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Binders are important construction materials, especially with plant-based granulates and fibers. A binder is chosen for its physical and chemical properties to be compatible with some construction requirements. New market trends show that green binders meet global sustainability targets, which is a step towards greener buildings and a greener environment. This study presents a cradle-to-gate comparative life cycle assessment (LCA) of synthetic binders (Polyvinyl Acetate (PVA) and Carboxymethyl Cellulose (CMC)) and agriculture starch-based binders made from cassava, wheat, and corn. The LCA was conducted using SimaPro software based on ISO 14040/14044 standards using the ReCiPe Midpoint and CML IA Baseline method. The assessment is cradle-to-gate with a binder production function unit of 1 kg. Key environmental sustainability metrics like Global Warming Potential (GWP) and Acidification Potential (AP) are assessed to rank the binder sustainability against each other. The results show that synthetic binder PVA has the highest environmental impact in almost all impact categories, especially GWP (6.55 kg CO eq in ReCiPe and 6.37 kg CO eq in CML) and AP (0.012 kg SO eq in ReCiPe and 0.015 kg SO eq in CML). Among natural binders, Corn Starch shows the lowest environmental impact with GWP values of 0.930 kg CO eq (ReCiPe) and 0.896 kg CO eq (CML) and AP values of 0.010 kg SO eq (ReCiPe) and 0.016 kg SO eq (CML). The agricultural binders (Cassava Starch, Wheat Starch, and Corn Starch) are environmentally friendlier than the synthetic binders (PVA and CMC). Although agricultural binders carry environmental costs associated with farming operations, they have lower environmental impacts than synthetic alternatives, demonstrating their sustainability potential in binder applications.

This paper focuses on the thermal behavior of the starch-based binder (Albertine F/1 by Hüttenes-Albertus) used in foundry technology of molding sand. The analysis of the course of decomposition of the starch material under controlled heating in the temperature range of 25-1100°C was conducted. Thermal analysis methods (TG-DTG-DSC), pyrolysis gas chromatography coupled with mass spectrometry (Py-GC/MS) and diffuse reflectance spectroscopy (DRIFT) were used. The application of various methods of thermal analysis and spectroscopic methods allows to verify the binder decomposition process in relation to conditions in the form in both inert and oxidizing atmosphere. It was confirmed that the binder decomposition is a complex multistage process. The identification of CO2 formation at set temperature range indicated the progressive process of decomposition. A qualitative evaluation of pyrolysis products was carried out and the course of structural changes occurring in the presence of oxygen was determined based on thermo-analytical investigations the temperature of the beginning of binder degradation in set condition was determined. It was noticed that, significant intensification of Albertine F/1 sample decomposition with formation of more degradation products took place at temperatures above 550ºC. Aromatic hydrocarbons were identified at 1100ºC.