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Melt inclusion data from primitive arc basalts from Mexico and Kamchatka show clear positive correlations of \"fluid mobile element\"/H2O ratios with the Cl/H2O ratio, suggesting that the trace element content of subduction zone fluids is strongly enhanced by complexing with chloride. This effect is observed for large-ion lithophile (LILE) elements, (e.g., Rb and Sr), but also for the light rare earth elements (REE, e.g., La and Ce) as well as for U. The correlations of these elements with Cl/H2O cannot be explained by the addition of sediment melts or slab melts to the mantle source, since Cl has no effect on the solubility or partitioning of these elements in silicate melt systems. On the other hand, the observed relationship of trace element abundance with Cl is consistent with a large body of experimental data showing greatly enhanced partitioning into aqueous fluid upon addition of chloride. Accordingly, it appears that a dilute, Cl-bearing aqueous fluid is the main carrier of LILE, light REE, and U from the slab to the source of melting in arcs. Moreover, elevated Ce/H2O ratios clearly correlate with fluid salinity and therefore are not suitable as a \"slab geothermometer\". From a synopsis of experimental and melt inclusion data, it is suggested that the importance of sediment or slab melting in the generation of arc magmas is likely overestimated, while the effects of trace element scavenging from the mantle wedge may be underestimated. Moreover, establishing reliable data sets for the fluid/mineral partition coefficients of trace elements as a function of pressure, temperature, and salinity requires additional efforts, since most of the commonly used experimental strategies have severe drawbacks and potential pitfalls.

The effects of the hydration mechanism on continental crust recycling are analyzed through a 2‐D finite element thermomechanical model. Oceanic slab dehydration and consequent mantle wedge hydration are implemented using a dynamic method. Hydration is accomplished by lawsonite and serpentine breakdown; topography is treated as a free surface. Subduction rates of 1, 3, 5, 7.5, and 10 cm/yr; slab angles of 30°, 45°, and 60°; and a mantle rheology represented by dry dunite and dry olivine flow laws have been taken into account during successive numerical experiments. Model predictions pointed out that a direct relationship exists between mantle rheology and the amount of recycled crustal material: the larger the viscosity contrast between hydrated and dry mantle, the larger the percentage of recycled material into the mantle wedge. Slab dip variation has a moderate impact on the recycling. Metamorphic evolution of recycled material is influenced by subduction style. TPmax, generally representative of eclogite facies conditions, is sensitive to changes in slab dip. A direct relationship between subduction rate and exhumation rate results for different slab dips; this relationship does not depend on the used mantle flow law. Thermal regimes predicted by different numerical models are compared to PT paths followed by continental crustal slices involved in ancient and recent subduction zones, making ablative subduction a suitable precollisional mechanism for burial and exhumation of continental crust.

Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ26Mg of the Martinique Island lavas varies from −0.25 to −0.10, in contrast to the narrow range that characterizes the mantle (−0.25 ± 0.04, 2 SD). These high δ26Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid–mantle interaction. This, in turn, suggests transfer of a large amount of fluidmobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration.

The roles of subduction of the Pacific plate and the big mantle wedge (BMW) in the evolution of east Asian continental margin have attracted lots of attention in past years. This paper reviews recent progresses regarding the composition and chemical heterogeneity of the BMW beneath eastern Asia and geochemistry of Cenozoic basalts in the region, with attempts to put forward a general model accounting for the generation of intraplate magma in a BMW system. Some key points of this review are summarized in the following. (1) Cenozoic basalts from eastern China are interpreted as a mixture of high-Si melts and low-Si melts. Wherever they are from, northeast, north or south China, Cenozoic basalts share a common low-Si basalt endmember, which is characterized by high alkali, Fe 2 O 3 T and TiO 2 contents, HIMU-like trace element composition and relatively low 206 Pb/ 204 Pb compared to classic HIMU basalts. Their Nd-Hf isotopic compositions resemble that of Pacific Mantle domain and their source is composed of carbonated eclogites and peridotites. The high-Si basalt endmember is characterized by low alkali, Fe 2 O 3 T and TiO 2 contents, Indian Mantle-type Pb-Nd-Hf isotopic compositions, and a predominant garnet pyroxenitic source. High-Si basalts show isotopic provinciality, with those from North China and South China displaying EM1-type and EM2-type components, respectively, while basalts from Northeast China containing both EM1- and EM2-type components. (2) The source of Cenozoic basalts from eastern China contains abundant recycled materials, including oceanic crust and lithospheric mantle components as well as carbonate sediments and water. According to their spatial distribution and deep seismic tomography, it is inferred that the recycled components are mostly from stagnant slabs in the mantle transition zone, whereas EM1 and EM2 components are from the shallow mantle. (3) Comparison of solidi of garnet pyroxenite, carbonated eclogite and peridotite with regional geotherm constrains the initial melting depth of high-Si and low-Si basalts at <100 km and ∼300 km, respectively. It is suggested that the BMW under eastern Asia is vertically heterogeneous, with the upper part containing EM1 and EM2 components and isotopically resembling the Indian mantle domain, whereas the lower part containing components derived from the Pacific mantle domain. Contents of H 2 O and CO 2 decrease gradually from bottom to top of the BMW. (4) Melting of the BMW to generate Cenozoic intraplate basalts is triggered by decarbonization and dehydration of the slabs stagnated in the mantle transition zone.

