3+ ions. 5D0 -7F2, the electric dipole transition is dominant indicating that Eu3+ ions situated at a non-centrosymmetric site in the crystal structure. GdVO4: Eu3+(1 mol%) annealed at 800 °C gives eminent red emission which can be further used as the potential candidate for bioimaging, lighting, temperature sensing and display devices.