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The end-of-life (EoL) management of solar panel waste has emerged as an important issue related to first-generation solar panels in South Korea, which have already entered their retirement stage. In this study, the sustainability impacts of three scenarios for recycling EoL solar panels, namely mechanical recycling (MR), chemical recycling (CR), and thermal recycling (TR), were investigated, and their environmental and economic benefits were evaluated using the life cycle sustainability assessment (LCSA) method, with landfilling as the reference scenario. The results obtained showed a high global warming potential (GWP) as well as acidification for MR owing to the additional burden of transportation and industrial processes associated with MR. For CR, the use of chemicals and subsequent landfilling resulted in approximately 4.7 times higher terrestrial eco-toxicity than was observed for the landfilling scenario. Further, the GWP of TR was approximately 1.5 times higher than that of CR owing to its high energy consumption. However, its environmental burden was generally lower than that of MR and CR. The results of this study, which capture the current situation of EoL PV panels in South Korea, can be employed to facilitate the establishment of regulations that ensure sustainable management in this regard.

This review examines the technological surveillance of photovoltaic panel recycling through a bibliometric study of articles and patents. The analysis considered the number of articles and patents published per year, per country, and, in the case of patents, per applicant. This analysis revealed that panel recycling is an increasingly prominent research area. However, the number of patents filed annually has varied in recent years, averaging fewer than 200 per year. The state-of-the-art review identified three main types of treatment for photovoltaic panel recycling: mechanical, chemical, and thermal. Among these, mechanical treatment serves as a preliminary stage before the recovery of valuable elements, which is achieved through chemical or thermal processes. The articles reviewed cover a range of processes, including hydrometallurgical and pyrometallurgical methods, and explore various classification processes, solvents, and oxidizing agents. In contrast, patents predominantly focus on pyrometallurgical processes. This analysis is supplemented by a survey of market-ready technologies, many of which include stages such as size reduction or delamination followed by pyrometallurgical processes. Additionally, the review highlights the collection processes implemented by some companies, noting that the volume of panels considered waste is currently insufficient to maintain a continuous and year-round operational process. This study identifies key challenges such as (i) reducing solar panel size due to the EVA polymer complicating conventional machinery use, (ii) high process costs from the need for high temperatures and costly additives, (iii) the environmental impact of thermal treatments with high energy consumption and air pollution, and (iv) the necessity for environmentally friendly solvents in hydrometallurgical treatments to reduce contamination during recycling. Future directions include developing specific machinery for panel size reduction, either creating or modifying a polymer to replace EVA for easier treatment, adopting hydrometallurgical treatments with green solvents proven effective in recycling minerals and electronic waste, and addressing the lack of detailed information on industrial processes to make more precise recommendations.

The production of photovoltaic modules is increasing to reduce greenhouse gas emissions. However, this results in a significant amount of waste at the end of their lifespan. Therefore, recycling these solar panels is important for environmental and economic reasons. However, collecting and separating crystalline silicon, cadmium telluride, and copper–indium–gallium–selenide panels can be challenging, especially in underdeveloped countries. The innovation in this work is the development of a process to recycle all solar panel waste. The dissolution of all metals through the leaching process is studied as the main step of the flowchart. In the first step of leaching, 98% of silver can be recovered by 0.5 M nitric acid. Then, the second and third step involves the use of glycine for base metal dissolution, followed by the leaching of valuable metals with hydrochloric acid. The effect of parameters such as the initial pH, acid concentration, solid/liquid ratio, and hydrogen peroxide concentration is studied. The results show that up to 100% of Cu, Pb, Sn, Zn, Cd, In, Ga, and Se can be recovered under optimal conditions. The optimal conditions for the dissolution of Cu, Zn, and Cd were a glycine concentration of 0.5 M, a temperature of 25 °C, a solid/liquid ratio of 10 gr/L, and 1% of hydrogen peroxide. The optimized glycine concentration for the leaching of lead and tin was 1.5 M. Indium and gallium were recovered at 100% by the use of 5 M hydrochloric acid, S/L ratio = 10 gr/L, and T = 45 °C. Separation of selenium and tellurium occurred using 0.5 M HCl at a temperature of 60 °C. Additionally, for the first time, a general outlook for the recycling of various end-of-life solar panels is suggested.

This paper proposes a cost estimation model for a mechanical solar panel recycling plant with multiple integrated processes. A sensitivity analysis evaluates various plant capacity scenarios, assumed by the expected market share percentage within the targeted country. A mixed-integer linear programming model is applied to optimize the equipment mix for each process, minimizing capital expenditure. For operating expenditure, a linear regression model estimates fixed, and variable costs based on the quantity of processed solar panels. Thailand, a country with high renewable energy penetration, serves as the case study. The empirical results highlight the significance of economies of scale, indicating that higher plant capacities (i.e., larger market shares) enhance project feasibility. The analysis indicates that the project becomes viable starting with a 15% market share, achieving an expected net present value of 130 thousand U.S. dollars and an internal rate of return of 8 percent. Additionally, the study demonstrates the environmental benefits of the recycling plant, projecting a reduction of 3,008 tons of CO2 emissions over a 20-year project lifecycle. The empirical findings provide valuable quantitative support for policymakers aiming to reduce greenhouse gas emissions and achieve net-zero goals in the energy sector, promoting sustainable waste management and renewable energy practices.