The transport of water from subducting crust into the mantle is mainly dictated by the stability of hydrous minerals in subduction zones. The thermal structure of subduction zones is a key to dehydration of the subducting crust at different depths. Oceanic subduction zones show a large variation in the geotherm, but seismicity and arc volcanism are only prominent in cold subduction zones where geothermal gradients are low. In contrast, continental subduction zones have low geothermal gradients, resulting in metamorphism in cold subduction zones and the absence of arc volcanism during subduction. In very cold subduction zone where the geothermal gradient is very low（？5？C/km）, lawsonite may carry water into great depths of ？300 km. In the hot subduction zone where the geothermal gradient is high（25？C/km）, the subducting crust dehydrates significantly at shallow depths and may partially melt at depths of 80 km to form felsic melts, into which water is highly dissolved. In this case, only a minor amount of water can be transported into great depths. A number of intermediate modes are present between these two end-member dehydration modes, making subduction-zone dehydration various. Low-T/low-P hydrous minerals are not stable in warm subduction zones with increasing subduction depths and thus break down at forearc depths of ？60–80 km to release large amounts of water. In contrast, the low-T/low-P hydrous minerals are replaced by low-T/high-P hydrous minerals in cold subduction zones with increasing subduction depths, allowing the water to be transported to subarc depths of 80–160 km. In either case, dehydration reactions not only trigger seismicity in the subducting crust but also cause hydration of the mantle wedge. Nevertheless, there are still minor amounts of water to be transported by ultrahigh-pressure hydrous minerals and nominally anhydrous minerals into the deeper mantle. The mantle wedge overlying the subducting slab does not partially melt upon water influx for volcanic arc magmatism, but it is hydrated at first with the lowest temperature at the slab-mantle interface, several hundreds of degree lower than the wet solidus of hydrated peridotites. The hydrated peridotites may undergo partial melting upon heating at a later time. Therefore, the water flux from the subducting crust into the overlying mantle wedge does not trigger the volcanic arc magmatism immediately.

The Circum-Pacific subduction zone is a famous gold metallogenic domain in the world, with two important gold metallogenic provinces, the North China Craton and Nevada, which are related to the destruction of the North China Craton and the Wyoming Craton, respectively. Their ore-forming fluids were possibly derived from the stagnant slab in the mantle transition zone. The oceanic lithospheric mantle usually contains serpentine layers up to thousands of meters thick. During plate subduction, serpentine is dehydrated at depths of <200 km and transformed into high-pressure hydrous minerals, known as Phases A to E, which carries water to the depth of >300 km. The overlying big mantle wedge is hydrated during the breakdown of these hydrous facies in the mantle transition zone. The dehydration of the subducted slab in the big mantle wedge releases sulfur-rich fluid, which extracts gold and other chalcophile elements in the surrounding rocks, forming gold-rich fluid. Because the cratonic geotherm is lower than the water-saturated solidus line of lherzolite, the fluid cannot trigger partial melting. Instead, it induces metasomatism and forms pargasite and other water-bearing minerals when it migrates upward to depths of less than 100 km in the cratonic lithospheric mantle, resulting in a water- and gold-rich weak layer. During the destruction of craton, the weak layer is destabilized, releasing gold-bearing fluids that accelerate the destruction. The ore-forming fluids migrate along the shallow weak zone and are accumulated at shallow depths, and subsequently escape along deep faults during major tectonic events, leading to explosive gold mineralization. The ore-forming fluids are rich in ferrous iron, which releases hydrogen at low pressure through iron hydrolysis. Therefore, decratonic gold deposits are often reduced deposits.

