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Asymmetric construction of all-carbon quaternary stereocenters in the total synthesis of natural products
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Asymmetric construction of all-carbon quaternary stereocenters in the total synthesis of natural products
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Journal Article
Asymmetric construction of all-carbon quaternary stereocenters in the total synthesis of natural products
2016
Overview
Structure units containing all-carbon quaternary stereogenic center are found in many bioactive natural products. However, enantioselective construction of this type of structure units has been a formidable challenge for synthetic community due to the steric hindrance enforced by all-carbon quatemary stereocenters. In this review, we present the achievements made by Chinese scientists in the area of asymmetric synthesis of all-carbon quaternary stereocenters in natural products during the past two years.