The transition towards renewable energy is not as impressive as expected when considering the wide array of efforts undertaken. Energy-abundant countries do not have sufficient stimuli to curb the use of fossil fuels; some of them even work on increasing international supply. Greenhouse gas emissions remain high. As the world population grows, more attention must be devoted to the transition towards renewables. This transition requires additional resources and leaves behind waste that must be recycled. Without a circular economy, the transition towards renewable energy will require extra power, resulting in a spiral that is very detrimental to the environment of our planet. This paper provides a picture of the current situation, discusses tendencies, and systemizes issues that must be tackled.

This review addresses the growing need for the efficient recycling of crystalline silicon photovoltaic modules (PVMs), in the context of global solar energy adoption and the impending surge in end-of-life (EoL) panel waste. It examines current recycling methodologies and associated challenges, given PVMs’ finite lifespan and the anticipated rise in solar panel waste. The study explores various recycling methods—mechanical, thermal, and chemical—each with unique advantages and limitations. Mechanical recycling, while efficient, faces economic and environmental constraints. Thermal methods, particularly pyrolysis, effectively break down organic materials but are energy-intensive. Chemical processes are adept at recovering high-purity materials but struggle with ecological and cost considerations. The review also highlights multifaceted challenges in recycling, including hazardous by-product generation, environmental impact, and the economic feasibility of recycling infrastructures. The conclusion emphasizes the need for innovative, sustainable, and economically viable recycling technologies. Such advancements, alongside global standards and policy development, are crucial for the long-term sustainability of solar energy and effective management of PVM waste.

The increasing adoption of renewable energy sources in Malaysia is anticipated to drive the demand for solar panel installations. Addressing the sustainable disposal of solar panels, with their typical lifespan of 20 to 25 years, is crucial to mitigate landfill issues. This study investigates thermal treatment using a patented solar panel pyrolysis reactor to disintegrate solar panel components with reduced energy consumption. By implementing controlled conditions, pyrolysis emerges as a practical solution for the safe disintegration of end-of-life solar panels. The modes of operation and pyrolysis temperature for the solar pyrolysis process were varied to find the best operation of the solar pyrolysis system. The modes of operation used were hybrid heating with heat recovery, hybrid heating without heat recovery, and single heating without heat recovery, and temperatures used were 250°C, 350°C and 450°C. The results show 99.5% of the solar panel material recovered at 450°C for 4 hours and 20 minutes. The material separation process yielded wt. 79% of glass, wt. 13% of binder & other, wt. 7% silicon, wt. 1% of metal. The findings suggest the potential for developing and commercialising solar panel pyrolysis systems on a larger scale, offering promising solutions for end-of-life solar panels with higher heat and energy efficiency. Further research and investment in scaling up this process could significantly contribute to the environmental sustainability of the solar energy industry, supporting the circular economy principles and reducing the environmental impact of solar panel disposal.

The article presents the developed technology for the comprehensive recycling of depleted, used or damaged photovoltaic (PV) cells made of crystalline silicon. The developed concepts of technology and the results of research on recycling were presented on silicon photovoltaic cells and modules. The sequence of steps and the type of procedures used are proposed. A thermal delamination method for used commercial photovoltaic modules has been developed to separate the materials. In addition, a recycling line was proposed along with the selection of machines and a holistic approach to project profitability based on a SWOT analysis. The presented semi-automatic installation enables recycling on a laboratory scale. The line was designed for the assumed capacity of 30 t/h. The total energy demand for the designed line was calculated, which showed that 16.49 kWh is needed to recycle 1 ton of photovoltaic laminates. Implementation of developed solutions on an industrial scale will allow to reduce production costs, mainly thanks to energy savings, which translates into less devastation of the natural environment and reduced material consumption. In addition, the implementation of the PV module recycling system will reduce and, consequently, eliminate a significant amount of used PV devices deposited in landfills. The content of the article gives a fresh and innovative look at the essence of photovoltaic panel recycling processes in terms of production benefits as well as financial and environmental benefits.

Transformation of waste into resources is an important part of the circular economy. Nowadays, the recovery of materials in the most effective way is crucial for sustainable development. Composite materials offer great opportunities for product development and high performance in use, but their position in a circular economy system remains challenging, especially in terms of material recovery. Currently, the methods applied for recycling composites are not always effective. The aim of the article is to analyse the most important methods of material recovery from multilateral composites. The manuscript presents three case studies related to the recycling of products manufactured from composites: used tyres, wind turbine blades, and solar panels. It shows the advantages and disadvantages of currently applied methods for multilateral composite utilisation and presents further trends in composite recycling. The results show that increasing volumes of end-of-life composites have led to increased attention from government, industry, and academia.

Academics predict that a significant volume of end-of-life (EOL) photovoltaic (PV) solar panel waste will be generated in the coming years due to the significant rise in the production and use of PV solar panels since the late 20th Century. This study focuses on identifying a sustainable solution for the management of EOL PV solar panel waste by triangulating the information collected on areas such as the current state, the key barriers, and the key enablers with respect to managing EOL PV solar panel waste, specifically in Western Australia (WA). The data were collected using online survey questions and interviews with users of PV solar panels, sellers of PV solar panels, recyclers of PV solar panels, and local governments in Western Australia. Findings reveal that although there is a low generation of PV solar panel waste at present, it is concerning that WA lacks systems and infrastructure to manage this waste. Introducing and implementing an Extended Producer Responsibility (EPR) policy, banning EOL PV solar panels from landfills, and, finally, increasing financial investment in this study area through grants, subsidies, and loans could be a sustainable solution for the management of EOL PV solar panel waste in WA.