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result(s) for
"thin metal films"
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Joining Technologies for Automotive Battery Systems Manufacturing
2018
An automotive battery pack for use in electric vehicles consists of a large number of individual battery cells that are structurally held and electrically connected. Making the required electrical and structural joints represents several challenges, including, joining of multiple and thin highly conductive/reflective materials of varying thicknesses, potential damage (thermal, mechanical, or vibrational) during joining, a high joint durability requirement, and so on. This paper reviews the applicability of major and emerging joining techniques to support the wide range of joining requirements that exist during battery pack manufacturing. It identifies the advantages, disadvantages, limitations, and concerns of the joining technologies. The maturity and application potential of current joining technologies are mapped with respect to manufacturing readiness levels (MRLs). Further, a Pugh matrix is used to evaluate suitable joining candidates for cylindrical, pouch, and prismatic cells by addressing the aforementioned challenges. Combining Pugh matrix scores, MRLs, and application domains, this paper identifies the potential direction of automotive battery pack joining.
Journal Article
Nanostructuration of Thin Metal Films by Pulsed Laser Irradiations: A Review
2019
Metal nanostructures are, nowadays, extensively used in applications such as catalysis, electronics, sensing, optoelectronics and others. These applications require the possibility to design and fabricate metal nanostructures directly on functional substrates, with specifically controlled shapes, sizes, structures and reduced costs. A promising route towards the controlled fabrication of surface-supported metal nanostructures is the processing of substrate-deposited thin metal films by fast and ultrafast pulsed lasers. In fact, the processes occurring for laser-irradiated metal films (melting, ablation, deformation) can be exploited and controlled on the nanoscale to produce metal nanostructures with the desired shape, size, and surface order. The present paper aims to overview the results concerning the use of fast and ultrafast laser-based fabrication methodologies to obtain metal nanostructures on surfaces from the processing of deposited metal films. The paper aims to focus on the correlation between the process parameter, physical parameters and the morphological/structural properties of the obtained nanostructures. We begin with a review of the basic concepts on the laser-metal films interaction to clarify the main laser, metal film, and substrate parameters governing the metal film evolution under the laser irradiation. The review then aims to provide a comprehensive schematization of some notable classes of metal nanostructures which can be fabricated and establishes general frameworks connecting the processes parameters to the characteristics of the nanostructures. To simplify the discussion, the laser types under considerations are classified into three classes on the basis of the range of the pulse duration: nanosecond-, picosecond-, femtosecond-pulsed lasers. These lasers induce different structuring mechanisms for an irradiated metal film. By discussing these mechanisms, the basic formation processes of micro- and nano-structures is illustrated and justified. A short discussion on the notable applications for the produced metal nanostructures is carried out so as to outline the strengths of the laser-based fabrication processes. Finally, the review shows the innovative contributions that can be proposed in this research field by illustrating the challenges and perspectives.
Journal Article
Color-neutral, transparent, antimicrobial glass surface based on nanostructured Cu-Zn
by
Mezzadrelli, Alessia
,
Hussain, Rubaiya
,
Pruneri, Valerio
in
Alloys
,
Antimicrobial
,
Antimicrobial agents
2025
We present the development of transparent, color-neutral, antimicrobial surfaces tailored for integration in touchscreen display applications. Co-sputtered copper-zinc Ultra-Thin Metal Film is deposited on Gorilla®Glass substrate and subsequently annealed to perform nanostructuring. Cu-Zn mixed material maintains high antimicrobial efficacy inherent of copper while the presence of the zinc acts in dampening the color of pure copper which offers a significantly improved color neutrality. The optimized nanostructured surface exhibits optical transmission exceeding 80% in the visible spectrum and a color difference ΔE under 3 in the CIE 1976 Lab* color space, satisfying stringent display industry standards for visual clarity and neutrality. Additionally, the nanostructured surface possesses electrical insulation to support capacitive touch functionality. Antimicrobial performance was validated through biological analysis on both as-deposited and thermally annealed samples, demonstrating high bactericidal efficacy that meets the U.S. Environmental Protection Agency requirements. These findings place Cu-Zn based device as a scalable and effective solution for next-generation hygienic interactive display technologies thanks to the lithography-free fabrication process.
