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Investigation of acoustical excess parameters and FTIR studies for binary liquid mixtures of tetrachloroethylene and cyclopentanone at different temperatures
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Investigation of acoustical excess parameters and FTIR studies for binary liquid mixtures of tetrachloroethylene and cyclopentanone at different temperatures
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Journal Article
Investigation of acoustical excess parameters and FTIR studies for binary liquid mixtures of tetrachloroethylene and cyclopentanone at different temperatures
2024
Overview
Speed of sound (U), Density (ρ), and viscosity (η) values of liquid mixtures of Tetrachloroethylene with Cyclopentanone and pure liquids were determined at regular intervals of molar range at different temperatures (303.15, 308.15, 313.15, 318.15) K. From the experimentally determined values, thermo-acoustic parameters such as excess molar volume (V E ) and excess free length (L f E ), excess Gibb’s free energy (ΔG E ) and excess enthalpy (H E ) have been estimated. The variations of the above parameters discussed based on intermolecular interactions existing in this binary mixture. The computed values of sound speed in the mixture from various theories are compared with experimentally calculated values and have a clear check to validate the theories for the present system, and FTIR studies provide detailed analysis of molecular interactions.
Publisher
IOP Publishing
