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Reaction Acceleration Promoted by Partial Solvation at the Gas/Solution Interface
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Journal Article
Reaction Acceleration Promoted by Partial Solvation at the Gas/Solution Interface
2021
Overview
The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent polarity. Partial solvation at the gas/solution interface is a major contributor to the 104‐fold reaction acceleration seen in bimolecular but not unimolecular reactions in microdroplets. Reaction acceleration can be used to manipulate selectivity by solvent choice. We report experimental evidence for the hypothesis that reaction acceleration in microdroplets is promoted by partial solvation at the gas/solution interface through careful kinetics measurements of a range of different types of reactions, including substitution, condensation, addition and elimination.
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