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A quantitative and qualitative study of gas generation observed in LiFePO4–TiNb2O7 cells
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A quantitative and qualitative study of gas generation observed in LiFePO4–TiNb2O7 cells
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Journal Article
A quantitative and qualitative study of gas generation observed in LiFePO4–TiNb2O7 cells
2024
Overview
Since 20 years, titanium oxide materials and in particular, lithium titanate spinel Li
4
Ti
5
O
12
(LTO) were considered as promising negative electrode materials for lithium-ion cells. In the case of the TiNb
2
O
7
compound (TNO), which has a larger theoretical lithiation capacity of 388 mAh g
−1
, few studies have focused on the outgassing of the material. In this work, we quantified the volume produced as a function of different cycling parameters and then characterized the produced species and show a prevalence of H
2
gas. The use of carbon coating as a mitigation strategy and its limitation is also discussed.
Graphical abstract
Publisher
Springer Netherlands,Springer Nature B.V
