Explore the vast range of titles available.

Soil erosion within agricultural landscapes has significant environmental and economic impacts and is strongly driven by reduced residue cover in agricultural fields. Large-area soil erosion models such as the Daily Erosion Project are important tools for understanding the patterns of soil erosion, but they rely on the accurate estimation of crop residue cover over large regions to infer the tillage practices, an erosion model input. Remote sensing analyses are becoming accepted as a reliable way to estimate crop residue cover, but most use localized training datasets that may not scale well outside small study areas. An alternative source of training data may be commonly conducted tillage surveys that capture information via rapid “windshield” surveys. In this study, we utilized the Google Earth Engine to assess the utility of three crop residue survey types (windshield tillage surveys, windshield binned residue surveys, and photo analysis surveys) and one synthetic survey (retroactively binned photo analysis data) as sources of training data for crop residue cover regressions. We found that neither windshield-based survey method was able to produce reliable regressions but that they can produce reasonable distinctions between low-residue and high-residue fields. On the other hand, both photo analysis and retroactively binned photo analysis survey data were able to produce reliable regressions with r2 values of 0.57 and 0.56, respectively. Overall, this study demonstrates that photo analysis surveys are the most reliable dataset to use when creating crop residue cover models, but we also acknowledge that these surveys are expensive to conduct and suggest some ways these surveys could be made more efficient in the future.

Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) is an extraction and clean-up technique originally developed for recovering pesticide residues from fruits and vegetables. Since its introduction, and until December 2013, about 700 papers have been published using the QuEChERS technique, according to a literature overview carried out using SciFinder, Elsevier SciVerse, and Google search engines. Most of these papers were dedicated to pesticide multiresidue analysis in food matrices, and this topic has been thoroughly reviewed over recent years. The QuEChERS approach is now rapidly developing beyond its original field of application to analytes other than pesticides, and matrices other than food, such as biological fluids and non-edible plants, including Chinese medicinal plants. Recently, the QuEChERS concept has spread to environmental applications by analyzing not only pesticides but also other compounds of environmental concern in soil, sediments, and water. To the best of our knowledge, QuEChERS environmental applications have not been reviewed so far; therefore, in this contribution, after a general discussion on the evolution and changes of the original QuEChERS method, a critical survey of the literature regarding environmental applications of conventional and modified QuEChERS methodology is provided. The overall recoveries obtained with QuEChERS and other extraction approaches (e.g., accelerated solvent extraction, ultrasonic solvent extraction, liquid/solid extraction, and soxhlet extraction) were compared, providing evidence for QuEChERS higher recoveries for various classes of compounds, such as biopesticides, chloroalkanes, phenols, and perfluoroalkyl substances. The role of physicochemical properties of soil (i.e., clay and organic carbon content, as well as cation exchange capacity) and target analytes (i.e., log K OW , water solubility, and vapor pressure) were also evaluated in order to interpret recovery and matrix effect data.

Pesticides are chemicals used to control different types of pests. Though pesticides played a role in improving the quantity and quality of production, they have been threatening ecosystems and posed effects on humans in different parts of the world. Unfortunately, there were no studies made about the effects of pesticide residues on ecosystems and consumers in the Fogera District of Amhara Region, Ethiopia. Hence, the main objective of this study was to understand the knowledge, attitude, and practices of respondents about the effects of pesticide residues on ecosystems and consumers. A cross-sectional survey complemented by focus group discussions and field observations was used to gather the required data for the study. The close-ended data were analyzed using descriptive statistics, logistic regressions, and independent t-test, and data from open-ended questions were grouped and summarized based on their similarities. The findings of the study confirmed that there was significant knowledge, attitude, and practices difference between farmers and consumers about the effects of pesticide residues on ecosystems and humans. Farmers used highly toxic pesticides to control pests and improve the glossiness of vegetables and khat. Though they didn’t use the sprayed vegetables for their home consumption, some of the farmers deliberately supplied pesticide-sprayed vegetables without worrying about the negative effects of the pesticides on the consumers. There were also fishing practices from rivers after intoxicating the fish using the pesticide sprayed feed. This, in turn, might poison individuals who consume the fish. In general, pesticide application practices and consumption of pesticide-sprayed foodstuffs and surface water might pose serious health risks to ecosystems and humans. To minimize the negative effects of pesticides, rigorous awareness-raising on the effects and management of pesticides, enforcement of laws, delineation of the pesticide free buffer zone for waters, the establishment of a clear pesticide supply chain to the end users, ecosystem assessment and food safety monitoring schemes are highly required.

