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Binders are important construction materials, especially with plant-based granulates and fibers. A binder is chosen for its physical and chemical properties to be compatible with some construction requirements. New market trends show that green binders meet global sustainability targets, which is a step towards greener buildings and a greener environment. This study presents a cradle-to-gate comparative life cycle assessment (LCA) of synthetic binders (Polyvinyl Acetate (PVA) and Carboxymethyl Cellulose (CMC)) and agriculture starch-based binders made from cassava, wheat, and corn. The LCA was conducted using SimaPro software based on ISO 14040/14044 standards using the ReCiPe Midpoint and CML IA Baseline method. The assessment is cradle-to-gate with a binder production function unit of 1 kg. Key environmental sustainability metrics like Global Warming Potential (GWP) and Acidification Potential (AP) are assessed to rank the binder sustainability against each other. The results show that synthetic binder PVA has the highest environmental impact in almost all impact categories, especially GWP (6.55 kg CO eq in ReCiPe and 6.37 kg CO eq in CML) and AP (0.012 kg SO eq in ReCiPe and 0.015 kg SO eq in CML). Among natural binders, Corn Starch shows the lowest environmental impact with GWP values of 0.930 kg CO eq (ReCiPe) and 0.896 kg CO eq (CML) and AP values of 0.010 kg SO eq (ReCiPe) and 0.016 kg SO eq (CML). The agricultural binders (Cassava Starch, Wheat Starch, and Corn Starch) are environmentally friendlier than the synthetic binders (PVA and CMC). Although agricultural binders carry environmental costs associated with farming operations, they have lower environmental impacts than synthetic alternatives, demonstrating their sustainability potential in binder applications.

Bituminous binders are thermal-dependent visco-elastic materials commonly used in pavement engineering. However, synthetic binders represent quite a new family of products that can be used in the substitution of conventional binders with various purposes. Among them, clear synthetic resins recently experienced a quick diffusion since they can be employed in the production of sustainable road pavements (which address aesthetic concerns, thermal aspects, etc.). Since specific studies addressing the rheological modeling of clear synthetic binders cannot be found in the literature, the purpose of this research is setting up an advanced rheological protocol to characterize such materials, bridging the existing knowledge gap. An extensive laboratory investigation with the dynamic shear rheometer was carried out in oscillatory mode (amplitude and frequency sweeps) to analyze the stress–strain state of such binders. An innovative test at a constant strain rate was used to construct non-linear master curves, overcoming various criticisms about the stress state of the binder when subjected to time-dependent deformations. Results indicated that, using non-linear data, horizontal and vertical shift factors (functions of temperature and strain rate) can be modeled through power law equations to obtain the master curves. This method was considered suitable for depicting the rheological response of the binders displaying such complex behaviors.

A method is proposed for producing carbon adsorbent as an extrudate based on heavy petroleum tar and various carbon fillers. To obtain sorbent granules, a heavy tar suspension is dissolved in excess heptane. With continuous mixing, filler is added to the solution, followed by concentrated sulfuric acid. After the formation of binder from the tar, the solid product is isolated. Green granules are extruded from the paste and then carbonized, with subsequent activation by steam. The proportions corresponding to carbon granules with the best specific surface (up to 900 m 2 /g) and mechanical strength are as follows: a 0.5 : 1 ratio of tar and filler; and a 1 : 1 ratio of acid and tar (by mass in both cases).When using two different fillers—walnut shell and coke from heavy tar—differences are noted in the micropore and mesopore structure of the carbon granules after activation: the samples based on coke have a more uniform micropore structure, with fewer mesopores. Since the parameters—the tar properties and the component ratios—may be closely controlled in the course of production, carbon granules with stable characteristics (specific surface, mechanical strength) may be produced.

Jackfruit latex gum was applied to pigment printing of cotton fabrics as a binder and their printing properties were compared with those of conventional pigment printing. The printing performances were influenced by the content of Jackfruit latex gum in the binder and the curing conditions. Based on a series of experiments, the pigment printing paste recipe and the process were optimized, considering color fastness, color strength, and fabric handle properties compared with those of the synthetic binder. The use of combined binder containing Jackfruit latex gum for pigment printing showed reasonable printing performances and offers an option for replacing synthetic binders, which cause adverse effect on human health and environments.

