Explore the vast range of titles available.

The vulcanization of rubber compounds is an exothermal process. A carbon black-filled and natural rubber-based (NR) formulation was mixed with different levels of sulfur (0.5, 1.0, 2.0, 4.0 and 6.0 phr) and studied with differential scanning calorimetry (DSC) for the determination of the vulcanization enthalpy. It was found that the vulcanization enthalpy is dependent on the amount of sulfur present in the compound and the vulcanization heat released was −18.4 kJ/mol S if referred to the entire rubber compound formulation or −46.0 kJ/mol S if the heat released is referred only to the NR present in the compound. The activation energy for the vulcanization of the rubber compounds was also determined by a DSC study at 49 kJ/mol and found to be quite independent from the sulfur content of the compounds under study. A simplified thermochemical model is proposed to explain the main reactions occurring during the vulcanization. The model correctly predicts that the vulcanization is an exothermal process although it gives an overestimation of the vulcanization enthalpy (which is larger for the EV vulcanization package and smaller for the conventional vulcanization system). If the devulcanization is conducted mechanochemically in order to break selectively the sulfur-based crosslinks, then the natural rubber compounds recovered from used tires can be re-vulcanized again and the exothermicity of such process can be measured satisfactorily with DSC analysis. This paper not only proposes a simplified mechanism of vulcanization and devulcanization but also proposes an analytical method to check the devulcanization status of the recycled rubber compound in order to distinguish truly devulcanized rubber from reclaimed rubber.

The infrastructures that were constructed decades ago do not meet the present structural benchmark, and they need to be demolished. In order to reclaim these lands, the existing pile foundations must be removed; otherwise, the land will lose its value. Since the piles are pulled out, vacant spaces are created in the ground. This causes the surrounding ground to experience settlement, jeopardizing its stability. The degree of influence depends upon the number of boreholes, the saturated condition of the ground, the time period of the vacant condition, the presence of loading, etc. It is important to understand the scope of the probable settlement under various situations. This study focused on determining the amount of displacement and its range for three different saturated soil types under loaded and unloaded conditions using the finite element method (FEM) analysis. It was observed that stiff ground underwent maximum deformation, while soft ground experienced the maximum influence from external factors. Moreover, the presence of loading not only increased the displacement amount and range, but it also caused a change in the location of the maximum displacement.

The processing of Citrus grandis Osbeck cv. Mato Peiyu (CGMP) fruits generates a considerable amount of waste, mainly the flavedo, albedo, and segment membrane; the generated waste yields severe environmental and economic challenges. In this study, we tried to reclaim some functional chemicals from the waste. Our data indicated that the essential oil content in the flavedo was 0.76–1.34%, with the major component being monoterpenes (93.75% in August, declining to 85.56% in November, including mainly limonene (87.08% to 81.12%) and others such as β-myrcene). p-Synephrine (mg/100 g dry weight) declined accordingly (flavedo, 10.40 to 2.00; albedo, 1.80 to 0.25; segment membrane, 0.3 in August, 0.2 in September, and none since October). Polyphenols (in μg/g) included gallic acid (70.32–110.25, 99.27–252.89, and 105.78–187.36, respectively); protocatechuic acid (65.32–204.94, 26.35–72.35, and 214.98–302.65, respectively), p-coumaric acid (30.63–169.13, 4.32–17.00, and 6.68–34.32, respectively), ferulic acid (12.36–39.36, 1.21–10.25, and 17.07–39.63, respectively), and chlorogenic acid (59.19–199.36, 33.08–108.57, and 65.32–150.14, respectively). Flavonoids (in μg/g) included naringin (flavedo, 89.32–283.19), quercetin (181.05–248.51), nobiletin (259.75–563.7), hesperidin, and diosmin. The phytosterol content (mg/100 g) was 12.50–44.00 in the flavedo. The total dietary fiber in the segment membrane was 57 g/100 g. The antioxidant activity against the DPPH• and ABTS+• free radicals was moderately high. In conclusion, the waste of CGMP fruits is worth reclaiming for essential oil, p-synephrine, polyphenolics, and dietary fiber. Notably, p-synephrine content (flavedo: <8 mg/100 g dry weight, albedo: <2.0, or segment membrane: <0.4 mg) can serve as a marker of the internal maturation of CGMP fruits.

