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Comb-Like Polymethylsiloxanes. Synthesis, Structure and Properties
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Comb-Like Polymethylsiloxanes. Synthesis, Structure and Properties
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Journal Article
Comb-Like Polymethylsiloxanes. Synthesis, Structure and Properties
2015
Overview
Comb-like polymethylsiloxanes consisting of a silsesquioxane backbone and dimethylsiloxane side chains were synthesized by means of the “grafting to” method using a linear polyfunctional matrix [SiMe(ONa)O]
n
and monofunctional oligomers (CH
3
)
3
Si[OSi(CH
3
)
2
]
n
OCOCH
3
. The effects of architecture of the synthesized methylsiloxane polymers on their physicochemical properties, rheology, and behavior at the air–water interface were studied and compared with those for the linear analogue – polydimethylsiloxane.
Publisher
Springer Netherlands,Springer Nature B.V