A sensitive and selective optical DNA biosensor was developed for dengue virus detection based on novel square-planar piperidine side chain-functionalized N,N′-bis-4-(hydroxysalicylidene)-phenylenediamine-nickel(II), which was able to intercalate via nucleobase stacking within DNA and be functionalized as an optical DNA hybridization marker. 3-Aminopropyltriethoxysilane (APTS)-modified porous silica nanospheres (PSiNs), was synthesized with a facile mini-emulsion method to act as a high capacity DNA carrier matrix. The Schiff base salphen complexes-labelled probe to target nucleic acid on the PSiNs renders a colour change of the DNA biosensor to a yellow background colour, which could be quantified via a reflectance transduction method. The reflectometric DNA biosensor demonstrated a wide linear response range to target DNA over the concentration range of 1.0 × 10−16–1.0 × 10−10 M (R2 = 0.9879) with an ultralow limit of detection (LOD) at 0.2 aM. The optical DNA biosensor response was stable and maintainable at 92.8% of its initial response for up to seven days of storage duration with a response time of 90 min. The reflectance DNA biosensor obtained promising recovery values of close to 100% for the detection of spiked synthetic dengue virus serotypes 2 (DENV-2) DNA concentration in non-invasive human samples, indicating the high accuracy of the proposed DNA analytical method for early diagnosis of all potential infectious diseases or pathological genotypes.

The road and construction sectors consume a large number of natural resources and energy, contributing significantly to waste generation and greenhouse gas emissions (GHG). The use of recycled aggregate from construction and demolition waste as a substitute for virgin aggregate is a current practice in the construction of new road sections. Additionally, in recent years, there has been an increasing focus on finding alternatives to bitumen for binders used in asphalt mixes. This study investigates and compares the impacts associated with two porous asphalt mixtures produced with CDW aggregates, virgin aggregates, and a polyolefin-based synthetic transparent binder through an LCA methodology. A cradle-to-gate approach was employed. Model characterization for calculating the potential environmental impacts of each porous asphalt mixture was performed using the ReCipe 2016 assessment method at the midpoint and endpoint levels. The results are presented with reference to a baseline scenario corresponding to a porous asphalt mixture, confirming the benefits associated with the use of recycled aggregates and in some cases the benefits of not using bitumen-based binders. This work contributes to the understanding of the importance of choosing the least environmentally damaging solution during the production or rehabilitation of road pavement infrastructure.

Most adhesives and binders, including bitumen for asphalt mixture production, are presently produced from petrochemicals after the refining of crude oil. The fact that crude oil reserves are a finite resource means that in the future, it may become necessary to produce these materials from alternative and probably renewable sources. Suitable resources of this kind may include polysaccharides, plant oils and proteins. This paper deals with the synthesis of polymer binders from monomers that could, in future, be derived from renewable resources. These binders consist of polyethyl acrylate (PEA) of different molecular weight, polymethyl acrylate (PMA) and polybutyl acrylate (PBA), which were synthesised from ethyl acrylate, methyl acrylate and butyl acrylate, respectively, by atom transfer radical polymerisation. The rheological properties of these binders were determined by means of oscillatory testing using a dynamic shear rheometer and combinations of stress/strain, temperature and frequency sweeps. The results indicate that PEA can be produced to have rheological properties similar to that of ‘soft’ 100/150 penetration grade bitumen, PMA with similar rheological properties to that of ‘hard’ 10/20 penetration grade bitumen, while PBA, due to its highly viscous nature and low dynamic moduli, cannot be used on its own as a binder. The synthetic polymers were found to be thermo-rheologically simple, and the shift factors, used to produce the dynamic moduli master curves, were found to fit an Arrhenius function.

To analyze the impact of polymer modifiers on the high-temperature viscosity and rheological properties of light-colored synthetic asphalt binders. Aromatic oils, petroleum resins, and polymer modifiers were selected to prepare a light-colored synthetic modified asphalt binder by physical mixing. In this study, SBS plus EVA was used to modify the light-colored synthetic asphalt binders, and seven sets of samples were prepared. The modified light-colored synthetic asphalt binder’s basic engineering properties were measured through the three major index tests; the rotational viscosity test and DSR test measure its high-temperature viscosity and rheological properties, and the content of different polymer modifiers was analyzed on the viscosity and influence of rheological properties. The results show that the compound modification method can increase the viscosity of light-colored synthetic asphalt binders, and SBS is better than EVA in improving the viscosity and rheological properties. EVA’s low content has little effect on the high-temperature viscosity and rheological properties of light-colored synthetic asphalt binders. Too much SBS will increase the impact of EVA to improve high-temperature viscosity. Modification of compounds may also improve the high-temperature rutting resistance of light-colored synthetic asphalt binders. SBS will degrade in the RTFOT aging process of light-colored synthetic asphalt binders, and its improving effect will be impaired. The content of SBS should not exceed 6%.

