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24 result(s) for "monzodiorite"
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Neoarchean orogenic, magmatic and hydrothermal events in the Kalgoorlie-Kambalda area, Western Australia: constraints on gold mineralization in the Boulder Lefroy-Golden Mile fault system
The Boulder Lefroy-Golden Mile (BLF-GMF) fault system is the most intensely mineralized structure (>2150 t Au to 2015) in the Archean Yilgarn Craton, Western Australia. The fault system links the Kalgoorlie and Kambalda mining districts in the Eastern Goldfields Province, a continental-margin orogen subdivided into the western Kalgoorlie ensialic rift and the eastern Kurnalpi volcanic arc. After rifting, the 2.73–2.66 Ga greenstone-greywacke succession in the Kalgoorlie-Kambalda area underwent five phases of orogenic deformation, predominantly during ENE-WSW shortening: D1 upright folding at ca. 2680 Ma, D2 sinistral strike-slip faulting at 2678–2663 Ma, D3 folding of late conglomerate-turbidite successions at 2665–2655 Ma, D4 dextral strike-slip faulting at 2655–2640 Ma and D5 east-northeast-striking normal faulting. Regional prehnite-pumpellyite to greenschist facies burial metamorphism took place during D1 and D3 crustal thickening, and amphibolite facies aureoles formed around granite batholiths during and after D3 at 400 ± 100 MPa pressure. The D2 BLF offsets D1 folds by 12 km SW-side south and contains a porphyry dyke (2676 ± 7 Ma) boudinaged by transtensional oblique-slip along a line pitching 21° southeast. The BLF is linked by transverse D2 thrusts to other sinistral faults recording strike-slip until 2663 ± 7 Ma. Late D2 strike-slip movement alternated with early D3 shortening. D3 thrusts accommodated strain in fault blocks of rigid mafic-ultramafic volcanic rocks consolidated during D1, while the sedimentary rocks in D3 synclines were foliated at high strain. Biotite-sericite alteration and gold-pyrite mineralization in the BLF-GMF system took place at 11 ± 4 km burial depth in faults active during D2 and D3. The Golden Mile (1708 t Au) and other deposits are associated with stocks and dykes of high-Mg monzodiorite-tonalite porphyry, part of a late-orogenic (2665–2645 Ma) mantle-derived suite of adakitic affinity. Hornblende and apatite compositions indicate that these intrusions are characterized by high water contents (5–6 wt% H2O in melt), by high oxidation states (δNNO +1.0 to +2.4 log units) and by igneous anhydrite. Some stocks contain pervasive anhydrite-pyrite mineralization of low gold grade (0.4 g/t). Biotite-sericite-pyrite ore bodies such as those at Kanowna Belle (140 t Au) also replace faulted metamorphic rocks above batholith domes cored by plutons of the monzodiorite suite. The D4 strike-slip faults are barren at Kambalda but control gold quartz-vein ore at Kalgoorlie (2651 ± 9 Ma), and Au-Ag breccia ore at Black Flag (<2648 ± 6 Ma).
