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Continental alkaline magmatism has been suggested to play a significant role in releasing deep mantle carbon into the atmosphere, which can greatly impact the global climate. However, the temporal variations of alkaline magmatism and their potential to modulate climate over geologic time remain poorly constrained. The detrital zircon record is a frequently used proxy for tracking secular variations in particular magmatism. Here, we use a novel machine‐learning technique to discriminate zircon from carbonatites, kimberlites, and other alkaline rocks. A global compilation of detrital zircon yields continental alkaline magmatic flare‐ups between 1,050−850, 650−500, 250−200, and 50−0 Ma. Our estimates indicate relatively elevated contributions of total magmatic carbon outgassing from alkaline magmatism during the aforementioned magmatic flare‐ups. We infer that anomalous alkaline magmatism may influence global warming during specific intervals of geologic time, but when they are not that voluminous or persistent extensive arc magmatism may drive warming conditions. Plain Language Summary The potential of volcanic CO2 emissions to modulate atmospheric CO2 levels and affect the environment of our planet has been recognized. Some specific volcanic types, such as continental arc volcanism, have been hypothesized to play a dominant role in driving long‐term climate change. Recently, the efficiency of continental alkaline magmatism in releasing carbon from the deep mantle to the atmosphere and its ability to influence Earth's climate is proposed for certain timescales and supported by empirical data. However, the quantitative estimation of the alkaline magmatic activity over geologic time and its general link to the global climate change remains poorly constrained. Here, we assess the alkaline magmatic variations based on the detrital zircon record and a novel machine‐learning model which could discriminate zircon from carbonatites, kimberlites and other related alkaline silicate rocks. The predictive result shows several peaks at 1,050−850, 650−500, 250−200, and 50−0 Ma, which is considered a minimum estimation due to the preservation bias of the detrital zircon record. Our estimates indicate that continental alkaline magmatism may influence global warming during specific intervals of geologic time such as the early Paleozoic and early Mesozoic. Key Points Frequency of magmatic events can be assessed by a machine‐learning analysis of zircon Continental alkaline magmatism peaked between 1,050−850, 650−500, 250−200, and 50−0 Ma Anomalous alkaline magmatism may contribute to global warming at certain times

Marine CO2 removal (CDR) using enhanced-alkalinity seawater discharge was simulated in the estuarine waters of the Salish Sea, Washington, US. The high-alkalinity seawater would be generated using bipolar membrane electrodialysis technology to remove acid and the alkaline stream returned to the sea. Response of the receiving waters was evaluated using a shoreline resolving hydrodynamic model with biogeochemistry, and carbonate chemistry. Two sites, and two deployment scales, each with enhanced TA of 2997 mmol m−3 and a pH of 9 were simulated. The effects on air-sea CO2 flux and pH in the near-field as well as over the larger estuary wide domain were assessed. The large-scale deployment (addition of 164 Mmoles TA yr−1) in a small embayment (Sequim Bay, 12.5 km2) resulted in removal of 2066 T of CO2 (45% of total simulated) at rate of 3756 mmol m−2 yr−1, higher than the 63 mmol m−2 yr−1 required globally to remove 1.0 GT CO2 yr−1. It also reduced acidity in the bay, ΔpH ≈ +0.1 pH units, an amount comparable to the historic impacts of anthropogenic acidification in the Salish Sea. The mixing and dilution of added TA with distance from the source results in reduced CDR rates such that comparable amount 2176 T CO2 yr−1 was removed over >1000 fold larger area of the rest of the model domain. There is the potential for more removal occurring beyond the region modeled. The CDR from reduction of outgassing between October and May accounts for as much as 90% of total CDR simulated. Of the total, only 375 T CO2 yr−1 (8%) was from the open shelf portion of the model domain. With shallow depths limiting vertical mixing, nearshore estuarine waters may provide a more rapid removal of CO2 using alkalinity enhancement relative to deeper oceanic sites.

