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17,877 result(s) for "unit cell"
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Structural Design of Vascular Stents: A Review
Percutaneous Coronary Intervention (PCI) is currently the most conventional and effective method for clinically treating cardiovascular diseases such as atherosclerosis. Stent implantation, as one of the ways of PCI in the treatment of coronary artery diseases, has become a hot spot in scientific research with more and more patients suffering from cardiovascular diseases. However, vascular stent implanted into vessels of patients often causes complications such as In-Stent Restenosis (ISR). The vascular stent is one of the sophisticated medical devices, a reasonable structure of stent can effectively reduce the complications. In this paper, we introduce the evolution, performance evaluation standards, delivery and deployment, and manufacturing methods of vascular stents. Based on a large number of literature pieces, this paper focuses on designing structures of vascular stents in terms of “bridge (or link)” type, representative volume unit (RVE)/representative unit cell (RUC), and patient-specific stent. Finally, this paper gives an outlook on the future development of designing vascular stents.
Fast formation of single-unit-cell-thick and defect-rich layered double hydroxide nanosheets with highly enhanced oxygen evolution reaction for water splitting
The development of high-efficiency electrocatalysts for oxygen evolution reactions (OERs) plays an important role in the water-splitting process. Herein, we report a facile way to obtain two-dimensional (2D) single-unit-cell-thick layered double hydroxide (LDH) nanosheets (NSs, ∼1.3 nm) within only 5 min. These nanosheets presented significantly enhanced OER performance compared to bulk LDH systems fabricated using the conventional co-precipitation method. The current strategy further allowed control over the chemical compositions and electrochemical activities of the LDH NSs. For example, CoFe-LDH NSs presented the lowest overpotential of 0.28 V at 10 mA/cm 2 , and the NiFe-LDHs NSs showed Tafel slopes of 33.4 mV/decade and nearly 100% faradaic efficiency, thus outperforming state-of-the-art IrO 2 water electrolysis catalysts. Moreover, positron annihilation lifetime spectroscopy and high-resolution transmission electron microscopy observations confirmed that rich defects and distorted lattices occurred within the 2D LDH NSs, which could supply abundant electrochemically active OER sites. Periodic calculations based on density functional theory (DFT) further showed that the CoFe- and NiFe-LDHs presented very low energy gaps and obvious spin-polarization behavior, which facilitated high electron mobility during the OER process. Therefore, this work presents a combined experimental and theoretical study on 2D single-unit-cell-thick LDH NSs with high OER activities, which have potential application in water splitting for renewable energy.
Novel Negative Poisson’s Ratio Lattice Structures with Enhanced Stiffness and Energy Absorption Capacity
The weak stiffness and strength of materials with negative Poisson’s ratio limits their application. In this paper, three types of novel lattices with negative Poisson’s ratio are proposed to improve not only stiffness and strength but also energy absorption capacity by embedding different ribs into a classic re-entrant structure. Unit cell analyses show these novel lattices have significantly increased Young’s modulus along the loading direction, and Type C can maintain sufficient negative Poisson’s ratio performance compared with the base lattice. In addition, the novel lattices exhibit higher yield stress, plateau stress and densification strain extracted from quasi-static compressive simulation. The lattices are prototyped by laser-based additive manufacturing and tested in quasi-static experiments, which show the experimental data match the numerical results within an error of margin. The work signifies the prospect of lattices with negative Poisson’s ratio in enhancing engineering-applicable structures, and indicates the potential of structural topology optimization in more sophisticated designs.
Topological, Mechanical and Biological Properties of Ti6Al4V Scaffolds for Bone Tissue Regeneration Fabricated with Reused Powders via Electron Beam Melting
Cellularized scaffold is emerging as the preferred solution for tissue regeneration and restoration of damaged functionalities. However, the high cost of preclinical studies creates a gap between investigation and the device market for the biomedical industry. In this work, bone-tailored scaffolds based on the Ti6Al4V alloy manufactured by electron beam melting (EBM) technology with reused powder were investigated, aiming to overcome issues connected to the high cost of preclinical studies. Two different elementary unit cell scaffold geometries, namely diamond (DO) and rhombic dodecahedron (RD), were adopted, while surface functionalization was performed by coating scaffolds with single layers of polycaprolactone (PCL) or with mixture of polycaprolactone and 20 wt.% hydroxyapatite (PCL/HA). The mechanical and biological performances of the produced scaffolds were investigated, and the results were compared to software simulation and experimental evidence available in literature. Good mechanical properties and a favorable environment for cell growth were obtained for all combinations of scaffold geometry and surface functionalization. In conclusion, powder recycling provides a viable practice for the biomedical industry to strongly reduce preclinical costs without altering biomechanical performance.
Experimental Study of Auxetic Structures Made of Re-Entrant (“Bow-Tie”) Cells
This article presents a study of metamaterial structures that exhibit auxetic properties. This unusual phenomenon of simultaneous orthogonal expansion of the metamaterial in tension, and vice versa in compression, with vertical and horizontal contraction, is explored for structures made of re-entrant unit cells. The geometry of such structures is analysed in detail, and the relationships are determined by the value of the Poisson’s ratio. It is shown that the Poisson’s ratio depends not only on the geometry of the unit cell but also on the degree of strain. Depending on the dimensions of the structure’s horizontal and inclined struts, the limit values are determined for the angle between them. By creating physical structures made of re-entrant cells, it is demonstrated that the mechanism of change in the structure’s dimensions is not due to the hinging but to the bending of the struts. The experimental section contains the results of compression tests of a symmetrical structure and tensile tests of a flat mesh structure. In the case of the mesh structure, a modification of the re-entrant cells was used to create arched strut joints. This modification makes it possible to obtain greater elongation of the mesh structure and larger NPR values.