Pesticide use and pesticide residues in foods have been the subject of controversial public discussions and media coverage in Germany. Against this background, a better understanding of public risk perceptions is needed to promote efficient public health communication. To this end, this study captures the German public's perception of pesticide residues in foods. A representative sample of the population aged 14 years and older (n = 1,004) was surveyed via computer-assisted telephone interviewing on their attitudes and knowledge with regard to pesticide residues. Based on questions regarding their typical consumer behavior, respondents were classified into conventional and organic consumers to identify differences as well as similarities between these two consumer types. As assessed with an open-ended question, both organic and conventional consumers viewed pesticides, chemicals, and toxins as the greatest threats to food quality and safety. Evaluating the risks and benefits of pesticide use, more than two-thirds of organic consumers (70%) rated the risks as greater than the benefits, compared with just over one-half of conventional consumers (53%). Concern about the detection of pesticide residues in the food chain and bodily fluids was significantly higher among organic compared with conventional consumers. Only a minority of respondents was aware that legal limits for pesticide residues (referred to as maximum residue levels) exist, with 69% of organic and 61% of conventional consumers believing that the presence of pesticide residues in foods is generally not permitted. A lack of awareness of maximum residue levels was associated with heightened levels of concern about pesticide residues. Finally, general exposure to media reporting on pesticide residues was associated with more frequent knowledge of legal limits for pesticide residues, whereas actively seeking information on pesticide residues was not. The possible mechanisms underlying these findings are discussed.

The present study investigated the concentrations of residues of four groups of pesticides in the People's Republic of China: organophosphorus, carbamate, pyrethroid, and triazine pesticides. Twenty-six pesticides were examined using gas chromatography-tandem mass spectrometry and liquid chromatography-tandem mass spectrometry in 2,169 samples of 12 typical vegetables collected from 15 provinces in China. The results showed that 908 (41.9%) samples were positive, with 133 (6.1%) samples exceeding the limit legal in China. Leafy vegetables showed higher positive rates than fruits and root vegetables. Organophosphorus, carbamate, pyrethroid, and triazine pesticides were found in 11.8, 7.7, 13.9, and 10.9% of the samples, respectively, which provided important information on current concentrations of cumulative assessment group pesticide residues for vegetables in China. Of the positive samples, a slight violation rate of 1.9% for the organophosphorus pesticide category exceeded China's maximum residue limits. Positive rates for chlorpyrifos in celery, pak-choi, and leeks were higher, but fewer exceeded China's maximum residue limits.

China’s croplands have experienced drastic changes in management practices, such as fertilization, tillage, and residue treatments, since the 1980s. There is an ongoing debate about the impact of these changes on soil organic carbon (SOC) and its implications. Here we report results from an extensive study that provided direct evidence of cropland SOC sequestration in China. Based on the soil sampling locations recorded by the Second National Soil Survey of China in 1980, we collected 4,060 soil samples in 2011 from 58 counties that represent the typical cropping systems across China. Our results showed that across the country, the average SOC stock in the topsoil (0–20 cm) increased from 28.6 Mg C ha−1 in 1980 to 32.9 Mg C ha−1 in 2011, representing a net increase of 140 kg C ha−1 year−1. However, the SOC change differed among the major agricultural regions: SOC increased in all major agronomic regions except in Northeast China. The SOC sequestration was largely attributed to increased organic inputs driven by economics and policy: while higher root biomass resulting from enhanced crop productivity by chemical fertilizers predominated before 2000, higher residue inputs following the large-scale implementation of crop straw/stover return policy took over thereafter. The SOC change was negatively related to N inputs in East China, suggesting that the excessive N inputs, plus the shallowness of plow layers, may constrain the future C sequestration in Chinese croplands. Our results indicate that cropland SOC sequestration can be achieved through effectively manipulating economic and policy incentives to farmers.

A total of 30 samples of filet green beans ( Phaseolus vulgaris ) from various popular markets in the Souss-Massa region (Morocco) were analyzed during 2021 for the presence of pesticide residues. We performed a QuEChERS extraction (Quick, Easy, Cheap, Effective, Rugged, and Safe) combined with Liquid Chromatography-Mass Spectrometry (LC–MS/MS) and Gas Chromatography-Mass Spectrometry (GC–MS/MS). The method was validated in accordance with SANTE 11312/2021 guidelines. The results of this survey indicated that 8 out of 30 green bean samples are positives (0.015 to 0.112 mg/kg). Azoxystrobin was the most frequently detected pesticide, occurring in 5 samples. For authorized pesticides, none of the samples exceeded the European Maximum residue level (EU MRL) in green beans, but residue of fipronil-unauthorized substance was detected in one sample at 0.027 mg/kg. Hence, it is important to increase inspections for locally marketed fresh green beans and align agricultural practices with regulatory requirements.

