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Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor
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Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor
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Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor
Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor
Journal Article

Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor

2024
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Overview
Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs). However, their energy storage mechanisms in zinc-based systems are still under debate. Herein, we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions. And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors. The zinc-ion capacitor with Mg 2+ mixed solution delivers 82 mAh·g −1 capacity at 1 A·g −1 and maintains 91% of the original capacitance after 10000 cycling. It is superior to the other assembled zinc-ion devices in single-component electrolytes. The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.
Publisher
University of Science and Technology Beijing,Springer Nature B.V,School of Materials Science and Engineering,Shenyang University of Technology,Shenyang 110870,China