Eruptive dynamics is influenced by gas escape from the ascending magma. Gas pathways form in the magma via bubble coalescence, leading to gas channeling. Magmatic crystals play a key role in gas channel formation. This work constrains experimentally decompression‐induced coalescence in high‐crystallinity silicic magmas without external deformation, focusing on low gas content and bimodal crystal size (microlites and phenocrysts). All percolating samples have permeabilities of 10−14 m2 at bulk porosities of 7–10 vol% and bulk crystallinities up to 75 vol%. Our results demonstrate the possibility of coalescence‐related outgassing at high pressure (120–350 MPa) and without external strain, which corresponds to magma stagnating deep in a volcanic conduit. Channeling at such low gas content implies that bimodal crystallinity favors effusive over explosive volcanic behavior. It may also be the missing physical mechanism explaining gas transfer across magmatic systems despite high melt viscosity and low or absent magma extrusion. Plain Language Summary The way volcanoes erupt is mainly controlled by the ability of gases to escape from the magma (outgassing). An efficient way to outgas is to connect bubbles together (coalescence) up to the point where channels form in the magma (channeling) in which gas can circulate toward the surface. We investigate experimentally how coalescence and channeling happen in immobile, crystal‐rich viscous magma in conditions (pressure and temperature) similar to those found in deep volcanic conduit, where only a small amount of gas (<10%) is present. Our experiments demonstrate that bubble connections are possible thanks to a large amount of crystals on which bubbles can lean, deform, and join each other. That gas can escape from magma at depth could favor effusive eruption over volcanic explosions and even bring new insights on degassing in immobile magma. Key Points Gas permeability in silicic magma is possible with gas volumes below 10% thanks to high crystallinity Outgassing at low gas content can happen without external deformation nor fracturation of the magma Volcanic outgassing in stagnant magmas is explained by deep conduit bubble channeling that may be a key mechanism in eruptive transition

The early Earth’s environment is controversial. Climatic estimates range from hot to glacial, and inferred marine pH spans strongly alkaline to acidic. Better understanding of early climate and ocean chemistry would improve our knowledge of the origin of life and its coevolution with the environment. Here, we use a geological carbon cycle model with ocean chemistry to calculate self-consistent histories of climate and ocean pH. Our carbon cycle model includes an empirically justified temperature and pH dependence of seafloor weathering, allowing the relative importance of continental and seafloor weathering to be evaluated. We find that the Archean climate was likely temperate (0–50 °C) due to the combined negative feed-backs of continental and seafloor weathering. Ocean pH evolves monotonically from 6.6 − 0.4 + 0.6 ( 2 σ ) at 4.0 Ga to 7.0 − 0.5 + 0.7 ( 2 σ ) at the Archean–Proterozoic boundary, and to 7.9 − 0.2 + 0.1 ( 2 σ ) at the Proterozoic–Phanerozoic boundary. This evolution is driven by the secular decline of pCO₂, which in turn is a consequence of increasing solar luminosity, but is moderated by carbonate alkalinity delivered from continental and seafloor weathering. Archean seafloor weathering may have been a comparable carbon sink to continental weathering, but is less dominant than previously assumed, and would not have induced global glaciation. We show how these conclusions are robust to a wide range of scenarios for continental growth, internal heat flow evolution and outgassing history, greenhouse gas abundances, and changes in the biotic enhancement of weathering.

The next step on the path toward another Earth is to find atmospheres similar to those of Earth and Venus—high–molecular-weight (secondary) atmospheres—on rocky exoplanets. Many rocky exoplanets are born with thick (>10 kbar) H₂-dominated atmospheres but subsequently lose their H₂; this process has no known Solar System analog. We study the consequences of early loss of a thick H₂ atmosphere for subsequent occurrence of a high–molecular-weight atmosphere using a simple model of atmosphere evolution (including atmosphere loss to space, magma ocean crystallization, and volcanic outgassing). We also calculate atmosphere survival for rocky worlds that start with no H₂. Our results imply that most rocky exoplanets orbiting closer to their star than the habitable zone that were formed with thick H₂-dominated atmospheres lack high–molecularweight atmospheres today. During early magma ocean crystallization, high–molecular-weight species usually do not form long-lived high–molecular-weight atmospheres; instead, they are lost to space alongside H₂. This early volatile depletion also makes it more difficult for later volcanic outgassing to revive the atmosphere. However, atmospheres should persist on worlds that start with abundant volatiles (for example, water worlds). Our results imply that in order to find high–molecular-weight atmospheres on warm exoplanets orbiting M-stars, we should target worlds that formed H₂-poor, that have anomalously large radii, or that orbit less active stars.