Mineral chemistry and thermobarometry of Jurassic arc granitoids: implications for petrotectonic and unroofing history of the southern Colombian Andes
The Jurassic magmatic record in the southern Colombian (Northern Andes) includes numerous subduction-related I-type calc-alkaline granitoids with diverse structures and textures, formed in two main episodes at ∼195 to 165 Ma and ∼165 to 145 Ma. We provide new insights into the mineral chemistry, estimates of intensive parameters and petrogenetic processes of 12 plutonic occurrences in the region, grouped in 4 petrographic associations. Primary mineral assemblages include labradorite-to-oligoclase, alkali feldspars, ferroan enstatite, Mg-rich augite to ferroan-diopside, tschermakite to hastingsite and hornblende and Mg-rich annite; Fe-rich phlogopite and actinolite are post-magmatic phases. Amphibole chemistry indicates that the older (195–165 Ma) Jurassic bodies formed from relatively highly oxidized (f O2 values buffered at −0.1 ≤ NNO ≤ +1.4) hydrous (∼4 to 6 wt % H2O) magmas and their differentiation involves significant crustal assimilation and/or magma mixing, fractional crystallization and late-magmatic re-equilibration processes. In contrast, the younger (165–145 Ma) Jurassic intrusives, derived from subducted-modified mantle sources, record moderately lower oxidized hydrous conditions (f O2 values −0.7 to 0.8 ≤ NNO; ∼5 wt % H2O) with magma evolution mainly controlled by fractional crystallization and late-magmatic re-equilibration processes. Clinopyroxene-only, amphibole-only and amphibole-plagioclase thermobarometry estimations suggest that the Jurassic occurrences crystallized over variable temperature (647°C–1087°C) and pressure (0.7–6.3 kbar) conditions, corresponding to emplacement depths ranging from ∼15, ∼8 to 11, ∼5 to 7 and <4 km along the arc crustal column. The obtained data combined with time evolution allow the identification of exhumed and fragmented arc blocks in the Jurassic magmatic system and provide an essential link between the orogenic deformation event poorly constrained in the Northern Andes.
Petrogenesis of Early Cretaceous adakites from the Liaodong Peninsula: insight into the lithospheric thinning of the North China Craton
Lithospheric thinning occurred in the North China Craton (NCC) that resulted in extensive Mesozoic magmatism, which has provided the opportunity to explore the mechanism of the destruction of the NCC. In this study, new zircon U–Pb ages, geochemical and Lu–Hf isotopic data are presented for Early Cretaceous adakitic rocks in the Liaodong Peninsula, with the aim of establishing their origin as well as the thinning mechanism of the NCC. The zircon U–Pb data show that crystallization occurred during 127–120 Ma (i.e. Early Cretaceous). These rocks are characterized by high Sr (294–711 ppm) content and Sr/Y ratio (38.5–108), low Yb (0.54–1.24 ppm) and Y (4.9–16.4 ppm) contents, and with no obvious Eu anomalies, implying that they are adakitic rocks. They are enriched in large-ion lithophile elements (e.g. Ba, K, Pb and Sr) and depleted in high-field-strength elements (e.g. Nb, Ta, P and Ti). These adakitic rocks have negative zircon ϵ Hf(t) contents (−28.9 to −15.0) with two-stage Hf model ages (T DM2) of 3004–2131 Ma. Based on the geochemical features, such as low TiO2 and MgO contents, and high La/Yb and K2O/Na2O ratios, these adakites originated from the partial melting of thickened eclogitic lower crust. They were in an extensional setting associated with the slab rollback of the Palaeo-Pacific Ocean. In combination with previous studies, as a result of the rapid retracting of the Palaeo-Pacific Ocean during 130–120 Ma, the asthenosphere upwelled and modified the thickened lithospheric mantle, which lost its stability, resulting in the lithospheric delamination and thinning of the NCC.
