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\"This book highlights the importance of carbon structures for technological advancements in applications for industrial and societal benefits. It provides an opportunity for researchers from different backgrounds and disciplines to take up further research on synthesis, properties, and applications of carbon nanomaterials. Each chapter introduces a particular carbon nanomaterial. Additionally, the book provides scientific inputs along with emerging perspectives from the author who has devoted almost four decades to the field of carbon science and technology\"-- Provided by author.

Nanotechnology is an advanced field of science having the ability to solve the variety of environmental challenges by controlling the size and shape of the materials at a nanoscale. Carbon nanomaterials are unique because of their nontoxic nature, high surface area, easier biodegradation, and particularly useful environmental remediation. Heavy metal contamination in water is a major problem and poses a great risk to human health. Carbon nanomaterials are getting more and more attention due to their superior physicochemical properties that can be exploited for advanced treatment of heavy metal-contaminated water. Carbon nanomaterials namely carbon nanotubes, fullerenes, graphene, graphene oxide, and activated carbon have great potential for removal of heavy metals from water because of their large surface area, nanoscale size, and availability of different functionalities and they are easier to be chemically modified and recycled. In this article, we have reviewed the recent advancements in the applications of these carbon nanomaterials in the treatment of heavy metal-contaminated water and have also highlighted their application in environmental remediation. Toxicological aspects of carbon-based nanomaterials have also been discussed.

Boron nitride nanotubes (BNNTs) are tubular nanoparticles with a structure analogous to that of carbon nanotubes, but with B and N atoms that completely replace the C atoms. Many favorable results indicate BNNTs as safe nanomaterials; however, important concerns have recently been raised about ultra-pure, long (˜10 µm) BNNTs tested on several cell types. Here, we propose additional experiments with the same BNNTs, but shortened (˜1.5 µm) with a homogenization/sonication treatment that allows for their dispersion in gum Arabic aqueous solutions. Obtained BNNTs are tested on human endothelial and neuron-like cells with several independent biocompatibility assays. Moreover, for the first time, their strong sum-frequency generation signal is exploited to assess the cellular uptake. Our data demonstrate no toxic effects up to concentrations of 20 µg/ml, once more confirming biosafety of BNNTs, and again highlighting that nanoparticle aspect ratio plays a key role in the biocompatibility evaluation. Original submitted 3 December 2013; Revised submitted 28 January 2014; Published online 6 February 2014

\"Carbon Nanotubes for a Green Environment: Balancing the Risks and Rewards describes the synthesis, characterization, and unique applications of undoped/doped carbon nanotubes as well as hybrids of them with grapheme or nanocomposites, focusing on green aspects of carbon nanotube applications. The volume shows new approaches used for tapping the potential and promise of key materials in isolation or combined with other materials. The research-oriented chapters highlight a spectrum of applications of carbon nanotubes as novel materials for energy storage as well as for environmental remediation, wastewater treatment, green health care products, and more. Chapters explore the use of carbon nanotubes for remediation methods for wastewater treatment such as by using graphene oxide-carbon nanotube composites and by applying undoped and doped carbon nanotubes for removing contaminates. The book also looks at the application of carbon nanotubes for enhanced oil recovery and for heavy metal separation. Other chapters look at the rheological behavior of carbon nanotubes-based materials and their role in processing for various products, the thermal and electrical transport in carbon nanotubes composites, and carbon nanotubes-based composite materials for electromagnetic shielding applications. The biomedical applications of carbon nanotube-based nanomaterials is also explored, such as FTIR spectroscopy\"-- Provided by publisher.

Nowadays, biomaterials have become a crucial element in numerous biomedical, preclinical, and clinical applications. The use of nanoparticles entails a great potential in these fields mainly because of the high ratio of surface atoms that modify the physicochemical properties and increases the chemical reactivity. Among them, carbon nanotubes (CNTs) have emerged as a powerful tool to improve biomedical approaches in the management of numerous diseases. CNTs have an excellent ability to penetrate cell membranes, and the sp2 hybridization of all carbons enables their functionalization with almost every biomolecule or compound, allowing them to target cells and deliver drugs under the appropriate environmental stimuli. Besides, in the new promising field of artificial biomaterial generation, nanotubes are studied as the load in nanocomposite materials, improving their mechanical and electrical properties, or even for direct use as scaffolds in body tissue manufacturing. Nevertheless, despite their beneficial contributions, some major concerns need to be solved to boost the clinical development of CNTs, including poor solubility in water, low biodegradability and dispersivity, and toxicity problems associated with CNTs’ interaction with biomolecules in tissues and organs, including the possible effects in the proteome and genome. This review performs a wide literature analysis to present the main and latest advances in the optimal design and characterization of carbon nanotubes with biomedical applications, and their capacities in different areas of preclinical research.

\"The first biography of the late Mildred Dresselhaus, a pioneer of nanoscience, a champion for women in STEM, and recipient the Presidential Medal of Freedom and the National Medal of Science\"-- Provided by publisher.

