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It is well known that global warming increases the atmospheric water vapor content, which results in substantial changes in the hydrological cycle. Using five observational data sets, the results show that an increasing trend of near‐surface water vapor pressure (AVP) over land and ocean was significant from 1975 to 1998, while such an increasing trend in AVP subsequently weakened from 1999 to 2019. This phenomenon is associated with decreased oceanic evaporation and land surface evapotranspiration in response to recent climate variations. One consequence of such a phenomenon is a large increase in near‐surface vapor pressure deficit (VPD), which in turn increases atmospheric demand for water vapor and thus aridity and drought over land. This result emphasizes the importance of water vapor change under global warming. Plain Language Summary As one of the key components of the atmosphere, water vapor plays a crucial role in regulating the processes in the climate system. It has long been established that water vapor generally increases with global rising mean air temperature as dictated by the Clausius‐Clapeyron theorem if relative humidity changes little. Here, we use five observational data sets to study the trend changes in near‐surface actual water vapor pressure (AVP) from 1975 to 2019. Our results show an increasing trend of global land and ocean AVP from 1975 to 1998, but the increasing trend has weakened since the late 1990s. This phenomenon in water vapor is associated with decreased oceanic evaporation and land surface evapotranspiration. This phenomenon further enhances the atmospheric vapor pressure deficit (VPD), which dominates the water and carbon cycling in the terrestrial ecosystem by regulating vegetation stomatal conductance. Key Points The increasing trend of near‐surface actual water vapor pressure (AVP) over land and ocean has weakened since the end of the 1990s The weakened water vapor pressure increase is associated with decreased oceanic evaporation and land surface evapotranspiration One consequence of the weakened water vapor pressure increase is a large increase in near‐surface vapor pressure deficit

Recent decades have been characterized by increasing temperatures worldwide, resulting in an exponential climb in vapor pressure deficit (VPD). VPD has been identified as an increasingly important driver of plant functioning in terrestrial biomes and has been established as a major contributor in recent drought-induced plant mortality independent of other drivers associated with climate change. Despite this, few studies have isolated the physiological response of plant functioning to high VPD, thus limiting our understanding and ability to predict future impacts on terrestrial ecosystems. An abundance of evidence suggests that stomatal conductance declines under high VPD and transpiration increases in most species up until a given VPD threshold, leading to a cascade of subsequent impacts including reduced photosynthesis and growth, and higher risks of carbon starvation and hydraulic failure. Incorporation of photosynthetic and hydraulic traits in ‘next-generation’ land-surface models has the greatest potential for improved prediction of VPD responses at the plant- and global-scale, and will yield more mechanistic simulations of plant responses to a changing climate. By providing a fully integrated framework and evaluation of the impacts of high VPD on plant function, improvements in forecasting and long-term projections of climate impacts can be made.

This updated version of the popular Handbook further explains all aspects of physical vapor deposition (PVD) process technology from the characterizing and preparing the substrate material, through deposition processing and film characterization, to post-deposition processing. The emphasis of the new edition remains on the aspects of the process flow that are critical to economical deposition of films that can meet the required performance specifications, with additional information to support the original material. The book covers subjects seldom treated in the literature: substrate characterization, adhesion, cleaning and the processing. The book also covers the widely discussed subjects of vacuum technology and the fundamentals of individual deposition processes. However, the author uniquely relates these topics to the practical issues that arise in PVD processing, such as contamination control and film growth effects, which are also rarely discussed in the literature. In bringing these subjects together in one book, the reader can understand the interrelationship between various aspects of the film deposition processing and the resulting film properties. The book is intended to be both an introduction for those who are new to the field and a valuable resource to those already in the field.