An Analytical Unit Cell Model for the Effective Thermal Conductivity of High Porosity Open-Cell Metal Foams
We present an analytical model for the effective thermal conductivity of fluid-saturated metal foams with open cells. For high porosity ranges ( ε ≥ 0.9 ) , the model is derived based on a realistic representative unit cell (a tetrakaidecahedron with cuboid node) under the assumption of parallel heat conduction along the highly tortuous cell ligaments and the saturating fluid. Good agreement with existing experimental data as well as the present measurements of open-cell aluminum foams saturated with either air or water validates the present model. More realistic and reasonable node size is estimated and compared with other model predictions. Ligament shape and pore size (PPI) are found to have little influence upon the effective thermal conductivity of the bulk porous media. Further, the influence of the fluid phase as well as the interactive heat conduction between solid and fluid phase on the overall effective thermal conductivity is quantified.
Dynamics of Polymeric Re-Entrant Auxetic Structures: Cyclic Compression Studies
The present study investigated the dynamic behavior of structures made of re-entrant unit cells subjected to cyclic compressive loading limited to the elastic range. The structures were assembled from printed polymer re-entrant cells in six combinations. Through the given compression cycles for three different amplitude values, strain-force relationships, which had the shape of a hysteresis loop, were obtained. Under compression, all unit cells of the structures deformed uniformly, though only for a certain amount of strain, whereas with larger changes, they underwent uncontrolled deformation. Experiments showed that structures composed of more than one unit cell exhibit different mechanical characteristics. It was observed that the width of the hysteresis loop depended on the degree of closing the structure and on the compression amplitude. The obtained hysteresis curves for different amplitudes also testify to the occurrence of the Mullins effect for these polymeric auxetic structures. Taking into account the maximum values of changes in dimensions for a given compression cycle, Poisson’s ratio values were determined, which were negative and below unity. The effect of strut thickness on the NPR was confirmed, decreasing its negative value along with the increasing thickness.
Analysis of Mechanical Properties and Parameter Dependency of Novel, Doubly Re-Entrant Auxetic Honeycomb Structures
This study proposes a new, doubly re-entrant auxetic unit-cell design that is based on the widely used auxetic honeycomb structure. Our objective was to develop a structure that preserves and enhances the advantages of the auxetic honeycomb while eliminating all negative aspects. The doubly re-entrant geometry design aims to enhance the mechanical properties, while eliminating the buckling deformation characteristic of the re-entrant deformation mechanism. The effects of the geometric modification are described and evaluated using two parameters, offset and deg. A series of experiments were conducted on a wide range of parameters based on these two parameters. Specimens were printed via the vat photopolymerization process and were subjected to a compression test. Our aim was to investigate the mechanical properties (energy absorption and compressive force) and the deformation behaviour of these specimens in relation to the relevant parameters. The novel geometry achieved the intended properties, outperforming the original auxetic honeycomb structure. Increasing the offset and deg parameters results in increasing the energy absorption capability (up to 767%) and the maximum compressive force (up to 17 times). The right parameter choice eliminates buckling and results in continuous auxetic behaviour. Finally, the parameter dependency of the deformation behaviour was predicted by analytical approximation as well.
Cubic Lattice Structures of Ti6Al4V under Compressive Loading: Towards Assessing the Performance for Hard Tissue Implants Alternative
Porous Lattice Structure (PLS) scaffolds have shown potential applications in the biomedical domain. These implants’ structural designs can attain compatibility mechanobiologically, thereby avoiding challenges related to the stress shielding effect. Different unit cell structures have been explored with limited work on the fabrication and characterization of titanium-based PLS with cubic unit cell structures. Hence, in the present paper, Ti6Al4V (Ti64) cubic PLS scaffolds were analysed by finite element (FE) analysis and fabricated using selective laser melting (SLM) technique. PLS of the rectangular shape of width 10 mm and height 15 mm (ISO: 13314) with an average pore size of 600–1000 μm and structure porosity percentage of 40–70 were obtained. It has been found that the maximum ultimate compressive strength was found to be 119 MPa of PLS with a pore size of 600 μm and an overall relative density (RD) of 57%. Additionally, the structure’s failure begins from the micro-porosity formed during the fabrication process due to the improper melting along a plane inclined at 45 degree.
Influence of ion site occupancies on the unit cell parameters, specific volumes, and densities of M8(AlSiO4)6X2 sodalites where M = Li, Na, K, Rb, and Ag and X = Cl, Br, and I
This paper discusses the effects of composition on the unit cell parameter ( a ), unit cell volume ( V ), specific volume ( v ), and density ( ρ ) of various sodalites including M 8 + AlSiO 4 6 Cl 2 ( M  = Li, Na, K, Rb, and/or Ag) and Na 8 AlSiO 4 6 X 2 - ( X  = Cl, Br, and/or I). Compositional models were developed, and the results show that the models are successful at predicting a , V , and v (and thus ρ ) within the compositional range available in the literature. Discussion is included on the correlation between the ionic radii of the alkali metals and halides in the sodalite β-cages and the measured values of a , V , v , and ρ . The data show linear increases in a and ρ with increases in the average ionic radii of the M + and X - constituents (data for v show a linear decrease).