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Ethyl 4,4''-Difluoro-5'-hydroxy-1,1':3',1''-terphenyl-4'-carboxylate
by
Samshuddin, Seranthimata
, Narayana, Badiadka
, Sarojini, Balladka Kunhanna
in
4,4'-difluoro chalcone
/ aromatization
/ chloramine-T
/ cyclohexenone derivative
/ terphenyl derivative
2011
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Ethyl 4,4''-Difluoro-5'-hydroxy-1,1':3',1''-terphenyl-4'-carboxylate
by
Samshuddin, Seranthimata
, Narayana, Badiadka
, Sarojini, Balladka Kunhanna
in
4,4'-difluoro chalcone
/ aromatization
/ chloramine-T
/ cyclohexenone derivative
/ terphenyl derivative
2011
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Ethyl 4,4''-Difluoro-5'-hydroxy-1,1':3',1''-terphenyl-4'-carboxylate
Journal Article
Ethyl 4,4''-Difluoro-5'-hydroxy-1,1':3',1''-terphenyl-4'-carboxylate
2011
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Overview
A simple and novel route for the synthesis of new terphenyl derivative as well as oxidative aromatization of α,β-unsaturated cyclohexenone to the corresponding phenol derivative is developed. The present work involves the condensation of ethylacetoacetate with 4,4'-difluoro chalcone followed by the aromatization using chloramine-T in acetic acid to yield the title compound (3). The synthesized compound (3) is well characterized by IR, NMR, LCMS and elemental analysis.
Publisher
MDPI AG
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