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Lanthanide-oxo clusters for efficient catalytic reduction of carboxamides
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Journal Article
Lanthanide-oxo clusters for efficient catalytic reduction of carboxamides
2023
Overview
The reduction of carboxamides into high value-added amines is a very interesting but great challenging topic. Herein we demonstrate that polynuclear lanthanide-oxo clusters Ln
16
(Ln = Eu and Gd) can be used as efficient catalyst to reduce primary and secondary carboxamides to amines with excellent yield of 71%–98% and broad substrates scope. The methodology can extend to the gram-scale synthesis of phenethylamine drug with 93% yield. Based on the isolation and characterization of catalytic intermediates, a catalytic mechanism involving multipath reaction is proposed. This work provides efficient lanthanide cluster catalysts for the reduction of carboxamides to amines.
Publisher
Science China Press,Springer Nature B.V
Subject