Purpose Piperidine side chain-functionalized N, N′-bissalicylidene phenylene di amine di-anion (salphen) consisting of salphen-Zn and salphen-Cu are able to intercalate with nucleic base stacking of DNA and can be applied as an optical DNA hybridization detector. Attaching DNA and salphen to glass surfaces has been done via coating the surface with the silane coupling agents containing 3-aminopropyltriethoxysilane that was synthesized for acting as a high-affinity RNA carrier matrix. The Schiff base salphen-zinc (II) and salphen-Cu (II) complexes-labelled probe to target nucleic acid renders a colour change of the DNA biosensor to a green and red background colour for zinc and copper, respectively. This study aims to indicate that the DNA biosensor data with high efficiency is used for detection of dengue virus serotypes 2 (DENV-2) and Chikungunya virus (CHIKV) concentration via salphen-Zn (II) and salphen-Cu (II), respectively, in human samples. Design/methodology/approach 1H-NMR and 13C-NMR have been used via PerkinElmer LAMBDA 35 instrument. The authors also used a double beam spectrophotometer with (CH3)4Si (TMS) as reference and dimethyl sulfoxide as solvent reference in pH = 7.0. Various DNA concentrations have been used for UV spectrophotometry at 300 nm and 400 nm for zinc and copper complexes, respectively. BRUKER mass spectra with DIONEX Ultimate 3000 LC model were used for all measurements. Mettler Teledo model (DSC882e) of differential scanning calorimeter (DSC) was used for measure the melting temperature of metal zinc and copper complexes. The morphology of the silica Nano spheres (SiNs) were scanned by FESEM with Model JSM-6700F from Japan. Findings The Cu (II) and Zn (II)-salphen-viruses DNA system for CHIKV and DENV-2, respectively, in different concentration have been investigated via various spectroscopies (Figure 3). CHIKV and DENV-2 DNA were selected from human saliva and urine samples as models for conformations of human G4-DNA. By increasing the amounts of DNAs, and G4, the UV–Vis bands of located above 300 nm, experienced a hypochromic effect. The Cu2+ complex exhibits selectivity towards the G4, and there is a similar affinity for Zn2+ complex binds to the G4. These results collectively suggest that the Cu2+ complex is stronger than the Zn2+ complex. The authors have found copper (II) and zinc (II) compounds and nucleic acid-complexes are strongly fluorescent molecules in the low energy range, from the visible to the near-infrared. Since the fluorescent emission of Zn (II) and Cu (II) complexes are enhanced by the binding to nucleic acids upon visible light exposure when bound to DNA. These complexes are important as selective fluorescent probes for nucleic acids and to highlight their potential application. UV–vis spectroscopy is an accurate for finding the extent of ligand interaction with DNA and metallic complexes–DNA binding. Generally, the binding of intercalative compounds to DNA can be characterized through absorption spectral titrations, where lowering in absorbance (hypochromism) and shift to longer wavelengths (red shift) were observed in this work. Originality/value The serum samples have been provided as citrate and collected in tubes after blood is allowed to clot. Then, it has been separated by centrifugation, and the authors have kept serum refrigerated at 4°C or frozen at –20°C. It is notable; specimens have been confirmed by Centres for Disease Control (CDC)-Dengue Branch previously. For the work, these samples have been frozen previously, and the diagnostic practiced tests at the CDC-Dengue Branch have been validated in serum and plasma. Therefore, plasma separated in lavender or heparins are suitable and acceptable for serology testing.

Leather is one of the most popular products across globe and holds a significant place in the economy, while the pollution, associated to traditional leather industry, is far away on the “green chemistry” principles. In this sense, polyurethanes, which exhibit tunable chemical structures by selecting suitable precursors, can fit specific requirements, and the developments of green strategies make them important candidates for leather industry. This mini review briefly outlines the recent development of conventional (petrol-based) and sustainable polyurethanes in the leather industry, including their design and properties, in applications such as synthetic leather and surface-finishing (coatings/binders). Finally, outlooks of the future tendency, including more environmental-friendly strategies, bio-sourced/recycled materials and development of high-value multifunctional leather materials, are also here proposed.