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The significant energy consumption and contribution to greenhouse gas emissions by the construction sector need careful attention to explore innovative sustainable solutions for improving the energy efficiency and thermal comfort of building envelopes. The integration of phase-change materials (PCMs) into building commodities is a favorable technology for minimizing energy consumption and enhancing thermal performance. This review paper covers the impact of PCM incorporation into construction materials, such as walls, roofs, and glazing units. Additionally, it examines different embedding techniques like direct incorporation, immersion, macro and micro-encapsulation, and form and shape-stable PCM. Factors affecting the thermal performance of PCM-integrated buildings, including melting temperature, thickness, position, volumetric change, vapor pressure, density, optical properties, latent heat, thermal conductivity, chemical stability, and climate conditions, are elaborated. Furthermore, the latest experimental and numerical simulations, as well as modeling techniques, evident from case studies, are investigated. Ultimately, the advantages of PCM integration, including energy savings, peak load reduction, improvement in interior comfort, and reduced heating, ventilation, and air-conditioning dependence, are explained alongside the limitations. Finally, the recent progress and future potential of PCM-integrated construction materials are discussed, focusing on innovations in this field, addressing the status of policies in line with the United Nations Sustainable Development Goals, and outlining research potential for the future.

Phase change energy storage (PCES) materials have attracted considerable interest because of their capacity to store and release thermal energy by undergoing phase changes. This paper offers a thorough examination of the latest developments in PCES materials (PCESMs) and their wide‐ranging applications in several industries. The text focuses primarily on the most recent advances in the design and creation of PCESMs. It emphasizes the investigation of new phase change materials (PCMs) that possess specific features, such as high latent heat, thermal conductivity, and cycling stability. The study investigates advanced methods such as nano structuring, hybridization, and encapsulation to improve the efficiency and dependability of PCESMs. PCESMs are employed in the construction industry for passive solar heating, thermal regulation, and energy‐efficient building designs. They facilitate effective thermal dissipation in electronics, hence, improving the efficiency and durability of electronic devices. Moreover, PCESMs are essential in enabling the incorporation of intermittent energy sources like solar and wind power into the grid, hence, supporting renewable energy storage. Furthermore, the research examines upcoming patterns and potential outcomes in the domain of PCESMs, including the progress of versatile PCES composites, integration with intelligent materials, and breakthroughs in thermal energy conversion technologies. These advancements have enormous promise to tackle worldwide energy concerns, decrease greenhouse gas emissions, and promote sustainable development. Recent advancements in PCESMs have opened up opportunities for their extensive use in many industries, providing inventive solutions for effective energy storage, thermal regulation, and ecological sustainability. Ongoing research and technological breakthroughs in this field are anticipated to propel further advancements and facilitate the achievement of a more environmentally friendly and energy‐efficient future.

Over the past few years, the combination of solar power with refrigeration technology has matured, providing a promising solution for sustainable cooling. However, a key challenge remains, namely the inherent intermittency of solar energy. Due to its uneven temporal distribution, it is difficult to ensure continuous 24 h operation when relying solely on solar energy. To address this issue, thermal energy storage technology has emerged as a viable solution. This paper presents a comprehensive systematic review of phase-change material (PCM) applications in solar refrigeration systems. It systematically categorizes solar energy conversion methodologies and refrigeration system configurations while elucidating the fundamental operational principles of each solar refrigeration system. A detailed examination of system components is provided, encompassing photovoltaic panels, condensers, evaporators, solar collectors, absorbers, and generators. The analysis further investigates PCM integration strategies with these components, evaluating integration effectiveness and criteria for PCM selection. The critical physical parameters of PCMs are comparatively analyzed, including phase transition temperature, latent heat capacity, specific heat, density, and thermal conductivity. Through conducting a critical analysis of existing studies, this review comprehensively evaluates current research progress within PCM integration techniques, methodological classification frameworks, performance enhancement approaches, and system-level implementation within solar refrigeration systems. The investigation concludes by presenting strategic recommendations for future research priorities based on a comprehensive systematic evaluation of technological challenges and knowledge gaps within the domain.