The issue of forming a reliable and stable structure of a crumb-rubber-modified binder is an important scientific and technical task. The authors supplemented existing concepts of the mechanism of effective interaction with rubber crumb by introducing a preliminary first stage: controlled partial physical destruction of rubber crumb—producing rubber reclaim. Proposed physical methods of rubber crumb destruction include high shear force (roll mills), high temperature, and a plasticizing medium. The controllability and degree of devulcanization of rubber were determined by acetone-chloroform extraction in different time intervals. The degree of devulcanization of rubber in the rubber reclaim was found to be 22 ± 0.24%, with stability over 14 days. It was found that the size of the particles of the rubber reclaim in the bitumen is less than 2 µm. The properties of the structure of the binder modified with rubber reclaim, characterizing the stability and sustainability, have been studied and established. The developed modified binders are stable in storage. Rheological parameters of the structure characterizing intermolecular interaction, such as shear stability for original and RTFOT-aged, modified bitumen, meet requirements of the state standard at test temperature 64 °C. The elastic structural component of the crumb-rubber-modified binder, as indicated by the relative irreversible deformation parameter J3,2, does not exceed 2.6 kPa (<4.5 kPa) at 64 °C. Additionally, it was determined that the rheological structural parameter for fatigue resistance, which characterizes the durability of road pavement under intensive operational conditions, does not exceed 4699 kPa (<5000 kPa) at 16 °C. The use of 10% rubber reclaim combined with waste frying oil provided the opportunity to obtain a modified binder with a stable and sustainable structure without the introduction of additional stabilizers and agents. Test results showed that the overall performance characteristics of the modified binder meet the 64(S)-40 grade standards.

Improper disposal and accumulation of waste tire rubbers have posed a serious threat to the development of a circular economy, a sustainable environment, and human health. In light of the drawback of the current waste management of waste tires, the recycling and transformation of reclaimed rubber (RR) into valuable end products has received significant attention from industries and the academic field. Herein, we propose a facile method to reuse RR in developing closed-cell elastomeric foams based on ethylene propylene diene rubber (EPDM). Rheometry results revealed that the introduction of RR up to 20 phr, increased the cure rate from 11.7 to 13.48%/min, reduced curing time from 12.21 to 9.3 min and also increased ultimate torque from 6.51 to 7.24 N.m. Morphological studies indicated that the RR increased the cell density from 12 to 78 cell/mm³ and reduced the number average cell size from 940 to 110 µm. The mechanical results indicated that the introduction of RR could be a feasible alternative for the fabrication of high-performance EPDM foams with improved hardness and resilience. By increasing RR content of EPDM/RR foams, the relative density and cell density of EPDM/RR foams increased, while cell size decreased. The introduction of 10 phr of RR, increased the hardness and resilience of the EPDM foam by 37 shore A and 68%, respectively. The research verified that the attempt to use RR to produce a good foam structure was found to be successful. The results open a way for EPDM/RR foam composites to be applied for sealing and gasket industries as an eco-friendly replacement for virgin products.

Climate change is impacting cities and urban regions in significant ways, and people living within them must work out how to live with and adapt to the changes they bring. Indigenous peoples are increasingly moving to and living in cities, yet how they experience climate change within them is not understood. While literature explores Indigenous experiences of climate change and how Indigenous knowledge is being used to combat it, this work is geographically located in rural and remote Indigenous territories—not cities. This paper presents the results of a review that sought to find out why this is the case. Our aim was to identify scholarship that discussed how Indigenous people are affected by climate change in cities. To do so, we undertake a narrative literature review, which analyses content to distil key concepts in the literature, which are then presented in the paper to form a narrative. We find a significant gap in the literature addressing Indigenous experiences and voices concerning climate change in cities. We argue that this is due to the ongoing legacy of settler colonization, which has erased Indigenous peoples from urban territories to the extent that even when they are visible, urban Indigenous people are characterized as inauthentic and vulnerable. We call for action to overturn this insidious form of urban nullius to reclaim and assert Indigenous voices on and about climate change and policy in cities.

