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Exploring the Potential of Robocasting for High-Density Electrolytes in Solid Oxide Fuel Cells

by Matei, Alexandru-Cristian , Ciobota, Dan-Năstase , Ioniță, Florentina-Gabriela , Drăguț, Dumitru-Valentin , Licu, Lidia , Caramarin, Ștefania , Okos, Alexandru

in 3-D printers / 3D printing / Additive manufacturing / Analysis / Binder removal / Ceramic materials / Ceramics / Efficiency / Electric properties / Electrolytes / Electrolytic cells / Fuel cell industry / Fuel cells / Heat treatment / High density / Hydrogels / International economic relations / Manufacturing / Mechanical properties / Methods / Microstructural analysis / Molten salt electrolytes / Particle size / Phase transitions / Porosity / Rheological properties / Rheology / robocasting / Screen printing / Sintering / Sintering (powder metallurgy) / Solid electrolytes / Solid oxide fuel cells / solid oxide fuel cells (SOFCs) / Structural integrity / Technology application / Viscoelasticity / Viscosity / Yttria-stabilized zirconia / yttria-stabilized zirconia (8YSZ) / Yttrium oxide / Zirconia / Zirconium oxide

2024

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Exploring the Potential of Robocasting for High-Density Electrolytes in Solid Oxide Fuel Cells

by Matei, Alexandru-Cristian , Ciobota, Dan-Năstase , Ioniță, Florentina-Gabriela , Drăguț, Dumitru-Valentin , Licu, Lidia , Caramarin, Ștefania , Okos, Alexandru

2024

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Exploring the Potential of Robocasting for High-Density Electrolytes in Solid Oxide Fuel Cells

by Matei, Alexandru-Cristian , Ciobota, Dan-Năstase , Ioniță, Florentina-Gabriela , Drăguț, Dumitru-Valentin , Licu, Lidia , Caramarin, Ștefania , Okos, Alexandru

2024

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Journal Article

Exploring the Potential of Robocasting for High-Density Electrolytes in Solid Oxide Fuel Cells

Matei, Alexandru-Cristian,

Ciobota, Dan-Năstase,

Ioniță, Florentina-Gabriela,

Drăguț, Dumitru-Valentin,

Licu, Lidia,

Caramarin, Ștefania,

Okos, Alexandru

2024

Overview

This study investigates the application of robocasting technology for fabricating high-density yttria-stabilized zirconia (8YSZ) electrolytes used in solid oxide fuel cells (SOFCs). The primary goal is to overcome the limitations of traditional manufacturing techniques, such as low density and poor microstructural control. Using a combination of hydrothermal synthesis, rheological testing, and robocasting, we achieved dense 8YSZ structures (over 95% density) with minimal porosity. The fabricated electrolytes underwent sintering and debinding processes, with thermal treatment profiles optimized for structural integrity. A microstructural analysis through SEM and XRD confirmed the formation of stable crystalline phase. This research opens new avenues for the use of additive manufacturing in electrochemical applications, particularly for producing complex ceramic components with superior characteristics.

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Publisher

MDPI AG

Subject

3-D printers

/ 3D printing

/ Additive manufacturing