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From Heteroditopic to Multitopic Receptors for Ion‐Pair Recognition: Advances in Receptor Design and Applications
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From Heteroditopic to Multitopic Receptors for Ion‐Pair Recognition: Advances in Receptor Design and Applications
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Journal Article
From Heteroditopic to Multitopic Receptors for Ion‐Pair Recognition: Advances in Receptor Design and Applications
2020
Overview
Ion‐pair recognition has emerged from cation and anion recognition and become a diverse and active field in its own right. The last decade has seen significant advances in receptor design in terms of the types of binding motifs, understanding of cooperativity and increase in complexity from heteroditopic to multitopic receptors. As a result, attention has turned to applying this knowledge to the rational design of ion‐pair receptors for applications in salt solubilisation and extraction, membrane transport and sensing. This Review highlights recent progress and developments in the design and applications of heteroditopic and multitopic receptors for ion‐pair recognition. From Design to Application: In the last decade ion‐pair recognition has evolved from an emerging to an established field. This Review discusses recent developments in the design and applications of heteroditopic and multitopic ion‐pair receptors. Unusual recognition motifs and topologies are highlighted as well as the applications of ion‐pair receptors as salt solubilisation and extraction agents, in membrane transport, sensing and as switchable receptors.
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