Journal Article
Double-gate metal-oxide TFT pixel circuit for improved luminance uniformity of mobile OLED display
by
Moon, Kook Chul
,
Son, Kyoung Seok
,
Lim, Jun Hyung
in
Bias
,
data voltage (V
,
data voltage (VDAT) range
2025
The small subthreshold swing (SS) of metal-oxide (MOx) thin-film transistors (TFTs) reduces the data voltage (V
DAT
) range of the organic light-emitting diode (OLED) display pixel circuit. This leads to a large OLED current error when a small change occurs in the gate-to-source voltage (V
GS
) of the driving TFT in the pixel. Therefore, we propose a new pixel circuit adopting a double-gate TFT structure for the driving TFT, which is mainly driven by the bottom gate with a thicker gate insulator to provide a wide V
DAT
range. The proposed pixel circuit further expands the V
DAT
range by employing threshold voltage (V
TH
) modulation effect depending on the gray level. It also allows for flexible adjustment of the V
TH
extraction time to reduce OLED current error at low gray levels. SPICE simulation and measured results verify that the proposed pixel circuit reduces the OLED current error rate to less than 10% even with a V
TH
variation of ±0.5 V or SS variation of ±5% for the current level from 0.1 nA to 30 nA.
Journal Article
Enhanced prediction and optimization of thin metal film optical properties using optimized ensemble learning models
2025
Thin metal films are essential for expanding sensors, optoelectronic, and photovoltaic technologies. The intricate relationship between material composition, thickness, and production presents significant challenges in optimizing optical properties. The paper introduces an AI-driven framework for the simultaneous prediction and optimization of metal film optical characteristics, such as transmittance(%T), reflectance(%R), and absorptance(%A) using a dataset of 1320 experimentally measured samples across material films of gold, aluminum, nickel, tin, copper, and molybdenum over 200–2000 nm wavelength range. The input features to the model include wavelength and material type. Ensemble Models such as Random Forest, Gradient Boosting, XGBoost, and Extra Trees were trained and optimized through GridSearchCV with stratified K-fold cross-validation. A multitask learning model was also implemented to explore potential improvements from joint prediction. Among all models, the CatBoost Regressor demonstrated superior performance, achieving R
2
= 0.99928, MAE = 0.21924, and MSE = 0.28203 on average across all outputs. To enhance interpretability, the feature importance analysis was employed, revealing that Material Type had a slightly more predictive influence than Wavelength. Additionally, material-specific error analysis identified challenging prediction zones tied to spectral extremes. The best performing machine learning model was deployed via a web-based GUI, enabling real-time prediction of thin-film optical properties. Overall, the proposed framework provides a scalable, interpretable, and deployable solution for AI-assisted material design and optical characterization. These findings accelerate thin metal film optimization by offering a reliable data-driven route for quick material property identification and enhancement through machine learning.
Journal Article
Enhancement of Optical Transparency and Electrical Conductivity of IZO/Ag/IZO Multilayer Film by Intense Pulsed Light and its Effect on the Photovoltaic Performances of Perovskite Solar Cells
2025
A highly conductive and transparent oxide/metal/oxide (OMO) multilayer transparent electrode is developed by flash lamp annealing (FLA). A transient thermal effect of FLA on the sandwich structure of the ultrathin Ag layer and zinc‐doped indium oxide (IZO) layer is systematically investigated. FLA enables IZO/Ag/IZO multilayer to maintain the continuous ultrathin Ag interlayer and improve the crystallinity of the IZO layers. This is due to a very short processing time, absorption of visible light by the Ag layer, heat transfer from the Ag layer to the IZO layer, and mechanical constraint of the Ag layer by neighbor IZO layers. This combination of continuous ultrathin Ag layer and highly crystalline IZO layer decreases light scattering in a visible range and allows the electron donation from the Ag layer of a high electron concentration to neighbor IZO layers of a high electron mobility. IZO/Ag/IZO multilayer film from an optimal FLA process achieves a very low sheet resistance of 4.1 Ω sq −1 and a high optical transmittance (90.1%) in the broadband range of 400–800 nm. A perovskite solar cell in the best IZO/Ag/IZO transparent electrode exhibits better current generation and higher fill factor than a device of FTO electrode.
Journal Article
Quantum-Size Effects in Ultra-Thin Gold Films on Pt(111) Surface
by
Silkin, Igor V.
,
Koroteev, Yury M.
,
Chulkov, Evgueni V.
in
Analysis
,
Approximation
,
Atomic properties
2023
We calculate, within the density-functional theory, the atomic and electronic structure of the clean Pt(111) and Au(111) surfaces and the nML-Au/Pt(111) systems with n varying from one to three. The effect of the spin–orbital interaction was taken into account. Several new electronic states with strong localization in the surface region were found and discussed in the case of clean surfaces. The Au adlayers introduce numerous quantum well states in the energy regions corresponding to the projected bulk band continuum of Au(111). Moreover, the presence of states resembling the true Au(111) surface states can be detected at n = 2 and 3. The Au/Pd interface states are found as well. In nML-Au/Pt(111), the calculated work function presents a small variation with a variation of the number of the Au atomic layer. Nevertheless, the effect is significantly smaller in comparison to the s-p metals.