Sources and oxidation state of the Permian arc magmatic rocks of SW Jilin Province in the eastern Central Asian Orogenic Belt: evidence from Li, Hf isotopes and oxygen fugacity
The late Palaeozoic continental-arc magmatic rocks in the Gongzhuling area are located in the Liaoyuan Accretionary Belt. Here we present new zircon U–Pb ages, whole-rock major- and trace-element compositions, Li and zircon Hf isotopic compositions and oxygen fugacity of these rocks with an aim to constrain the lithium isotopic composition of the source region and origin of the magmas. These rocks were formed during 269–258 Ma in middle–late Permian time. The dioritic rocks were formed through mixing processes, with the mafic melts originating from a metasomatized mantle wedge and the felsic melts from the lower crust of a Neoproterozoic arc. The mantle wedge has been metasomatized by Li-rich fluids derived from subducted oceanic crust, as indicated by the δ7Li values of +0.4 ‰ to +3.5 ‰ and positive ϵHf(t) values (+0.7 to +13.1). Redox-sensitive Ce in the zircons indicates the fO2 of the magmas to be low to intermediate (FMQ−2.2 to FMQ+2.6; FMQ is the fayalite–magnetite–quartz redox buffer), precluding large-scale porphyry Cu–Mo mineralization. The middle–late Permian magmatic rocks represent the terminal magmatic record of the subduction of the Palaeo-Asian oceanic crust, meaning that the final closure of the Palaeo-Asian Ocean in the eastern Central Asian Orogenic Belt occurred at the end of the Permian Period. Recent identification of Mesoproterozoic (c. 1400 Ma) granites suggests some Palaeoproterozoic crustal fragments still exist in the Liaoyuan Accretionary Belt, but only in a small amount; therefore, it is concluded that the crustal growth of the Liaoyuan Accretionary Belt occurred mainly during the Neoproterozoic period.
Geochemistry and petrogenesis of the early Palaeozoic appinite-granite complex in the Western Kunlun Orogenic Belt, NW China: implications for Palaeozoic tectonic evolution
The Datong pluton, the largest early Palaeozoic granitoid in the Western Kunlun Orogenic Belt (WKOB) in NW China, is a typical appinite-granite complex. It consists of diorites, quartz diorites, monzodiorites, quartz monzodiorites, monzonites, quartz monzonites, syenites, granodiorites and monzogranites. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating yielded crystallization ages of 459 ± 3 Ma for the quartz monzonites and 452 ± 5 Ma for the monzogranites (Late Ordovician). The rocks possess a wide range of SiO2 (56.0–73.4 wt %), MgO (0.17–4.55 wt %) and Mg no. (25–60), with high K2O (2.83–5.29 wt %) contents, exhibiting high-K calc-alkaline to shoshonitic traits. They are characterized by enrichments in large-ion lithophile elements (LILEs) and light rare Earth elements (LREEs), as well as depletions in high-field-strength elements (HFSEs). The rocks have initial 87Sr/86Sr ratios of 0.7086–0.7185, negative εNd(t) values of –3.72 to –1.79 and εHf(t) values vary from –1.6 to +4.7. These features are modelled to show that they were most likely derived from an enriched lithospheric mantle source and that fractional crystallization with minor crustal contamination was involved in their petrogenetic process. Considering the distribution and chronology of the Palaeozoic intrusions – such as Kegang, Bulong, Qiukesu, Yierba, North Kudi, Dongbake, Buya, Ayilixi and Warengzilafu granitoid plutons with ages of c. 420–530 Ma – in conjunction with the Palaeozoic metamorphic overprinting in the WKOB, we propose a divergent double-subduction model to explain the destruction of the Proto-Tethys Ocean and suggest that the Datong pluton was likely emplaced in a post-collisional setting following the termination of subduction in response to slab break-off.
The REE-Zr-U-Th Minerals of the Maronia Monzodiorite, N. Greece: Implications on the Saturation and Segregation Mechanisms of Critical Metals in Intermediate–Mafic Compositions
This work delves into the presence of REE-Ti-Zr-U-Th minerals, in the mafic–intermediate rocks of the Maronia pluton, Greece, an Oligocene intrusion formed through arc-magmatism during subduction. In Maronia monzodiorite, critical metals are contained in three principal mineral groups, namely, the REE-Ti-Zr, REE-Ca-P, and U-Th assemblages. The REE-Ti-Zr group includes REE-ilmenite, chevkinite-like phases, zirconolite, and baddeleyite. The REE-Ca-P assemblage is represented by allanite-(Ce), monazite-(Ce), and huttonitic monazite-(Ce). The U-Th assemblage comprises thorite–coffinite and uraninite–thorianite solid solutions. The paragenetic sequencing of these minerals offers insights into their formation conditions and correlation with the pluton’s magmatic evolution. In the REE-Ti-Zr group, mineral formation progresses from REE-ilmenite to baddeleyite through chevkinite-like phases and zirconolite under oxidizing conditions. The REE-Ca-P sequence involves allanite-(Ce), followed by monazite-(Ce), late allanite-(Ce), and huttonitic monazite-(Ce). In the U-Th group, earlier thorite–coffinite phases are succeeded by uraninite–thorianite solid solutions, indicating Si-undersaturation at late magmatic stages. Fluctuations in Ca-activity induce alternating formations of allanite-(Ce) and monazite-(Ce). These mineral variations are attributed to early-stage interactions between high-K calc-alkaline and shoshonitic gabbroic melts, influencing critical metal enrichment and mineral speciation. The study’s insights into paragenesis and geological processes offer implications for mineral exploration in analogous geological settings.
