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Iodine Rearrangements of Tetraallylsilane and Synthesis of Silicon-Stereogenic Organosilanes
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Journal Article
Iodine Rearrangements of Tetraallylsilane and Synthesis of Silicon-Stereogenic Organosilanes
2024
Overview
Tetraallylsilane can undergo either a mono or double rearrangement when treated with iodine (I2). The extent of rearrangement depends on the equivalents of I2 used, where 1 equivalent gives high yields of mono-rearranged products and excess (e.g., 3 equivalents) causes double rearrangement to occur. This transformation can be applied to the synthesis of potentially valuable silicon-stereogenic organosilanes.
Publisher
MDPI AG,MDPI
Subject
