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Electrochemical borylation of carboxylic acids
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Journal Article
Electrochemical borylation of carboxylic acids
2021
Overview
A simple electrochemically mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented. This protocol features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors. The use of this method in challenging contexts is exemplified with a modular formal synthesis of jawsamycin, a natural product harboring five cyclopropane rings.
Publisher
National Academy of Sciences
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