Micro-thermoelectric coolers are emerging as a promising solution for high-density cooling applications in confined spaces. Unlike thin-film micro-thermoelectric coolers with high cooling flux at the expense of cooling temperature difference due to very short thermoelectric legs, thick-film micro-thermoelectric coolers can achieve better comprehensive cooling performance. However, they still face significant challenges in both material preparation and device integration. Herein, we propose a design strategy which combines Bi 2 Te 3 -based thick film prepared by powder direct molding with micro-thermoelectric cooler integrated via phase-change batch transfer. Accurate thickness control and relatively high thermoelectric performance can be achieved for the thick film, and the high-density-integrated thick-film micro-thermoelectric cooler exhibits excellent performance with maximum cooling temperature difference of 40.6 K and maximum cooling flux of 56.5 W·cm −2 at room temperature. The micro-thermoelectric cooler also shows high temperature control accuracy (0.01 K) and reliability (over 30000 cooling cycles). Moreover, the device demonstrates remarkable capacity in power generation with normalized power density up to 214.0 μW · cm −2  · K −2 . This study provides a general and scalable route for developing high-performance thick-film micro-thermoelectric cooler, benefiting widespread applications in thermal management of microsystems. The micro-thermoelectric coolers face challenges in high-performance material preparation and high-density device integration. Here, the authors combine Bi 2 Te 3 -based film prepared by powder direct molding with micro-thermoelectric cooler integrated via phase-change batch transfer.

Context Gallium, renowned for its notably low melting point and unique property of becoming liquid at room temperature, is a valuable constituent in phase change materials. In this study, we investigate the solid–liquid phase transition of gallium using the modified embedded atom method (MEAM) potential. It addresses the technique to compute the free energy difference between the solid and liquid without using a reference state. We examine various thermodynamic and dynamic properties, including density, specific heat capacity, diffusivity, and radial distribution functions. We compute the coexistence temperature of the solid–liquid phase transitions of gallium from free energy analysis. This information is crucial for understanding the behavior of the material under different pressure conditions and can be valuable for various applications, such as materials processing and high-pressure studies. The analysis, findings, and insights of the present work will be of great significance to the broad scientific and engineering communities in the field of phase transformation of materials. Methods A series of molecular dynamics(MD) simulations were conducted using the LAMMPS software packages. The gallium atoms are modeled using the modified embedded atom method (MEAM) potential. To accurately predict the solid–liquid phase transitions of gallium, we calculated free energy by employing the “constrained λ integration” method, coupled with multiple histogram reweighting (MHR). The solid–liquid coexistence line is determined through the Gibbs–Duhem integration technique.

Phase change materials (PCMs) have emerged as a key enabler of high-performance, low-carbon buildings through latent heat-based thermal energy storage. This paper presents a systematic and critical synthesis of advances in PCM technologies for building applications published between 2022 and 2025, analyzing over 300 peer-reviewed studies to evaluate thermal performance, economic viability, environmental impact, and climate adaptability across three integration approaches: passive, active, and hybrid systems. The studies analyzed show that passive envelope integration employing macroencapsulated or form-stable PCMs in walls, roofs, and glazing is reported to deliver 15–45% energy savings with payback periods of 8–15 years, primarily through enhanced thermal inertia and indoor temperature stabilization. Active systems, which couple PCMs with HVAC, heat pumps, or air handling units, are found to achieve 20–40% energy reductions and shorter payback periods (3–8 years) by enabling load shifting, peak shaving, and improved coefficient of performance (COP). Hybrid configurations integrating passive and active strategies with AI-driven control demonstrate, in the literature, the highest potential, with reported energy savings of up to 50%, though they entail greater complexity and capital cost. The review further highlights material-level innovations, including ternary composite PCMs, bio-based alternatives, and nano-enhanced formulations that address intrinsic limitations such as low thermal conductivity (0.1–0.3 W/m·K for organics) and cycling instability. Despite significant progress, critical gaps persist in standardized testing protocols, long-term field validation, comprehensive lifecycle assessments, and real-world scalability, particularly in tropical and cold climates. By bridging material science, building physics, and energy system engineering, this work provides a forward-looking roadmap to accelerate the deployment of PCM-based solutions in the global decarbonization of the built environment.