The disposal of aged transformer insulating oils presents a significant environmental challenge due to the presence of diverse contaminants. This study proposes a novel biorefinery approach for reclaiming three aged transformer insulating oils, each with service periods ranging from 20 to 25 years, utilizing magnesium oxide (MgO) as a potent absorbent. The reclamation process involves a synergy of centrifugation, dehydration, and absorption with MgO, resulting in the substantial restoration of aged transformer insulating oils, imbuing them with desired insulating characteristics. Additionally, an adaptive neuro-fuzzy inference system (ANFIS) algorithm is developed to estimate the remaining life of transformers based on the properties of the reclaimed oil. This entails analyzing input variables, selecting the optimal combination based on their correlation with the degree of polymerization, and identifying optimal membership functions for the ANFIS model. The performance of the proposed ANFIS model is evaluated, demonstrating training and testing accuracies of 91.2% and 88.6%, respectively. Subsequently, the model is applied to assess transformer insulation and estimate expected life, offering valuable assistance to experts in transformer condition assessment. Overall, this algorithm presents a sustainable alternative to traditional methods for assessing transformer conditions and estimating expected life, thereby enhancing transformer maintenance practices and promoting environmental sustainability.

Bitumen is a commonly used material for road construction. According to environmental regulations, vegetable-based materials are applied for binder modification. Fluxed road bitumen containing a bio-flux oxidation product increases the consistency over time. The efficiency of crosslinking depends on the number of double bonds and their position in the aliphatic chain of fatty acid. The main goal of this paper was to examine the structural changes taking place during hardening bitumen with bio-flux additives. Two types of road bitumens fluxed with two different oxidized methyl esters of rapeseed oil were used in this study. Various chemical and rheological tests were applied for the fluxed-bitumen at different stages of oxygen exposure. The oxidation of rapeseed oil methyl ester reduced the iodine amount by about 10%–30%. Hardening of the fluxed bitumen generally results in an increase of the resins content and a reduction of the aromatics and asphaltenes. In the temperature range of 0 °C to 40 °C, bio-flux results with a much higher increase in the phase angle than in temperatures above 40 °C in the bitumen binder. The increase in the proportion of the viscous component in the low and medium binder temperature is favorable due to the potential improvement of the fatigue resistance of the asphalt mixture with such binders.

The foundry industry generates large amounts of waste when casting metal into sand moulds. An important issue is the activities that are related to the re-recovery of the grain matrix (the main component of the moulding sand) for realising subsequent technological cycles. This process is particularly important in the case of the expensive chromite matrix that is necessary for use in manganese steel casting. The effects of the reclamation treatments of spent alkali-phenolic binder sand were evaluated by scanning electron microscopy with EDS, analysing the chemical composition in micro areas and proving the loss of binder on the surfaces of the matrix grains. Tests were also performed using the main criteria for evaluating a reclaimed organic binder: sieve analysis and ignition loss. A thermogravimetric analysis study was performed to assess the change in the chromite character of the grain matrix under the influence of temperature. The effects of the reclamation measures were verified by making moulding compounds on a matrix of reclaimed sand and a mixture of reclaimed and fresh sand. The tests and analyses that were carried out indicated the direction of an effective method for reclaiming used alkali-phenolic binder masses and the extent of the proportion of the regenerate in moulding sand in order to maintain the relevant technological parameters of the moulding sand.

Access to comprehensive municipal pound, animal welfare shelters, and rescue group data for admissions and outcomes for stray and owner-relinquished cats in Australia is currently lacking. This hinders effective assessment of existing management strategies for domestic cats by animal management agencies. Our study aimed to estimate the numbers of cat admissions and intakes to Australian municipal council pounds, animal welfare organizations (excluding smaller animal welfare organizations thought to have annual cat intakes of less than 500), and animal rescue groups and their respective outcomes for 2018–2019 (pre-COVID). Unavailable municipal council data were imputed based on known data and council human populations. Only Victoria and New South Wales had publicly available municipal data, and only RSPCA had publicly available data in all states. We estimated a total of 179,615 (7.2/1000 human residents) admissions to pounds, shelters, and rescue groups in 2018–2019, with an estimated 5% reclaimed, 65% rehomed, and 28% euthanized. Reclaim rates were low across all the agencies. Councils operating their own pound had nearly double the euthanasia rate (estimated at 46%) compared to animal welfare organizations (25%). Rescue groups rehomed an estimated 35% of the total number of cats rehomed by all agencies. The upper quartiles of councils with intakes of >50 cats in Victoria and New South Wales had estimated euthanasia rates from 73% to 98%, and 67% to 100%, respectively. We recommend that comprehensive municipal pound, shelter, and rescue statistics be routinely calculated using standardized methods and made available publicly in a timely fashion. This would inform management strategies to optimize live outcomes and therefore reduce the negative mental health impacts on staff tasked with euthanizing healthy and treatable cats and kittens.