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Synthesis and optical properties of bis- and tris-alkynyl-2-trifluoromethylquinolines
by
Jopp, Stefan
, Villinger, Alexander
, Langer, Peter
, Spruner von Mertz, Franziska
, Ehlers, Peter
in
alkynes
/ catalysis
/ Chemistry
/ fluorescence
/ Full Research Paper
/ heterocycles
/ palladium
2024
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Synthesis and optical properties of bis- and tris-alkynyl-2-trifluoromethylquinolines
by
Jopp, Stefan
, Villinger, Alexander
, Langer, Peter
, Spruner von Mertz, Franziska
, Ehlers, Peter
in
alkynes
/ catalysis
/ Chemistry
/ fluorescence
/ Full Research Paper
/ heterocycles
/ palladium
2024
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Synthesis and optical properties of bis- and tris-alkynyl-2-trifluoromethylquinolines
Journal Article
Synthesis and optical properties of bis- and tris-alkynyl-2-trifluoromethylquinolines
2024
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Overview
Three bis- or tris-brominated 2-trifluoromethylquinolines have been successfully applied in palladium-catalysed Sonogashira reactions, leading to several examples of alkynylated quinolines in good to excellent yields. Optical properties of selected products have been studied by steady state absorption and fluorescence spectroscopy which give insights of the influence of the substitution pattern and of the type of substituents on the optical properties.
Publisher
Beilstein-Institut
Subject
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