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Amorphous SnO–Sb2O3–SiO2 glassy anode: high-performance electrode materials for Na-ion batteries
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Amorphous SnO–Sb2O3–SiO2 glassy anode: high-performance electrode materials for Na-ion batteries
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Journal Article
Amorphous SnO–Sb2O3–SiO2 glassy anode: high-performance electrode materials for Na-ion batteries
2021
Overview
Amorphous SnO–Sb
2
O
3
–SiO
2
glass anode prepared by simple mechanical ball milling method. Physical and electrochemical properties of prepared glass anode identified by X-ray powder diffraction (XRD), scanning electron microscopy, cyclic voltammetry, galvanostatic, and electrochemical impedance spectroscopy (EIS) techniques. Amorphous nature of SnO–Sb
2
O
3
–SiO
2
60 h of ball-milled glass anode confirmed by XRD technique. The glass anode showed excellent electrochemical performance up to 100 cycles in the voltage range between 0 and 3.0 V. Cycle performance tests showed that the anode delivered a specific discharge and charge capacity of 782 and 654 mAh g
−1
with 100% columbic efficiency about 100 cycles at 0.5 C rate. Its shows ~ 99% capacity retention even at a high-capacity rate of 5 C with a current density of 258 mAh g
−1
. The EIS spectroscopy revealed that the charge transfer resistance (
R
ct
) decreasing to an increasing cycle number which ascribed to superior conductivity of glass anode. This research contributed to the development of a large-scale preparation procedure for high-performance SnO–Sb
2
O
3
–SiO
2
glass anode materials for use in Na-ion batteries.
Publisher
Springer US,Springer Nature B.V
