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As more economies are transitioning away from fossil fuels for their electricity production and towards greener alternatives, many socioeconomic implications of this shift remain actively debated. The present paper attempts to assess the economic impact of investments in renewable energy sources (RESs) for Greece and whether the broader effects of this transition can offset the negative impact that will occur due to the targeted phase-out of lignite plants by 2028, which constitute the predominant power source for Greece. Our methodological approach builds on input–output analysis and the creation of composite RES industries for the estimation of the net effects of a series of monetary shocks that correspond to Greece’s phase-out investment plan, utilizing the most recent national input–output tables and satellite structural business statistics. We focus on the structural effects of these shocks on a series of socioeconomic indicators, including GDP, employment, wages, government income (through taxes), and capital formation. The results indicate that even though lignite power production still provides a significant contribution to the Greek economy, investing in renewables presents a significant opportunity for value added and job creation.

As part of the European Green Deal, the EU aims to become climate-neutral and reach net-zero greenhouse gas emissions by 2050. Ιn this context, EU member states are required to develop a national strategy to achieve the required emissions reductions under the Paris Agreement and EU climate goals. Western Macedonia is a region in North-western Greece with its economy largely dominated by lignite mining, lignite-fired power plants and district heating systems. In 2019, the Greek Government set the goal of withdrawing all lignite plants by 2028, with most units being withdrawn already by 2023. This decision has had an immense socio-economic impact on the region of Western Macedonia. This research work reflects the current situation at the socio-economic and socio-political level in Western Macedonia and discusses the policies implemented in the context of the lignite phase-out process to ensure a just transition for households and businesses of the region. Although there is not a ‘one-size-fits-all’ blueprint for successful low-carbon transitions of high-carbon intensive regional economies, the main target of our paper is understanding the impacts, challenges and opportunities of decarbonizing Western Macedonia.

The establishment of sustainable energy frameworks amidst global climate change and dwindling petroleum reserves has prompted a focus on energy transition, marking a shift in how energy is utilized within systems. Greece, historically reliant on lignite for electricity generation, faces the challenge of transitioning towards a low-carbon economy. This study explores the potential of creating a multipurpose entrepreneurship and culture center, the Mediterranean Center for Entrepreneurship and Culture (MCEC), in Megalopolis, Arcadia, Greece, as a strategic intervention for economic, social, and environmental restructuring. Drawing on best practices and comprehensive analyses of external factors, the study outlines the conceptualization and evaluation of the MCEC, considering economic feasibility, development scenarios, financial sustainability, and stakeholder engagement. The discussion highlights the anticipated benefits of the MCEC, including job creation, entrepreneurship promotion, and socio-cultural advancement, underscoring its potential to mitigate the impacts of lignite phase-out and foster sustainable regional development. Overall, the establishment of the MCEC is poised to yield positive socio-economic impacts, including employment growth, entrepreneurship promotion, infrastructure development, and cultural enrichment, contributing to the resilience and prosperity of the Megalopolis region and beyond.

The European Green Deal envisages a clean and decarbonised energy sector with net-zero greenhouse gas emissions by 2050. These ambitious objectives entrust the Member States with enormous tasks in connection with the transformation process, which must always be designed in a proportionate manner. For this purpose, compensation measures are regularly part of decarbonisation strategies. In the context of the German lignite phase-out, new legal challenges arise due to State aid law. In particular, the present case poses the question of how elements of settlement agreements are to be assessed under State aid law. This field currently seems to be almost unexplored, as the Commission’s notice on the notion of State aid only refers to settlement agreements in connection with tax law. However, settlement agreements contain some important elements that should be properly taken into account by the Commission in its State aid assessment. The fact that settlement agreements serve to avoid legal and factual uncertainties, especially in the context of highly complex decarbonisation strategies, must play a decisive role in an all-embracing economic analysis.

Co-fermentation of lignite and biomass has been considered as a new approach in achieving clean energy. Moreover, the study of the characteristics of solid phase in the synergistic degradation process is of great significance in revealing their synergistic relationship. Accordingly, in order to produce biogas, lignite, straw, and the mixture of the two were used as the substrates, the solid phase characteristics of which were analyzed before and after fermentation using modern analytical methods. The results revealed that the mixed fermentation of lignite and straw promoted the production of biomethane. Moreover, the ratios of C/O and C/H were found to be complementary in the co-fermentation process. Furthermore, while the relative content of C-C/C-H bonds was observed to be significantly decreased, the aromatics degree of lignite was weakened. Also, while the degree of branching increased, there found to be an increase in the content of cellulose amorphous zone, which, consequently, led to an increase in the crystallinity index of the wheat straw. Hence, the results provide a theoretical guidance for the efficient utilization of straw and lignite.