High-resolution P wave tomography shows that the subducting Pacific slab is stagnant in the mantle transition zone and forms a big mantle wedge beneath eastern China. The Mg isotopic investigation of large numbers of mantle-derived volcanic rocks from eastern China has revealed that carbonates carried by the subducted slab have been recycled into the upper mantle and formed carbonated peridotite overlying the mantle transition zone, which becomes the sources of various basalts. These basalts display light Mg isotopic compositions ( δ 26 Mg =–0.60‰ to –0.30‰) and relatively low 87 Sr/ 86 Sr ratios (0.70314–0.70564) with ages ranging from 106 Ma to Quaternary, suggesting that their mantle source had been hybridized by recycled magnesite with minor dolomite and their initial melting occurred at 300−360 km in depth. Therefore, the carbonate metasomatism of their mantle source should have occurred at the depth larger than 360 km, which means that the subducted slab should be stagnant in the mantle transition zone forming the big mantle wedge before 106 Ma. This timing supports the rollback model of subducting slab to form the big mantle wedge. Based on high P-T experiment results, when carbonated silicate melts produced by partial melting of carbonated peridotite was raising and reached the bottom (180–120 km in depth) of cratonic lithosphere in North China, the carbonated silicate melts should have 25–18 wt% CO 2 contents, with lower SiO 2 and Al 2 O 3 contents, and higher CaO/Al 2 O 3 values, similar to those of nephelinites and basanites, and have higher ε Nd values (2 to 6). The carbonatited silicate melts migrated upward and metasomatized the overlying lithospheric mantle, resulting in carbonated peridotite in the bottom of continental lithosphere beneath eastern China. As the craton lithospheric geotherm intersects the solidus of carbonated peridotite at 130 km in depth, the carbonated peridotite in the bottom of cratonic lithosphere should be partially melted, thus its physical characters are similar to the asthenosphere and it could be easily replaced by convective mantle. The newly formed carbonated silicate melts will migrate upward and metasomatize the overlying lithospheric mantle. Similarly, such metasomatism and partial melting processes repeat, and as a result the cratonic lithosphere in North China would be thinning and the carbonated silicate partial melts will be transformed to high-SiO 2 alkali basalts with lower ε Nd values (to −2). As the lithospheric thinning goes on, initial melting depth of carbonated peridotite must decrease from 130 km to close 70 km, because the craton geotherm changed to approach oceanic lithosphere geotherm along with lithospheric thinning of the North China craton. Consequently, the interaction between carbonated silicate melt and cratonic lithosphere is a possible mechanism for lithosphere thinning of the North China craton during the late Cretaceous and Cenozoic. Based on the age statistics of low δ 26 Mg basalts in eastern China, the lithospheric thinning processes caused by carbonated metasomatism and partial melting in eastern China are limited in a timespan from 106 to 25 Ma, but increased quickly after 25 Ma. Therefore, there are two peak times for the lithospheric thinning of the North China craton: the first peak in 135−115 Ma simultaneously with the cratonic destruction, and the second peak caused by interaction between carbonated silicate melt and lithosphere mainly after 25 Ma. The later decreased the lithospheric thickness to about 70 km in the eastern part of North China craton.

We present the first detailed 2D seismic tomographic image of the trench‐outer rise, fore‐ and back‐arc of the Tonga subduction zone. The study area is located approximately 100 km north of the collision between the Louisville hot spot track and the overriding Indo‐Australian plate where ∼80 Ma old oceanic Pacific plate subducts at the Tonga Trench. In the outer rise region, the upper oceanic plate is pervasively fractured and most likely hydrated as demonstrated by extensional bending‐related faults, anomalously large horst and graben structures, and a reduction of both crustal and mantle velocities. The 2D velocity model presented shows uppermost mantle velocities of ∼7.3 km/s, ∼10% lower than typical for mantle peridotite (∼30% mantle serpentinization). In the model, Tonga arc crust ranges between 7 and 20 km in thickness, and velocities are typical of arc‐type igneous basement with uppermost and lowermost crustal velocities of ∼3.5 and ∼7.1 km/s, respectively. Beneath the inner trench slope, however, the presence of a low velocity zone (4.0–5.5 km/s) suggests that the outer fore‐arc is probably fluid‐saturated, metamorphosed and disaggregated by fracturing as a consequence of frontal and basal erosion. Tectonic erosion has, most likely, been accelerated by the subduction of the Louisville Ridge, causing crustal thinning and subsidence of the outer fore‐arc. Extension in the outer fore‐arc is evidenced by (1) trenchward‐dipping normal faults and (2) the presence of a giant scarp (∼2 km offset and several hundred kilometers long) indicating gravitational collapse of the outermost fore‐arc block. In addition, the contact between the subducting slab and the overriding arc crust is only 20 km wide, and the mantle wedge is characterized by low velocities of ∼7.5 km/s, suggesting upper mantle serpentinization or the presence of melts frozen in the mantle. Key Points Mantle hydration of subducting and upper plates, subduction erosion and arc magmatism

