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Stress Reduction of a V-Based BCC Metal Hydride Bed Using Silicone Oil as a Glidant
by
Wang, Yao
, Chu, Desheng
, Kong, Hanyang
, Hu, Faping
, Wu, Chaoling
, Zheng, Xin
, Yan, Yigang
in
Alloys
/ BCC metals
/ Chemical properties
/ Contact angle
/ Containers
/ Energy
/ Fluidity
/ Hydrogen
/ Hydrogen storage
/ Locking
/ metal hydride
/ Metal hydrides
/ Oil
/ Particle size
/ Retention
/ silicone oil
/ Silicones
/ Sorption
/ Storage capacity
/ Stress concentration
/ Stress measurement
/ Transition metal compounds
/ Vanadium
/ Viscosity
/ volume expansion
2022
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Stress Reduction of a V-Based BCC Metal Hydride Bed Using Silicone Oil as a Glidant
by
Wang, Yao
, Chu, Desheng
, Kong, Hanyang
, Hu, Faping
, Wu, Chaoling
, Zheng, Xin
, Yan, Yigang
in
Alloys
/ BCC metals
/ Chemical properties
/ Contact angle
/ Containers
/ Energy
/ Fluidity
/ Hydrogen
/ Hydrogen storage
/ Locking
/ metal hydride
/ Metal hydrides
/ Oil
/ Particle size
/ Retention
/ silicone oil
/ Silicones
/ Sorption
/ Storage capacity
/ Stress concentration
/ Stress measurement
/ Transition metal compounds
/ Vanadium
/ Viscosity
/ volume expansion
2022
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Stress Reduction of a V-Based BCC Metal Hydride Bed Using Silicone Oil as a Glidant
by
Wang, Yao
, Chu, Desheng
, Kong, Hanyang
, Hu, Faping
, Wu, Chaoling
, Zheng, Xin
, Yan, Yigang
in
Alloys
/ BCC metals
/ Chemical properties
/ Contact angle
/ Containers
/ Energy
/ Fluidity
/ Hydrogen
/ Hydrogen storage
/ Locking
/ metal hydride
/ Metal hydrides
/ Oil
/ Particle size
/ Retention
/ silicone oil
/ Silicones
/ Sorption
/ Storage capacity
/ Stress concentration
/ Stress measurement
/ Transition metal compounds
/ Vanadium
/ Viscosity
/ volume expansion
2022
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Stress Reduction of a V-Based BCC Metal Hydride Bed Using Silicone Oil as a Glidant
Journal Article
Stress Reduction of a V-Based BCC Metal Hydride Bed Using Silicone Oil as a Glidant
2022
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Overview
The large volume expansion and self-locking phenomenon of metal hydride particles during hydrogen sorption often leads to a high stress concentration on the walls of a container, which may cause the collapse of the container. In present study, silicone oil was investigated as a glidant for a V-based BCC metal hydride bed to alleviate the stress concentration during hydrogen sorption. The results indicated that the addition of 5 wt% silicone oil slightly reduced the initial hydrogen storage capacity of V40Ti26Cr26Fe8 (particle size: ~325 μm) but improved the absorption reversibility, regardless of the oil viscosity. It was observed that silicone oil formed a thin oil layer of 320~460 nm in thickness on the surface of the V40Ti26Cr26Fe8 particles, which might improve the fluidity of the powder, reduce the self-locking phenomenon and alleviate the stress concentration on the container walls. Consequently, the maximum strain on the surface of the hydrogen storage container decreased by ≥22.5% after adding 5 wt% silicone oil with a viscosity of 1000 cSt.
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