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Kinetics of the Epoxidation of Crotonic Acid by Aqueous Hydrogen Peroxide Catalysed by Sodium Orthovanadatae
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Kinetics of the Epoxidation of Crotonic Acid by Aqueous Hydrogen Peroxide Catalysed by Sodium Orthovanadatae
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Journal Article
Kinetics of the Epoxidation of Crotonic Acid by Aqueous Hydrogen Peroxide Catalysed by Sodium Orthovanadatae
2012
Overview
The kinetics of epoxidation of crotonic acid with hydrogen peroxide catalysed by sodium orthovanadate have been investigated at 400C. The rate of epoxidation reaction is first order with respect to the [substrate] and [catalyst] and zero order in hydrogen peroxide concentration. The strength of the medium shows insignificant effect on the reaction rate. Temperature dependence parameters have been computed. On the basis of kinetics and experimental results, a suitable mechanism is proposed.
Publisher
Oriental Scientific Publishing Company
Subject
