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On determining absolute entropy without quantum theory or the third law of thermodynamics
by
Steane, Andrew M
in
Absolute zero
/ entropy
/ Gibbs-Duhem equation
/ Ideal gas
/ Ionization
/ Quantum mechanics
/ Quantum theory
/ Sackur-Tetrode equation
/ Saha equation
/ Statistical methods
/ Thermodynamics
/ third law of thermodynamics
2016
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On determining absolute entropy without quantum theory or the third law of thermodynamics
by
Steane, Andrew M
in
Absolute zero
/ entropy
/ Gibbs-Duhem equation
/ Ideal gas
/ Ionization
/ Quantum mechanics
/ Quantum theory
/ Sackur-Tetrode equation
/ Saha equation
/ Statistical methods
/ Thermodynamics
/ third law of thermodynamics
2016
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![On determining absolute entropy without quantum theory or the third law of thermodynamics](https://www.mbrl.ae/o/mbrl-theme/images/site-assets/generic/no-book-image.png)
On determining absolute entropy without quantum theory or the third law of thermodynamics
by
Steane, Andrew M
in
Absolute zero
/ entropy
/ Gibbs-Duhem equation
/ Ideal gas
/ Ionization
/ Quantum mechanics
/ Quantum theory
/ Sackur-Tetrode equation
/ Saha equation
/ Statistical methods
/ Thermodynamics
/ third law of thermodynamics
2016
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On determining absolute entropy without quantum theory or the third law of thermodynamics
![On determining absolute entropy without quantum theory or the third law of thermodynamics](https://syndetics.com/index.aspx?isbn=/mc.gif&issn=1367-2630&client=MBRL&type=mbrl)
Journal Article
On determining absolute entropy without quantum theory or the third law of thermodynamics
2016
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Overview
We employ classical thermodynamics to gain information about absolute entropy, without recourse to statistical methods, quantum mechanics or the third law of thermodynamics. The Gibbs-Duhem equation yields various simple methods to determine the absolute entropy of a fluid. We also study the entropy of an ideal gas and the ionization of a plasma in thermal equilibrium. A single measurement of the degree of ionization can be used to determine an unknown constant in the entropy equation, and thus determine the absolute entropy of a gas. It follows from all these examples that the value of entropy at absolute zero temperature does not need to be assigned by postulate, but can be deduced empirically.
Publisher
IOP Publishing
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