The capabilities of temperature-monitored IR spectroscopy for studying the organic matter and mineral composition of humic substances (HS) were tested. Temperature dependences of the mid-IR spectra of humic substances heated in the air in the range 25–215 °C (298–488 K, with a step of 2.5 °C)—for three commercially available samples isolated from brown coal (leonardite)—were performed. The characteristic bands were identified, and their changes in band maxima positions and intensities were compared. From the viewpoint of interpretation of HS components, the spectra were divided into regions of quartz lattice region (800–260 cm−1), quartz overtone region (1270–800 cm−1), humic substance organic matter region (1780–1270 cm−1), quartz combination region (2800–1780 cm−1), CH-speciation region (3100–2800 cm−1), and hydrogen-speciation region (4000–3100 cm−1) thus selected to contain the dominating type of bands. For the first time, a reversible change in the frequencies of the band maxima in IR spectra upon heating was observed, which can be interpreted as forming structures with a particular order in the studied humic substances in the dry state. For a single sample, both the band-shift scale and the functional dependence of the various bands on temperature differ significantly. The approach differentiates crystalline quartz bands, amorphous silica, and HSOM/surface groups experiencing a different temperature behavior of the band maxima and their intensities. Band-maximum temperature dependence can be considered more stable to changes in experimental conditions than band maxima at a single temperature, thus providing a more detailed HS structure analysis without HS decomposition or destruction.

Fly ash (FA) from lignite coal combusted in different Thermal Power Plants (TPPs) was used for the synthesis of zeolites (FAZs) of the Na-X type by alkaline activation via three laboratory procedures. FAZs were characterized with respect to their morphology, phase composition and surface properties, which predetermine their suitability for applications as catalysts and adsorbents. FAZs were subsequently modified with metal oxides (CuO) to improve their catalytic properties. The catalytic activity of non-modified and CuO-modified FAZs in the total oxidation of volatile organic compounds was investigated. FAZs were studied for their potential to retain CO2, as their favorable surface characteristics and the presence of iron oxides make them suitable for carbon capture technologies. Thin films of FAZs were deposited by in situ crystallization, and investigated for their morphology and optical sensitivity when exposed to pollutants in the gas phase, e.g., acetone. This study contributes to the development of novel technological solutions for the smart and valuable utilization of FA in the context of the circular economy and green energy production.

Coal spontaneous combustion (CSC) is one of the main disasters in the process of coal mining. In this paper, the important role of high-latent heat phase change material CH 3 COONa·3H 2 O (SAT) in controlling CSC was studied and compared with common inhibitors (NaCl, CaCl 2 , ascorbic acid (VC)). The thermal performance characteristics of SAT were revealed by the C80 micromanometer, and the effects of different inhibitors on the thermal behavior of Shengli lignite were analyzed and compared. Furthermore, the gas–solid coaxial fixed bed measurement system was used in conjunction with the Pfeiffer online mass spectrometer, to design the natural temperature rise experiment of coal after the heating interruption in the same programmed temperature rise interval, investigating the effects of different inhibitors on the temperature and gas production in the process of coal oxidation. The results show that the heat absorption effect of SAT is more significant than common inhibitors, which not only improves the heat absorption rate of the samples but also increases the total heat absorption of the sample by 236.6 J·g −1 compared with the raw coal. In the programmed temperature rise experiment, the maximum temperature point of the SAT-inhibited coal sample is reduced by 15.5% compared with raw coal, the time to reach the maximum temperature point is delayed by 20.5%, and the SAT inhibitor effectively inhibits the production of CO and CO 2 gases. The method described in this paper provides a new idea for the prevention and control of CSC.

The article describes chemical and also selected physical properties of ponded high temperature fly ash (FA) and bottom ash (BA) from a Mělník lignite power plant located in the Czech Republic. The research was carried out on samples obtained from drills with a depth of up to 54 m and the age of the samples retrieved from the lowest layers of the stockpile dating back to 1960. At the same time, a comparison was made with fresh fly ash and fresh bottom ash obtained from the identical power plant. The study analyzed a total of 98 stockpile samples. The properties selected were studied across the entire stockpile, namely moisture content, specific density, specific surface, carbon content, elemental and phase composition, pH, electrical conductivity and leachability. SEM analyses were also performed. The performed measurements of chemical properties proved the chemical stability of the material even after several decades of storage in the stockpile. The largest changes are evident in the results of the analyses related to the leachability of SO3, Cl− and F−. In contrast, the pH does not change significantly, and the composition is pH neutral or alkaline. Regarding ponded BA, particle disintegration was noted depending on the increasing core borehole depth.

The purpose of this study is to synthesize geopolymer binders as an environmentally friendly alternative to conventional cement using available local raw materials. Waste materials such as chalcedonite (Ch), amphibolite (A), fly ash from lignite combustion (PB), and diatomite dust (D) calcined at 900 °C were used to produce geopolymer binders. Metakaolin (M) was used as an additional modifier for binders based on waste materials. The base materials were subjected to fluorescence X-ray fluorescence (XRF) analysis and X-ray diffractometry (XRD) to determine chemical and phase composition. A laser particle size analysis was also performed. The various mixtures of raw materials were activated with a 10 M solution of NaOH and sodium water glass and then annealed for 24 h at 60 °C. The produced geopolymer binders were conditioned for 28 days under laboratory conditions and then subjected to microstructural analysis (SEM) and flexural and compressive strength tests. The best compressive strength results were obtained by the Ch + PB samples—more than 57 MPa, while the lowest results were obtained by the Ch + D+A + M samples—more than 20 MPa. On the other hand, as a result of the flexural strength tests, the highest flexural results were obtained by D + A + M + PB binders—more than 12 MPa, and the lowest values were obtained by binders based on Ch + D+A + M—about 4.8 MPa.