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CeO2 is a crucial functional material in catalysis and energy applications, whose performance is highly morphology-dependent. Traditional synthesis methods often rely on organic templates or surfactants, which complicate the processes and pose environmental concerns. This study introduces an eco-friendly approach utilizing a methanol–water (MeOH-H2O) mixed solvent system combined with NH4HCO3 to achieve controllable synthesis of multi-morphology CeO2 without surfactants or templates. The effects of different solvent systems (pure H2O, pure MeOH, and their mixtures) and NH4HCO3 as an inexpensive regulator on precursor phase behavior and crystallization were systematically investigated. By optimizing the Ce:N molar ratios (1:1 to 1:7) as well as reaction times (0.5 to 36 h), our findings indicate that H2O significantly enhances crystallinity (from 40.9% to 61.4% for precursors, reaching 70.3% after calcination) and promotes octahedra formation in the MeOH-H2O mixed system, while NH4HCO3 acts as a structure-directing agent to control size (e.g., ~240 nm octahedra at Ce:N = 1:1, up to 375 nm at Ce:N = 1:2) and partially substitutes for high-temperature calcination in improving crystallinity. Variety morphologies, including plates, dendrites, octahedra, and hollow structures, were successfully synthesized. This work elucidates the synergistic mechanism by which solvents and NH4HCO3 influence CeO2 nucleation and growth, thereby providing an environmentally friendly synthesis route with significant potential applications in catalysis and energy storage.

2D metal-organic frameworks (MOFs) are considered as promising electrochemical sensing materials and have attracted a lot of attention in recent years. Compared with bulk MOFs, the construction of 2D MOFs can increase the exposure of active sites by obtaining a larger surface area ratio. Herein, a facile one-pot hydrothermal synthesis of pyridine-regulated lamellar Ni-MOFs with ultrathin and well-defined 2D morphology is described. Compared with the bulk structure, the 2D lamellar Ni-MOF has higher surface area and active site density, showing better electrochemical glucose sensing performance. The 2D lamellar Ni-MOF exhibits a fast amperometric response of less than 3 s and a high sensitivity of 907.54 µA mm cm toward glucose with a wide linear range of 0.5-2665.5 µm. Furthermore, the 2D lamellar Ni-MOF also possesses excellent stability and reproducibility, and can be used to detect glucose with high accuracy and reliability in different environments.

Classic control theory applied to compliant and soft robots generally involves an increment of computation that has no equivalent in biology. To tackle this, morphological computation describes a theoretical framework that takes advantage of the computational capabilities of physical bodies. However, concrete applications in robotic locomotion control are still rare. Also, the trade-off between compliance and the capacity of a physical body to facilitate its own control has not been thoroughly studied in a real locomotion task. In this paper, we address these two problems on the state-of-the-art hydraulic robot HyQ. An end-to-end neural network is trained to control HyQ’s joints positions and velocities using only Ground Reaction Forces. Our simulations and experiments demonstrate better controllability using less memory and computational resources when increasing compliance. However, we show empirically that this effect cannot be attributed to the ability of the body to perform intrinsic computation. It invites to give an increased emphasis on compliance and co-design of the controller and the robot to facilitate attempts in machine learning locomotion.

Rare-earth (RE)-based metal organic frameworks (MOFs) are quickly gaining popularity as flexible functional materials in a variety of technological fields. These MOFs are useful for more than just conventional uses like gas sensors and catalyst materials; in fact, they also show significant promise in emerging technologies including photovoltaics, optical, and biomedical applications. Using yttrium and europium as ionic host centres and dopants, respectively, and 1,3,5-benzenetricarboxylic acid (H3-BTC) as an organic linker, we describe a simple and green approach for the fabrication of RE-MOFs. Specifically, Y-BTCs and Eu-doped Y-BTCs MOFs have been synthesised in a single step using an eco-friendly method that makes use of ultrasound technology. To establish a correlation between the morphological and structural properties and reaction conditions, a range of distinct reaction periods has been employed for the synthetic processes. Detailed analyses of the synthesised samples through powder X-ray diffraction (PXRD), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FT-IR) have confirmed the phase formation. Furthermore, thermal analyses such as thermogravimetric analysis (TGA) have been employed to evaluate the thermal stability and structural modifications of the Y-BTC and Eu-doped Y-BTC samples. Finally, the luminescent properties of the synthesised samples doped with Eu3+ have been assessed, providing an evaluation of their characteristics. As a proof of concept, an Eu-doped Y-BTC sample has been applied for the sensing of nitrobenzene as a molecule test of nitro derivatives.

To reduce solid waste production and enable the synergistic conversion of solid waste into high-value-added products, we introduce a novel, sustainable, and ecofriendly method. We fabricate nanofiber and nanosheet silicon carbides (SiC) through a carbothermal reduction process. Here, the calcined coal gangue, converted from coal gangue, serves as the silicon source. The carbon sources are the carbonized waste tire residue from waste tires and the pre-treated kerosene co-refining residue. The difference in carbon source results in the alteration of the morphology of the SiC obtained. By optimizing the reaction temperature, time, and mass ratio, the purity of the as-made SiC products with nanofiber-like and nanosheet-like shapes can reach 98%. Based on the influence of synthetic conditions and the results calculated from the change in the Gibbs free energy of the reactions, two mechanisms for SiC formation are proposed, namely the reaction of intermediate SiO with CO to form SiC-nuclei-driven nanofibrous SiC and the SiO-deposited carbon surface to fabricate nuclei-induced polymorphic SiC (dominant nanosheets). This work provides a constructive strategy for preparing nanostructured SiC, thereby achieving “turning trash into treasure” and broadening the sustainable utilization and development of solid wastes.

