Asset Details
Do you wish to reserve the book?
Chiral Polymer-Mediated Pd@MOF-808 for Efficient Sequential Asymmetric Reaction
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Chiral Polymer-Mediated Pd@MOF-808 for Efficient Sequential Asymmetric Reaction
Do you wish to request the book?
Chiral Polymer-Mediated Pd@MOF-808 for Efficient Sequential Asymmetric Reaction
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Chiral Polymer-Mediated Pd@MOF-808 for Efficient Sequential Asymmetric Reaction
2023
Overview
The design and construction of organocatalysts that combined the homogeneous and heterogeneous natures to realize efficient catalysis are highly desired and challenging. Functionalized-polymers, a kind of flexible materials, provide a platform to modulate the states of immobilized catalysts in rigid supports. Herein, a chiral polymer (CP) mediated catalyst containing Pd NPs have been reported (CP@Pd@MOF-808). Chiral active sites were anchored on the polymer, and the chiral polymer threaded within the host pores of MOFs to promise the homogeneousness of chiral sites in a heterogeneous support MOF-808. This strategy kept the flexibility and freedom of chiral sites after immobilization, thus exhibited comparable performances with the corresponding homogeneous catalyst. The well-designed CP@Pd@MOF-808 was applied to sequential asymmetric reactions with excellent reactivity and stereoselectivity (up to 89% yields and 95% ee values), which were even better than that of homogeneous catalyst.A rationally designed Chiral Polymer-Mediated MOF catalyst containing metal NPs was developed for sequential reaction with high efficiency.
Publisher
Springer Nature B.V
Subject