Soil organic carbon (SOC) loss is one of the main causes of soil degradation in croplands. Thus, spatial and temporal monitoring of SOC is extremely important, both from the environmental and economic perspective. In this regard, the high temporal, spatial, and spectral resolution of the Sentinel-2 data can be exploited for monitoring SOC contents in the topsoil of croplands. In this study, we aim to test the effect of the threshold for a spectral index linked to soil moisture and crop residues on the performance of SOC prediction models using the Multi-Spectral Instrument (MSI) Sentinel-2 and the European Land Use/cover Area frame Statistical survey (LUCAS) topsoil database. The LUCAS spectral data resampled according to MSI/Sentinel-2 bands, which were used to build SOC prediction models combining pairs of the bands. The SOC models were applied to a Sentinel-2 image acquired in North-Eastern Germany after removing the pixels characterized by clouds and green vegetation. Then, we tested different thresholds of the Normalized Burn Ratio 2 (NBR2) index in order to mask moist soil pixels and those with dry vegetation and crop residues. The model accuracy was tested on an independent validation database and the best ratio of performance to deviation (RPD) was obtained using the average between bands B6 and B5 (Red-Edge Carbon Index: RE-CI) (RPD: 4.4) and between B4 and B5 (Red-Red-Edge Carbon Index: RRE-CI) (RPD: 2.9) for a very low NBR2 threshold (0.05). Employing a higher NBR2 tolerance (higher NBR2 values), the mapped area increases to the detriment of the validation accuracy. The proposed approach allowed us to accurately map SOC over a large area exploiting the LUCAS spectral library and, thus, avoid a new ad hoc field campaign. Moreover, the threshold for selecting the bare soil pixels can be tuned, according to the goal of the survey. The quality of the SOC map for each tolerance level can be judged based on the figures of merit of the model.

Pesticide residues in food comprise compounds such as insecticides, fungicides, herbicides, miticides, and plant activators. The insecticides diazinon (O, O-diethyl O -2-isopropyl-6-methylpyrimidin-4-yl phosphorothioate) and malathion (O, O-dimethyl dithiophosphate of diethyl-mercaptosuccinate) are classified as probably carcinogenic (Group 2A) and the fungicides chlorothalonil (2,4,5,6-tetrachloro-1,3-benzenedicarbonitrile) and hexachlorobenzene (pentachlophenyl chloride) as possibly carcinogenic to humans (Group 2B) by the International Agency for Research on Cancer under the World Health Organization. In this study, gas chromatographic and gas chromatography-tandem mass spectrometric analyses were used to determine the concentrations of pesticide residues in agricultural products and assess the effects of chronic human exposure to pesticide residues through the consumption of agricultural products during 2018–2020. Food consumption data were obtained from the Korea National Health and Nutrition Examination Survey of 2016–2018. The chronic exposures determined using mean consumption data for the whole population and mean concentrations of the pesticide residues were 5.15E−11 to 2.08E−05 [lower bound (LB)] and 2.41E−07 to 4.69E−05 mg/kg bw/day [upper bound (UB)], corresponding to 0.00012–2.16% of the hazard index (HA). Exposures to pesticide residues, calculated using the 95th percentile of the consumption data, were 0–8.76E−05 (LB) and 9.26E−07 to 1.56E−04 mg/kg bw/day (UB), corresponding to 0.00045–9.41% of the HA. Based on the result of current exposure assessment, it could be considered that the pesticide residues in agricultural products are properly controlled by the regulatory authorities.

Open burning of agricultural residue adversely impacts climate change, air quality, and public health. Considering this, the current study examines the public and farmer’s perceptions about crop residue burning (CRB), including the obstacles to sustainable crop residue management practices and health implications in Haryana, India. A questionnaire-based survey was conducted with 418 study participants, having 56.1% of respondents as male and 43.4% as female. Results indicate a statistically significant association between CRB, socio-demographic factors, and respiratory issues. The study found that respiratory problems caused by CRB were more severe in the 60 + age group (93.3%) and the < 18 age group (70%). There is a mixed response from males (64%) and females (67.6%) regarding the impact of CRB on respiratory health. The study cites a variety of reasons for not adopting alternative technologies for crop residue management which include high cost (48%), followed by the unavailability of alternative technology (22%) and the belief that alternative technologies are not beneficial for timely clearing crop residues (13%). The minimum compensation required by farmers to avoid CRB varies significantly among respondents, with 45% citing INR 10,000 ($120) per acre as the minimum amount. The study also appraises behavioral and societal aspects of adopting new technologies. It was reported that government schemes have implementation challenges, but recycling crop residues for commercial use has a considerable scope. Considering this, the study also discusses the way ahead in light of the various initiatives the government has taken up for sustainable crop residue management.