Journal Article

Manipulation of metavalent bonding to stabilize metastable phase: A strategy for enhancing zT in GeSe

Zhang, Chaohua, Hong, Min, Huang, Yilun, Lyu, Tu, Zeng, Manting, Liu, Fusheng, Hu, Lipeng, Wang, Moran, Yu, Yuan

2024

Overview

Exploration of metastable phases holds profound implications for functional materials. Herein, we engineer the metastable phase to enhance the thermoelectric performance of germanium selenide (GeSe) through tailoring the chemical bonding mechanism. Initially, AgInTe2 alloying fosters a transition from stable orthorhombic to metastable rhombohedral phase in GeSe by substantially promoting p‐state electron bonding to form metavalent bonding (MVB). Besides, extra Pb is employed to prevent a transition into a stable hexagonal phase at elevated temperatures by moderately enhancing the degree of MVB. The stabilization of the metastable rhombohedral phase generates an optimized bandgap, sharpened valence band edge, and stimulative band convergence compared to stable phases. This leads to decent carrier concentration, improved carrier mobility, and enhanced density‐of‐state effective mass, culminating in a superior power factor. Moreover, lattice thermal conductivity is suppressed by pronounced lattice anharmonicity, low sound velocity, and strong phonon scattering induced by multiple defects. Consequently, a maximum zT of 1.0 at 773 K is achieved in (Ge0.98Pb0.02Se)0.875(AgInTe2)0.125, resulting in a maximum energy conversion efficiency of 4.90% under the temperature difference of 500 K. This work underscores the significance of regulating MVB to stabilize metastable phases in chalcogenides. The metastable rhombohedral GeSe is generated by alloying GeSe with AgInTe2 via tailoring the chemical bonding mechanism from covalent bonding to metavalent bonding. The addition of Pb is introduced to further amplify the degree of metavalent bonding, thereby preventing the transition from metastable rhombohedral to hexagonal phase at elevated temperatures. The production and stabilization of metastable rhombohedral phase optimize the transport of carriers and phonons, resulting in an enhanced thermoelectric performance of GeSe and a maximum energy conversion efficiency of 4.90% under the temperature difference of 500 K.

• Publisher: John Wiley & Sons, Inc,Wiley
• Subject: Acoustic velocity / Anharmonicity / band structure / Carrier density / Carrier mobility / Chemical bonds / Energy conversion / Energy conversion efficiency / Functional materials / Germanium / GeSe / Heat conductivity / Hexagonal phase / High temperature / Hybridization / metastable phase / Metastable phases / metavalent bonding / Microscopy / Phase transitions / Power factor / Thermal conductivity / Thermal cycling / thermoelectric / Valence band