Dopamine homeostasis is an important clinical diagnostic index, because an abnormal level in the human body is closely related to certain serious diseases. Herein, a novel electrochemical sensing platform based on gold nanobipyramid/multi-walled carbon nanotube hybrids (AuNBP/MWCNTs) is developed to detect dopamine in human fluids. Using field emission scanning electron microscopy, it is observed that AuNBPs of about 60 nm with two pyramids are well dispersed on the surface of MWCNTs. Energy-dispersive X-ray spectrometry, X-ray diffraction and X-ray photoelectron spectroscopy confirm that AuNBPs are self-assembled onto the surface of MWCNTs to form the hybrids. Cyclic voltammetry reveals that the AuNBP/MWCNTs exhibit good electrocatalytic activity toward dopamine oxidation owing to the synergistic effects of AuNBPs and MWCNTs. In addition, both cyclic voltammetry and differential pulse voltammetry display three well-resolved and distinct oxidation peaks on the AuNBP/MWCNT-modified glassy carbon electrode. Based on AuNBP/MWCNTs, the newly developed electrochemical sensor is used to detect dopamine in the presence of ascorbic acid and uric acid over a wide linear range from 50 nM to 2.7 mM and a low detection limit of 15 nM (at S/N = 3). The electrochemical sensor can also be applied for the quantitative analysis of dopamine in real samples.

[Abstract] : [Objective] : We reviewed studies on pulmonary, reproductive, and developmental toxicity caused by carbon nanotubes (CNTs). In paricular, we analyzed how CNT exposure affects the several processes of pulmonary toxicity, including inflammation, injury, fibrosis, and pulmonary tumors. [Methods] : In pulmonary toxicity, there are various processes, including inflammation, injury, fibrosis, respiratory tumor in the lungs, and biopersistence of CNTs and genotoxicity as tumor-related factors, to develop the respiratory tumor. We evaluated the evidence for the carcinogenicity of CNTs in each process. In the fields of reproductive and developmental toxicity, studies of CNTs have been conducted mainly with mice. We summarized the findings of reproductive and developmental toxicity studies of CNTs. [Results] : In animal studies, exposure to CNTs induced sustained inflammation, fibrosis, lung cancer following long-term inhalation, and gene damage in the lung. CNTs also showed high biopersistence in animal studies. Fetal malformations after intravenous and intraperitoneal injections and intratracheal instillation, fetal loss after intravenous injection, behavioral changes in offsprings after intraperitoneal injection, and a delay in the delivery of the first litter after intratracheal instillation were reported in mice-administered multi-walled carbon nanotubes (MWCNTs). Single-walled carbon nanotubes (SWCNTs) appeared to be embryolethal and teratogenic in mice when given by intravenous injection ; moreover, the tubes induced death and growth retardation in chicken embryos. [Conclusion] : CNTs are considered to have carcinogenicity and can cause lung tumors. However, the carcinogenicity of CNTs may attenuate if the fiber length is shorter. The available data provide initial information on the potential reproductive and developmental toxicity of CNTs.

Water deficit stress is one of the most significant environmental abiotic factors influencing plant growth and metabolism globally. Recently, encouraging outcomes for the use of nanomaterials in agriculture have been shown to reduce the adverse effects of drought stress on plants. The present study aimed to investigate the impact of various carbon nanomaterials (CNMs) on the physiological, morphological, and biochemical characteristics of bell pepper plants subjected to water deficit stress conditions. The study was carried out as a factorial experiment using a completely randomized design (CRD) in three replications with a combination of three factors. The first factor considered was irrigation intensity with three levels [(50%, 75%, and 100% (control) of the field capacity (FC)] moisture. The second factor was the use of carbon nanomaterials [(fullerene C60, multi-walled carbon nanotubes (MWNTs) and graphene nanoplatelets (GNPs)] at various concentrations [(control (0), 100, 200, and 1000 mg/L)]. The study confirmed the foliar uptake of CNMs using the Scanning Electron Microscopy (SEM) technique. The effects of the CNMs were observed in a dose-dependent manner, with both stimulatory and toxicity effects being observed. The results revealed that exposure to MWNTs (1000 mg/L) under well-watered irrigation, and GNPs treatment (1000 mg/L) under severe drought stress (50% FC) significantly ( P  < 0.01) improved fruit production and fruit dry weight by 76.2 and 73.2% as compared to the control, respectively. Also, a significant decrease (65.9%) in leaf relative water content was obtained in plants subjected to soil moisture of 50% FC over the control. Treatment with GNPs at 1000 mg/L under 50% FC increased electrolyte leakage index (83.6%) compared to control. Foliar applied MWNTs enhanced the leaf gas exchange, photosynthesis rate, and chlorophyll a and b concentrations, though decreased the oxidative shock in leaves which was demonstrated by the diminished electrolyte leakage index and upgrade in relative water content and antioxidant capacity compared to the control. Plants exposed to fullerene C60 at 100 and 1000 mg/L under soil moisture of 100 and 75% FC significantly increased total flavonoids and phenols content by 63.1 and 90.9%, respectively, as compared to the control. A significant increase (184.3%) in antioxidant activity (FRAP) was observed in plants exposed to 200 mg/L MWCNTs under irrigation of 75% FC relative to the control. The outcomes proposed that CNMs could differentially improve the plant and fruit characteristics of bell pepper under dry conditions, however, the levels of changes varied among CNMs concentrations. Therefore, both stimulatory and toxicity effects of employed CNMs were observed in a dose-dependent manner. The study concludes that the use of appropriate (type/dose) CNMs through foliar application is a practical tool for controlling the water shortage stress in bell pepper. These findings will provide the basis for more research on CNMs-plant interactions, and with help to ensure their safe and sustainable use within the agricultural chains.