The increasing necessity for efficient and sustainable thermal management solutions in marine environments has attracted interest in nano-enhanced bio-based phase change materials NE BB-PCMs. This review explores the advancements in NEPCMs tailored for marine applications, emphasizing their potential to revolutionize energy storage and thermal regulation on marine vessels and platforms. These materials combine the high energy storage capacity of bio-based phase change materials (PCMs) with the enhanced thermal properties afforded by nanotechnology, offering a promising solution to improve energy efficiency, reduce fossil fuel dependence, and mitigate environmental impact in marine settings. Direct mixing, encapsulation, and in-situ synthesis methods are analyzed for their effectiveness in enhancing thermal conductivity and stability in harsh marine conditions. This paper discusses various nanoparticles, including carbon-based materials and metal oxides, optimizing the thermal characteristics of PCMs by increasing conductivity and reducing supercooling. Applications include thermal energy storage for desalination, temperature regulation on ships, and anti-icing coatings for marine structures. Challenges like biodegradability, cost, and long-term performance under marine conditions are addressed. This review highlights NEPCMs’ potential in improving sustainability and operational efficiency in the marine environment sector.

This review highlights the latest advancements in thermal energy storage systems for renewable energy, examining key technological breakthroughs in phase change materials (PCMs), sensible thermal storage, and hybrid storage systems. Practical applications in managing solar and wind energy in residential and industrial settings are analyzed. Current challenges and research opportunities are discussed, providing an overview of the field’s current and future state. Following the PRISMA 2020 guidelines, 1040 articles were initially screened, resulting in 49 high-quality studies included in the final synthesis. These studies were grouped into innovations in TES systems, advancements in PCMs, thermal management and efficiency, and renewable energy integration with TES. The review underscores significant progress and identifies future research directions to enhance TES’s efficiency, reliability, and sustainability in renewable energy applications.

The increasing concerns about CO2 emissions and climate change have pointed out the urgency of promoting sustainability in the building sector. One promising solution to enhance the energy efficiency of buildings and diminish environmental impact is the integration of phase-change materials (PCMs) into ventilated façade systems. This review article critically examines the current state of research on this innovative approach, with a particular focus on fire safety considerations. The paper explores the integration of PCM into ventilated façades, highlighting the potential for significant improvements in energy consumption, thermal comfort, and reductions in CO2 emissions. However, the flammability of PCMs introduces substantial fire safety challenges that must be addressed to ensure the safe application of this solution. The fire safety of both ventilated façades and PCMs is approached, followed by specific fire safety concerns when PCMs are integrated into ventilated façade systems. The conclusion states that while the integration of PCMs into ventilated façades offers substantial environmental benefits, attention to fire safety is essential. This necessitates the implementation of rigorous fire protection measures during the design and construction phases. By addressing both the environmental advantages and fire safety challenges, this review aims to provide a comprehensive understanding of the potential and limitations of PCM-integrated ventilated façades, offering valuable insights for researchers, engineers, and policymakers in the field of sustainable buildings.

This experimental study explores the integration of Phase Change Materials (PCMs) within building envelopes. The research specifically centers on the utilization of two microencapsulated paraffin-based PCMs with melting points of 37 °C and 43 °C. The study assesses their performance within cement and gypsum-based PCM composites, concentrating on service areas often overlooked in thermal analysis, including underground garages, staircases, and utility rooms. The experimental setup included constructing three chambers inside an underground garage during the hot months of June and July in Saudi Arabia. Two chambers were assigned to integrate the PCM, while the third chamber served as a control without PCM. The experiment unfolds in two phases. In the initial phase, the objective was to determine which PCM is more effective in reducing the heat load inside the chambers. This led to the adoption of the 43 °C PCM for the subsequent stage. The adoption of the 43 °C PCM resulted in a fourfold decrease in heat compared to the 37 °C PCM. The second phase investigates the integration of the selected PCM with cement and gypsum composites. The percentage of PCM incorporated into the concrete and gypsum composites was determined experimentally. For cement-based composites, the identified percentage that maintains material integrity is 20%, and for gypsum-based composites, it is 22%. The findings demonstrate a significant reduction in cooling load with PCM incorporation, with cement-based composites exhibiting superior thermal performance compared to gypsum-based alternatives and reducing the heat load by approximately 63%. Additionally, it was observed that concrete reduced the highest temperature during the day by 5.2 °C, which equates to about a 10% reduction, further enhancing comfort. Conducted over the course of two summer seasons, this study contributes valuable insights toward improving the quality of life for building occupants, considering various factors such as their living environment.