Journal Article

Regulation Mechanism of Different Metal Cations on the Structure and Gel Properties of Montmorillonite

Zhang, Tiantian, Geng, Junming, Zhang, Zepeng, Liu, Dinghua, Wang, Sixiao, Yan, Haowei

2025

Overview

Metal cations are often used to regulate montmorillonite, but the mechanism is still unclear. In this paper, the regulation of different cations in montmorillonite was studied, and it was found that the regulation of different cations had significant effects on the structure of montmorillonite. Firstly, the viscosity is negatively correlated with particle size, and the order of particle size is trivalent > divalent > monovalent cation. Secondly, the swelling capacity is positively correlated with the absolute value of zeta potential, and the order of the zeta potential is monovalent > trivalent > divalent cation. Thirdly, the smaller hydrated ion radius and static electricity of monovalent cations significantly reduce the layer spacing. Meanwhile, isomorphism displacement results in a significant increase in the proportion of cis-vacant configuration due to changing the electronegativity of the octahedron. The comprehensive performance is that the particle size is significantly reduced and the absolute value of zeta potential is significantly increased. It is easy to peel off and expand in water to form a uniform and stable colloidal substance, which has the best gel performance. The research results can provide theoretical support for the regulation of montmorillonite structure and gel properties by different valence metal cations.

• Publisher: MDPI AG,MDPI
• Subject: Clay / Crystal structure / Divalent cations / Electronegativity / Fourier transforms / Isomorphism / Laws, regulations and rules / Montmorillonite / NMR / Nuclear magnetic resonance / Particle size / Scanning electron microscopy / Spectrum analysis / Static electricity / Viscosity / Zeta potential