Evidence for Neoarchean basement for the Deccan volcanic flows around Koyna-Warna region, western India; zircon U-Pb age and Hf-isotopic results
Deep boreholes around the Koyna-Warna seismic zone in the southwestern part of the Deccan Volcanic Province (DVP) enable a rare access to the basement beneath the thick (typically 1-2 km) lava pile, the nature of which has been enigmatic for long. Utilizing the drill core from borehole KBH-1 near Rasati village, we present here in situ Laser Ablation - Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS) and LA-MC (multi collector)-ICPMS zircon U-Pb age and Hf-isotopic composition for two samples along with a brief description of the petrology and geochemistry of the representative lithounits of the basement section. The KBH-1 basement section comprises predominantly grey migmatite gneisses of granodiorite, tonalite and quartz monzodiorite composition apart from minor pink monzogranite. The grey gneisses show geochemical affinity to Neoarchean Tonalite-Trondhjemite-Granodiorite (TTG) suites and modern calc-alkalic granitoids. Zircons from a granodiorite and a monzogranite samples yield consistent U-Pb ages of 2710± 63 Ma and 2700±49 Ma (2σ errors). The initial 176Hf/177Hf values lie in a narrow range (0.281162 to 0.281283) corresponding to εHf(T) values of +3.7 to +8.0 indicating that the magmatic precursors of the KBH-1 gneisses represent juvenile magmatism around 2700 Ma. In terms of the composition and age, a correlation between the gneisses in the KBH-1 borehole and the Neoarchean basement gneisses of the Eastern Dharwar Craton (EDC) is emphasized arguing for the extension of the EDC to the Koyna-Warna region.
Equilibrium crystallization of massif-type anorthosite residual melts: a case study from the 1.64 Ga Ahvenisto complex, Southeastern Finland
Fe–Ti–P-rich mafic to intermediate rocks (monzodiorites and oxide–apatite–gabbronorites, OAGNs) are found as small intrusions in most AMCG (anorthosite–magnerite–charnokite–granite) suites. The origin of the monzodioritic rocks is still debated, but in many studies, they are presumed to represent residual liquid compositions after fractionation of anorthositic cumulates. In the 1.64 Ga Ahvenisto complex, SE Finland, monzodioritic rocks occur as minor dike-like lenses closely associated with anorthositic rocks. We report new field, petrographic, and geochemical (XRF, ICP-MS, EMPA) data complemented with crystallization modeling (rhyolite-MELTS, MAGFRAC) for the monzodioritic rocks, apatite–oxide–gabbronorite, and olivine-bearing anorthositic rocks of the Ahvenisto complex. The presented evidence suggest that the monzodioritic rocks closely represent melt compositions while the apatite–oxide–gabbronorite and olivine-bearing anorthositic rocks are cumulates. The monzodioritic rocks seem to form a liquid line of descent (LLD) from primitive olivine monzodiorites to more evolved monzodiorites. Petrological modeling suggests that the interpreted LLD closely corresponds to a residual melt trend left after fractional crystallization (FC) and formation of the cumulate anorthositic rocks and minor apatite–oxide–gabbronorite in shallow magma chambers. Consequent equilibrium crystallization (EC) of separate monzodioritic residual magma batches can produce the observed mineral assemblages and the low Mg numbers measured from olivine (Fo25–45) and pyroxenes (En48–63, Mg#cpx 60–69). The monzodioritic rocks and apatite–oxide–gabbronorites show similar petrological and geochemical characteristics to corresponding rock types in other AMCG suites, and the model described in this study could be applicable to them as well.