The climatological characteristics of water vapor transport over the Tibetan Plateau (TP) were investigated in this study by using the ERA-interim and JRA55 monthly reanalysis dataset. The trends of water vapor budget and water vapor sources during the past 40 years were also revealed. The analyses show that the TP is a water vapor convergence area, where the convergence was enhanced from 1979 to 2018. In addition, the convergence is much stronger in JJA, with a linear trend that is twice the annual average trend. The climatological water vapor sources over the TP were identified mainly at the southern and western boundaries, with the vapor sources at the southern boundaries originating from the Arabian Sea and Bay of Bengal and the vapor sources at the western boundary being transported by mid-latitude westerlies. The TP is a moisture sink at a climatological mean, with an annual average net water vapor flux of 11.86 × 106kg ∙ s−1. Water vapor transport is much stronger in JJA than in other times of the year, and the net water vapor flux is 29.60 × 106kg ∙ s−1. The net water vapor flux in the TP increased with a linear trend of 0.12×106kg ∙ s−1 ∙ year−1 (α = 0.01), while the increase in the flux was more significant in JJA than in other times of the year with a linear trend of 0.30 ×106kg ∙ s−1 ∙ year−1 (α = 0.01). Detailed features in the water vapor flux and transport changes across the TP’s four boundaries were explored by simulating backward trajectories with a Lagrangian trajectory model (hybrid single-particle Lagrangian integrated trajectory model, HYSPLIT). In the study period, the water vapor contribution rate of western channel is increased. However, the Southern channel’s water vapor contribution decreased.

Compound extremes such as cooccurring soil drought (low soil moisture) and atmospheric aridity (high vapor pressure deficit) can be disastrous for natural and societal systems. Soil drought and atmospheric aridity are 2 main physiological stressors driving widespread vegetation mortality and reduced terrestrial carbon uptake. Here, we empirically demonstrate that strong negative coupling between soil moisture and vapor pressure deficit occurs globally, indicating high probability of cooccurring soil drought and atmospheric aridity. Using the Global Land Atmosphere Coupling Experiment (GLACE)-CMIP5 experiment, we further show that concurrent soil drought and atmospheric aridity are greatly exacerbated by land–atmosphere feedbacks. The feedback of soil drought on the atmosphere is largely responsible for enabling atmospheric aridity extremes. In addition, the soil moisture–precipitation feedback acts to amplify precipitation and soil moisture deficits in most regions. CMIP5 models further show that the frequency of concurrent soil drought and atmospheric aridity enhanced by land–atmosphere feedbacks is projected to increase in the 21st century. Importantly, land–atmosphere feedbacks will greatly increase the intensity of both soil drought and atmospheric aridity beyond that expected from changes in mean climate alone.

Tree species growing along the forest–grassland ecotone are near the moisture limit of their range. Small increases in temperature can increase vapor pressure deficit (VPD) which may increase tree water use and potentially hasten mortality during severe drought. We tested a 40% increase in VPD due to an increase in growing temperature from 30 to 33°C (constant dewpoint 21°C) on seedlings of 10 tree species common to the forest–grassland ecotone in the southern Great Plains, USA. Measurement at 33 vs 30°C during reciprocal leaf gas exchange measurements, that is, measurement of all seedlings at both growing temperatures, increased transpiration for seedlings grown at 30°C by 40% and 20% for seedlings grown at 33°C. Higher initial transpiration of seedlings in the 33°C growing temperature treatment resulted in more negative xylem water potentials and fewer days until transpiration decreased after watering was withheld. The seedlings grown at 33°C died 13% (average 2 d) sooner than seedlings grown at 30°C during terminal drought. If temperature and severity of droughts increase in the future, the forest–grassland ecotone could shift because low seedling survival rate may not sufficiently support forest regeneration and migration.