Micron-scale robots require systems that can morph into arbitrary target configurations controlled by external agents such as heat, light, electricity, and chemical environment. Achieving this behavior using conventional approaches is challenging because the available materials at these scales are not programmable like their macroscopic counterparts. To overcome this challenge, we propose a design strategy to make a robotic machine that is both programmable and compatible with colloidal-scale physics. Our strategy uses motors in the form of active colloidal particles that constantly propel forward. We sequence these motors end-to-end in a closed chain forming a two-dimensional loop that folds under its mechanical constraints. We encode the target loop shape and its motion by regulating six design parameters, each scale-invariant and achievable at the colloidal scale. We demonstrate the plausibility of our design strategy using centimeter-scale robots called kilobots. We use Brownian dynamics simulation to explore the large design space beyond that possible with kilobots, and present an analytical theory to aid the design process. Multiple loops can also be fused together to achieve several complex shapes and robotic behaviors, demonstrated by folding a letter shape “M,” a dynamic gripper, and a dynamic pacman. The material-agnostic, scale-free, and programmable nature of our design enables building a variety of reconfigurable and autonomous robots at both colloidal scales and macroscales.

It is well known that the functionality of inorganic materials strongly depends on the chemical composition, morphology, particle size, crystal facet, etc., which are strongly influenced by the synthesis process. The precise control of the synthesis process is expected to lead to the discovery of new functionality and improvement of the functionality of materials. For example, in a high-temperature solid-phase reaction, it is difficult to control the morphology of nanocrystals. On the other hand, synthesizing functional materials using solution processes, such as hydrothermal and solvothermal reactions, makes it possible to control the morphology and particle size precisely. Usually, the solution process is strongly related to the dissolution reprecipitation mechanism. Therefore, the material composition can be strictly controlled and is suitable for forming fine particles with high crystallinity. In this review paper, the role of the solvent in the solution process, its effect on particle size and morphology of the transition metal oxide, and the related functional improvement will be focused. Furthermore, the direct formation of functional thin films by the solution process and the morphology control by non-oxide materials by the topotactic reaction will also be introduced.

The all‐inorganic lead halide perovskites, including cesium lead iodide (CsPbI3), have attracted significant attention due to their possible applications in photovoltaics, light‐emitting devices, and other optoelectronic technologies, driven by their intrinsic optoelectronic properties. This study introduces a simple, green, and scalable solution synthesis method for the CsPbI3 perovskite fabrication, utilizing β‐diketonate [Cs(hfa)]n and [Pb(hfa)2diglyme]2 precursors and ethanol as solvent. The as‐synthesized nanoribbons are initially fabricated in the pure yellow δ‐phase, as confirmed by X‐ray diffraction and energy‐dispersive X‐ray analysis. Thermal analysis through differential scanning calorimetry highlights the reversible phase transition from δ‐CsPbI3 to the black cubic α‐phase. The photoactive and metastable black γ‐CsPbI3 is obtained via high‐temperature annealing and rapid cooling under inert conditions. Optical characterizations have been performed in order to extrapolate a bandgap of 2.89 eV for the δ‐phase and 1.62 eV for the γ‐phase, while the photoluminescence analysis displays intense emissions at 530 and 700 nm for the δ‐ and γ‐phase, respectively. Ambient photoemission spectroscopy further elucidates the energy levels of the γ‐phase, determining a highest occupied molecular orbital energy of 5.68 eV and a work function of 4.32 eV. These findings demonstrate the possibility to synthesize pure CsPbI3 and obtain the γ‐CsPbI3 phase with promising applications. Cesium lead iodide (CsPbI3) nanoribbons obtained through mild condition synthesis are herein reported without surfactant species and toxic solvent starting from β‐diketonate complexes of Cs and Pb. The morphological and structural features, together with the thermal stability and phase transitions from the yellow δ to the black α and γ‐CsPbI3 phases, have been investigated.

It is well known that the functionality of inorganic materials strongly depends on the chemical composition, morphology, particle size, crystal facet, etc., which are strongly influenced by the synthesis process. The precise control of the synthesis process is expected to lead to the discovery of new functionality and improvement of the functionality of materials. For example, in a high-temperature solid-phase reaction, it is difficult to control the morphology of nanocrystals. On the other hand, synthesizing functional materials using solution processes, such as hydrothermal and solvothermal reactions, makes it possible to control the morphology and particle size precisely. Usually, the solution process is strongly related to the dissolution reprecipitation mechanism. Therefore, the material composition can be strictly controlled and is suitable for forming fine particles with high crystallinity. In this review paper, the role of the solvent in the solution process, its effect on particle size and morphology of the transition metal oxide, and the related functional improvement will be focused. Furthermore, the direct formation of functional thin films by the solution process and the morphology control by non-oxide materials by the topotactic reaction will also be introduced.

Semiconductor polymeric graphitic carbon nitride (g-C3N4) photocatalysts have garnered significant and rapidly increasing interest in the realm of visible light-driven hydrogen evolution reactions. This interest stems from their straightforward synthesis, ease of functionalization, appealing electronic band structure, high physicochemical and thermal stability, and robust photocatalytic activity. This review starts with the basic principle of photocatalysis and the development history, synthetic strategy, and structural properties of g-C3N4 materials, followed by the rational design and engineering of g-C3N4 from the perspectives of nano-morphological control and electronic band tailoring. Some representative results, including experimental and theoretical calculations, are listed to show the advantages of optimizing the above two characteristics for performance improvement in photocatalytic hydrogen evolution from water splitting. The existing opportunities and challenges of g-C3N4 photocatalysts are outlined to illuminate the developmental trajectory of this field. This paper provides guidance for the preparation of g-C3N4 and to better understand the current state of the art for future research directions.