Albite ± Actinolite-Altered Porphyry Dykes in Archean Gold Deposits of the Boulder Lefroy-Golden Mile Fault System, Yilgarn Craton, Western Australia: Petrography, Chronology, and Comparison to Canadian Albitites
The Boulder Lefroy-Golden Mile fault system in the Archean Yigarn Craton is the most productive gold-mineralized structure in Australia (>2300 t Au). The New Celebration deposit (51 t Au) is part of a group of hematite- and anhydrite-bearing mesothermal deposits and Fe-Cu-Au skarns associated with monzodiorite-tonalite intrusions in the strike-slip fault system. Ore-grade biotite-carbonate and late sericite-carbonate-alkali feldspar replacement is bound to the contacts of a felsic (low Cr, Ni, V) quartz-plagioclase porphyry dyke dated at 2676 ± 7 Ma. The sodic-potassic alteration of the felsic boudinaged dyke contrasts with the albite-actinolite alteration in the adjacent mafic (high Cr, Ni, V) plagioclase porphyry dated at 2662 ± 4 Ma, although both share the same sulfide-oxide assemblage: pyrite ± chalcopyrite, magnetite ± hematite. The younger porphyry locally crosscuts foliation and is bordered by post-kinematic actinolite-pyrite selvages overprinting talc-chlorite-phlogopite-dolomite schist. It contains auriferous pyrite (70 ppb Au; 610 ppb Ag) where sampled for zircon U-Pb chronology at +224 m elevation. Above the sample site, the dyke was mined as gold ore (1–6 g/t Au) at +300–350 m. Temperature estimates based on actinolite-albite pairs (300–350 °C) agree with the fluid inclusion trapping temperature of main-stage auriferous veins (330 ± 20 °C). These relationships are interpreted to indicate syn-mineralization emplacement. Gold-related albite-altered porphyry dykes (albitites) also occur in the world-class Hollinger-McIntyre (986 t Au) and Kerr Addison-Chesterville deposits (336 t Au), Abitibi greenstone belt, Canada.
Devonian Island-Arc Magmatism of the Voikar Zone in the Polar Urals
Abstract—The studied deep-seated plutonic rocks of the Malyi Ural Paleozoic island arc include Sob’ gabbroid, diorite, and plagiogranitoid and Kongor gabbroid, diorite, and monzonitoid, which formed under similar P–T conditions. U–Pb LA-ICP-MS zircon dating established similar concordant age values: 406 ± 2 Ma for hornblende gabbrodiorite of the major intrusive phase in the Sob’ complex and 396 ± 1 and 393 ± 2 Ma for bipyroxene gabbrodiorite of the early and major phases in the Kongor complex. Our age data have made it possible to determine the formation time of the Kongor complex as Late Emsian–Early Eifelian (399–393 Ma). The largest volumes of island-arc igneous rocks belonging to the calc-alkali gabbro–diorite–tonalite–plagiogranite series formed in the Praghian–Early Eifelian (410–393 Ma). The Late Emsian–Early Eifelian (399–393 Ma) was characterized by the development of much smaller bodies consisting of Kongor rocks pertaining to the calc-alkali and high-K calk-alkali range, gradually transitioning into shoshonite–latite. High-K rocks formed upon completion of calc-alkali magmatism, likely due to the gradual decay of Devonian suprasubduction magmatism and partial melting in magma generation or due to the involvement of a second magma source.