The subduction and rollback of the paleo-Pacific plate during Mesozoic time was the key engine for the evolution of the continental margin in eastern China. It led to lateral accretion of continental crust in Northeast China, lithospheric destruction beneath the North China Craton, and the generation of huge volumes of felsic magmatic rocks in South China. This had a profound influence on deep material cycles and the evolution of epigenetic environmental systems along the continental margin of East Asia. To fully understand the transformation of the dynamic mechanism during the subduction and rollback of the paleo-Pacific plate, we have attempted to trace the remnants and fragments of the subducted paleo-Pacific plate at great depths. Such remnants in both temporal and spatial dimensions can be tracked by using geochemical and geophysical approaches. Studies of the trace elements, Mg-Zn isotopes and Os-Nd-Hf-Pb-O isotopes in continental basalts from eastern China reveal a significant number of the remnants of subduction of the paleo-Pacific plate, and the initial subduction can be traced back to the Early Jurassic. Large-scale geophysical imaging unveils a multitude of high-velocity anomalies in the lower mantle of East Asia. Notably, many high-velocity bodies, aptly referred to as “slab graveyards”, are nestled at the base of the lower mantle. Numerous isolated high-velocity anomalies are also present in the upper part of the lower mantle, creating conduits for the descent of the subducted slabs into the lower mantle. However, a resolution of the remnants for the subducted slabs within the lower mantle are quite low. Consequently, their impact on the lower mantle’s dynamics is yet to be thoroughly investigated. Finally, the presently observed big mantle wedge (BMW) in East Asia has developed through subduction of the Pacific plate in the Cenozoic. However, following the rollback of the paleo-Pacific plate (began at ∼145 Ma), a Cretaceous BMW system would also form above the mantle transition zone in East Asia. There are significant differences in tectonic-magmatic processes and basin-forming and hydrocarbon-accumulation processes among different regions along the East Asian continental margin. Such differences may be controlled by variations in the speed and angle of rollback of the paleo-Pacific plate.

Whether arc magmatism occurs above oceanic subduction zones is the forefront of studies on convergent plate margins. The most important petrologic issue related to the evolution of arc systems is the origin of arc magmatism, among which arc basalts are the most important one because they provide insights into mantle enrichment mechanism and crust-mantle interaction at oceanic subduction zones. Fluids or melts released either by dehydration or by melting of subducting oceanic slab infiltrate and metasomatize the overlying mantle wedge at varying depth, leading to the formation of source regions of arc basalts. Such processes make most of arc basalts commonly enriched in large ion lithosphile elements and light rare earth elements, but depleted in high-field strength elements and heavy rare earth elements. Small amounts of arc basalts are characterized by relatively high Nb contents or by Nb enrichment. Rare basalts with compositions similar to ocean island basalts or mid-ocean ridge basalt also occur in arc systems. For these peculiar rocks, it remains debated whether their source is affected by subduction-related components. During their ascent and before their eruption, arc basaltic magmas are subjected to crystal fractionation, mixing and crustal contamination. In addition to the contribution of subducting slab components to the mantle source of arc basalts, the materials above the subducting slab at forearc depths would have been transported either by drag or by subduction erosion into the subarc mantle and into the source of arc magmas. Heats and materials brought by corner flows also play important roles in the generation of arc basalts. Despite the important progresses made in recent studies of arc basalts, further efforts are needed to investigate subarc mantle metasomatism, material recycling, the formation of arc magma sources, geodynamic mechanism in generating arc basalts, and their implicationd s for the initiation of plate tectonics on Earth.