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Light Detection and Ranging (LiDAR) sensors can precisely determine object distances using the pulsed time of flight (TOF) or amplitude-modulated continuous wave (AMCW) TOF methods and velocity using the frequency-modulated continuous wave (FMCW) approach. In this paper, we focus on modelling and analysing the reflection of vector beams (VBs) and vector vortex beams (VVBs) for optical sensing in LiDAR applications. Unlike traditional TOF and FMCW methods, this novel approach uses VBs and VVBs as detection signals to measure the orientation of reflecting surfaces. A key component of this sensing scheme is understanding the relationship between the characteristics of the reflected optical fields and the orientation of the reflecting surface. To this end, we develop a computational model for the reflection of VBs and VVBs. This model allows us to investigate critical aspects of the reflected field, such as intensity distribution, intensity centroid offset, reflectance, and the variation of the intensity range measured along the azimuthal direction. By thoroughly analysing these characteristics, we aim to enhance the functionality of LiDAR sensors in detecting the orientation of reflecting surfaces.