Global warming intensifies atmospheric water vapor transport between ocean and land, which increases the likelihood of extreme precipitation and floods. However, accurate estimations of water vapor exchange between ocean and land are difficult due to the lack of available data and effective methods. This study developed a novel eight-directionvector decomposition algorithm for calculating water vapor flux between ocean and land based on the ERA5 dataset, and the results showed that global water vapor exchange between ocean and land had significantly increased in the past 40 years, except for Antarctica. During 1980–2018, the average annual net water vapor inflow from ocean to land (Qnet) was 44.68 × 1015 kg yr−1, and Qnet increased at a rate of 1.48 × 1015 kg yr−1 decade−1. The intensified atmospheric water vapor exchange between ocean and land was directly caused by the increase of atmospheric water vapor content, which largely depended on the rising air temperature, and it was found that water vapor flux between ocean and land increased by over 8% K−1 with the increasing air temperature at the global average. This study also identified El Niño–Southern Oscillation (ENSO) as an important contributor to the global ocean–land water vapor exchange anomalies. A strong El Niño event (MEI = 1) can result in a 1.36 × 1015 kg yr−1 (3.03%) decrease in Qnet, and a strong La Niña event (MEI=-1) can increase Qnet by 1.38 × 1015 kg yr−1 (3.09%). The eight-direction-vector decomposition algorithm was effective in ocean–land water vapor flux estimations at different spatial and temporal scales, which could provide great insights into the mechanisms of extreme precipitation events.

It is necessary to calculate the saturation vapor pressure of water and of ice for some purposes in many disciplines. A number of formulas are available for this calculation. These formulas either are tedious or are not very accurate. In this study, a new formula has been developed by integrating the Clausius–Clapeyron equation. This new formula is simple and easy to remember. In comparison with the International Association for the Properties of Water and Steam reference dataset, the mean relative errors from this new formula are only 0.001% and 0.006% for the saturation vapor pressure of water and of ice, respectively, within a wide range of temperatures from −100° to 100°C. In addition, this new formula yields a mean relative error of 0.0005% within the commonly occurring temperature range (10°–40°C). Therefore, this new formula has significant advantages over the improved Magnus formula and can be used to calculate the saturation vapor pressure of water and of ice in a wide variety of disciplines.

Compound drought‐heatwave (CDHW) events threaten ecosystem productivity and are often characterized by low soil moisture (SM) and high vapor pressure deficit (VPD). However, the relative roles of SM and VPD in constraining forest productivity during CDHWs remain controversial. In the summer of 2022, China experienced a record‐breaking CDHW event (DH2022). Here, we applied satellite remote‐sensing data and meteorological data, and machine‐learning techniques to quantify the individual contributions of SM and VPD to forest productivity variations and investigate their interactions during the development of DH2022. The results reveal that SM, rather than VPD, dominates the forest productivity decline during DH2022. We identified a possible critical tipping point of SM below which forest productivity would quickly decline with the decreasing SM. Furthermore, we illuminated the evolution of SM, VPD, evapotranspiration, forest productivity, and their interactions throughout DH2022. Our findings broaden the understanding of forest response to extreme CDHWs at the ecosystem scale. Plain Language Summary Low soil moisture (SM) and high vapor pressure deficit (VPD) are widely recognized as the dominant drivers of forest productivity decline during compound drought‐heatwave (CDHW) events. In the summer of 2022, a record‐breaking CDHW (DH2022) struck China. In this study, we decoupled the respective impacts of SM and VPD in determining forest productivity decline during DH2022. We found that during DH2022, SM, rather than VPD, is the dominant driver of forest productivity decline, and once SM decreases below a certain threshold, forest productivity would decline sharply. We illuminated the evolution of SM, VPD, evapotranspiration, forest productivity, and their interactions throughout DH2022. Our findings promote the understanding of forest response to extreme CDHWs at the ecosystem scale and thus potentially improve terrestrial ecosystem models' ability to evaluate and predict the impacts of CDHWs. Key Points Soil moisture (SM), rather than vapor pressure deficit, dominates the forest productivity decline in the 2022 China compound drought‐heatwave event Forest productivity would decline sharply once SM drops below a certain threshold during extreme compound drought‐heatwave events Evolution of the 2022 China compound drought‐heatwave event and its impacts on forests were illuminated