Methane has been proposed as an exoplanet biosignature. Imminent observations with the James Webb Space Telescope may enable methane detections on potentially habitable exoplanets, so it is essential to assess in what planetary contexts methane is a compelling biosignature. Methane’s short photochemical lifetime in terrestrial planet atmospheres implies that abundant methane requires large replenishment fluxes. While methane can be produced by a variety of abiotic mechanisms such as outgassing, serpentinizing reactions, and impacts, we argue that—in contrast to an Earth-like biosphere—known abiotic processes cannot easily generate atmospheres rich in CH₄ and CO₂ with limited CO due to the strong redox disequilibrium between CH₄ and CO₂. Methane is thus more likely to be biogenic for planets with 1) a terrestrial bulk density, high mean-molecular-weight and anoxic atmosphere, and an old host star; 2) an abundance of CH₄ that implies surface fluxes exceeding what could be supplied by abiotic processes; and 3) atmospheric CO₂ with comparatively little CO.

A novel design of Kibble (watt) balance has been designed and is being constructed at the National Physical Laboratory. Lheory predicts that this type of balance will be simpler to construct and operate due to the removal of many of the alignment sensitivities present in existing balances. The balance uses a compact twisted pair coil in both the weighing and moving modes. This paper describes the design and manufacture of the coil and presents results of outgassing measurements made on the coil using a vacuum mass comparator.

Recent improvements in additive layer manufacturing (ALM) have provided new designs of geometrically complex structures with lighter materials and low processing costs. The use of additive manufacturing in spacecraft production is opening up many new possibilities in both design and fabrication, allowing for the reduction of the weight of the structure subsystems. In this aim, polymeric ALM structures can become a choice, in terms of lightweight and demisability, as far as good thermomechanical properties. Moreover, provided that fused-deposition modeling (FDM) is used, nanosats and other structures could be easily produced in space. However, the choice of the material is a crucial step of the process, as the final performance of the printed parts is strongly dependent on three pillars: design, material, and printing process. As a high-performance technopolymer, polyether ether ketone (PEEK) has been adopted to fabricate parts via ALM; however, the space compatibility of 3D-printed parts remains not demonstrated. This work aimed to realize a nanosat polymeric structure via FDM, including all the phases of the development process: thermomechanical design, raw material selection, printing process tuning, and manufacturing of a proof of concept of a technological model. The design phase includes the application of topology optimization to maximize mass saving and take full advantage of the ALM capability. 3D-printed parts were characterized via thermomechanical tests, outgassing tests of 3D-printed parts are reported confirming the outstanding performance of polyether ether ketone and its potential as a material for structural space application.

We present time-series observations of the split comet 240P/NEAT near perihelion, obtained using the Nordic Optical Telescope. The brighter component, 240P-A, has an estimated radius in the range 400–600 m, and loses dust at the peak rate 130 kg s−1. The ejected dust has characteristic size ∼50 μm, is expelled sunward at ∼25 m s−1, with a total ejected mass in the period of observation ∼1.5 × 109 kg. Mass loss from the fainter component, 240P-B, peaks at ∼35 kg s−1 and the total ejected mass was 2.3 × 108 kg. The radius of 240P-B is uncertain, with a best estimate ∼300 m and an absolute lower limit 50 m. 240P-A and 240P-B are currently separating at about 1 m s−1, a speed that is likely accelerating as a result of differential outgassing forces, and have a separation age of >3 yr. The splitting of 240P is incompatible with the action of tides, impact, and internal pressure build up. 240P fits a developing picture, in which small comets are destroyed by rotational instabilities triggered by outgassing torques, an explanation that can be tested in 240P by future observations.

Coastal ecosystems release or absorb carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O), but the net effects of these ecosystems on the radiative balance remain unknown. We compiled a dataset of observations from 738 sites from studies published between 1975 and 2020 to quantify CO2, CH4 and N2O fluxes in estuaries and coastal vegetation in ten global regions. We show that the CO2-equivalent (CO2e) uptake by coastal vegetation is decreased by 23–27% due to estuarine CO2e outgassing, resulting in a global median net sink of 391 or 444 TgCO2e yr−1 using the 20- or 100-year global warming potentials, respectively. Globally, total coastal CH4 and N2O emissions decrease the coastal CO2 sink by 9–20%. Southeast Asia, North America and Africa are critical regional hotspots of GHG sinks. Understanding these hotspots can guide our efforts to strengthen coastal CO2 uptake while effectively reducing CH4 and N2O emissions.The authors show that estuarine and coastal vegetation are collectively a greenhouse gas (GHG) sink for the atmosphere, but methane and nitrous oxide emissions counteract the carbon dioxide uptake. Critical coastal GHG sink hotspots are identified in Southeast Asia, North America and Africa.