Journal Article
Selective Laser Ablation of Metal Thin Films Using Ultrashort Pulses
by
Kim, Yunseok
,
Fushinobu, Kazuyoshi
,
Kim, Young-Jin
in
Ablation
,
Conduction heating
,
Conductive heat transfer
2021
Selective thin-film removal is needed in many microfabrication processes such as 3-D patterning of optoelectronic devices and localized repairing of integrated circuits. Various wet or dry etching methods are available, but laser machining is a tool of green manufacturing as it can remove thin films by ablation without use of toxic chemicals. However, laser ablation causes thermal damage on neighboring patterns and underneath substrates, hindering its extensive use with high precision and integrity. Here, using ultrashort laser pulses of sub-picosecond duration, we demonstrate an ultrafast mechanism of laser ablation that leads to selective removal of a thin metal film with minimal damage on the substrate. The ultrafast laser ablation is accomplished with the insertion of a transition metal interlayer that offers high electron–phonon coupling to trigger vaporization in a picosecond timescale. This contained form of heat transfer permits lifting off the metal thin-film layer while blocking heat conduction to the substrate. Our ultrafast scheme of selective thin film removal is analytically validated using a two-temperature model of heat transfer between electrons and phonons in material. Further, experimental verification is made using 0.2 ps laser pulses by micropatterning metal films for various applications.
Journal Article
Even–Odd Layer Oscillatory Behavior of Electronic and Phononic Specific Heat in an Ultra-Thin Metal Film
2024
Both electronic and phononic statistical and thermal properties, modulated by the quantum size effect, are suggested in a thin metal film. In order to show the quantum size effect of specific heat, the densities of the electron and phonon states of an ultra-thin film are treated within the framework of quantum statistics. It was found that strong and weak “even–odd layer oscillatory behavior” was exhibited by the ultra-thin metal film in electronic and lattice specific heat, respectively. Such a behavior, which depends on film thickness, results from the quantum confinement of electrons and phonons in the vertical (thickness) direction of the film, where both electrons and phonons form their respective quantum well standing wave modes. If, for example, the thickness of the ultra-thin metal film is exactly an integer multiple of a half wavelength of the standing wave of electrons in the thickness direction, the corresponding density of states would become maximized, and the electronic specific heat would take its maximum. In the literature, less attention has been paid to the size-dependent electron Fermi wavelength for quantum size effects, i.e., the Fermi wavelength in ultra-thin metal films has always been identified as a constant. We shall show how the Fermi wavelength varies with the size of a nanofilm, including an explicit analytic formulation for the thickness dependence of the electron Fermi wavelength. Size-dependent resonantly oscillatory behavior, depending on the ultra-thin or nanoscale film thickness, would have possible significance for researching some fundamental physical characteristics (e.g., low-dimensional quantum statistics) and may find potential applications in new thermodynamic device design.
Journal Article
Infrared Electrochromic Devices Based on Thin Metal Films
2023
Tunable emissivity technology is promising for the dynamic regulation of infrared radiation. Herein, infrared electrochromic devices based on thin metal films that operate via a novel hydrogen‐induced metal–insulator transition are demonstrated. The use of thin magnesium–nickel (MgxNi) alloy films as both a variable emissivity material and top conductive electrode simplifies the device structure and ensures that large changes in emissivity can be achieved. The constructed sandwich‐structured electrochromic devices also have polyethyleneimine (PEI) as a middle proton‐conducting electrolyte layer and hydrogen tungsten bronze (HxWO3)/indium tin oxide (ITO) as a bottom ion‐storage layer. Upon application of a voltage of ±2.6 V, the emissivity of the MgxNi/Pd/PEI/HxWO3/ITO device can be reversibly regulated, with emissivity changes of 0.48 and 0.43 in the 3–5 and 7.5–14 µm atmospheric windows, respectively. Under open‐circuit conditions, the high‐emissivity state of the device can be stably maintained for 3 h. The emissivity change is affected by the composition and thickness of the MgxNi film and the device failure mechanism involves the breakage and oxidation of this film after cycling. Corresponding flexible devices that exhibit electrochromism in the visible region have great potential for adaptive thermal camouflage, smart thermal management, and dynamic information displays. An infrared electrochromic device is constructed based on a hydrogen‐induced metal–insulator phase transition from metallic Mg2Ni to dielectric Mg2NiH4. Reversible emissivity changes are achieved by alternately applying ±2.6 V. The high‐emissivity state is maintained for 3 h, with subsequent device failure caused by stress accumulation and oxidation. The device can be modified to also induce visible color changes.
Journal Article