Asset Details
Do you wish to reserve the book?
Modelling and thermodynamic properties of pure CO2 and flue gas sorption data on South African coals using Langmuir, Freundlich, Temkin, and extended Langmuir isotherm models
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Modelling and thermodynamic properties of pure CO2 and flue gas sorption data on South African coals using Langmuir, Freundlich, Temkin, and extended Langmuir isotherm models
Do you wish to request the book?
Modelling and thermodynamic properties of pure CO2 and flue gas sorption data on South African coals using Langmuir, Freundlich, Temkin, and extended Langmuir isotherm models
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Modelling and thermodynamic properties of pure CO2 and flue gas sorption data on South African coals using Langmuir, Freundlich, Temkin, and extended Langmuir isotherm models
2022
Overview
Carbon sequestration in unmineable coal seams has been proposed as one of the most attractive technologies to mitigate carbon dioxide (CO
2
) emissions in which CO
2
is stored in the microporous structure of the coal matrix in an adsorbed state. The CO
2
adsorption process is hence considered one of the more effective methodologies in environmental sciences. Thus, adsorption isotherm measurements and modelling are key important scientific measures required in understanding the adsorption system, mechanism, and process optimization in coalbeds. In this paper, three renowned and reliable adsorption isotherm models were employed including Langmuir, Freundlich, and Temkin for pure CO
2
adsorption data, and the extended-Langmuir model for multicomponent, such as flue gas mixture-adsorption data as investigated in this research work. Also, significant thermodynamics properties including the standard enthalpy change (
Δ
H
∘
), entropy change (
Δ
S
∘
), and Gibbs free energy (
Δ
G
∘
) were assessed using the van’t Hoff equation. The statistical evaluation of the goodness-of-fit was done using three (3) statistical data analysis methods including correlation coefficient (
R
2
), standard deviation (
σ
), and standard error (SE). The Langmuir isotherm model accurately represent the pure CO
2
adsorption on the coals than Freundlich and Temkin. The extended Langmuir gives best experimental data fit for the flue gas. The thermodynamic evaluations revealed that CO
2
adsorption on the South African coals is feasible, spontaneous, and exothermic; and the adsorption mechanism is a combined physical and chemical interaction between the adsorbate and the adsorbent.
Publisher
Springer Nature Singapore,Springer Nature B.V,SpringerOpen
