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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
by
Huang, Ke
, Wang, Qiang
, Jiang, Xue
, Zhang, Jiahui
, Xiong, Xiaoli
, Wang, Zhipeng
in
Ambient temperature
/ carbon
/ Carbonates
/ Catalytic activity
/ Characterization and Evaluation of Materials
/ Chemistry and Materials Science
/ Classical Mechanics
/ Cloth
/ Crystallography and Scattering Methods
/ Dielectric barrier discharge
/ Emission spectra
/ Energy Materials
/ Hydroxides
/ Hydroxyl radicals
/ Intermetallic compounds
/ Iron compounds
/ Materials Science
/ Microplasmas
/ Nanosheets
/ Nickel compounds
/ nitrogen
/ Oxidation
/ oxygen
/ Polymer Sciences
/ Solid Mechanics
/ Synthesis
2021
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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
by
Huang, Ke
, Wang, Qiang
, Jiang, Xue
, Zhang, Jiahui
, Xiong, Xiaoli
, Wang, Zhipeng
in
Ambient temperature
/ carbon
/ Carbonates
/ Catalytic activity
/ Characterization and Evaluation of Materials
/ Chemistry and Materials Science
/ Classical Mechanics
/ Cloth
/ Crystallography and Scattering Methods
/ Dielectric barrier discharge
/ Emission spectra
/ Energy Materials
/ Hydroxides
/ Hydroxyl radicals
/ Intermetallic compounds
/ Iron compounds
/ Materials Science
/ Microplasmas
/ Nanosheets
/ Nickel compounds
/ nitrogen
/ Oxidation
/ oxygen
/ Polymer Sciences
/ Solid Mechanics
/ Synthesis
2021
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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
by
Huang, Ke
, Wang, Qiang
, Jiang, Xue
, Zhang, Jiahui
, Xiong, Xiaoli
, Wang, Zhipeng
in
Ambient temperature
/ carbon
/ Carbonates
/ Catalytic activity
/ Characterization and Evaluation of Materials
/ Chemistry and Materials Science
/ Classical Mechanics
/ Cloth
/ Crystallography and Scattering Methods
/ Dielectric barrier discharge
/ Emission spectra
/ Energy Materials
/ Hydroxides
/ Hydroxyl radicals
/ Intermetallic compounds
/ Iron compounds
/ Materials Science
/ Microplasmas
/ Nanosheets
/ Nickel compounds
/ nitrogen
/ Oxidation
/ oxygen
/ Polymer Sciences
/ Solid Mechanics
/ Synthesis
2021
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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
Journal Article
Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
2021
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Overview
A fast and facile approach was designed to fabricate carbonate (Ci)-modified NiFe layered double hydroxide (LDH) nanosheets array on carbon cloth (CC) by dielectric barrier discharge (DBD) microplasma. The whole synthetic process can be completed within 1 h at ambient temperature and pressure. The prepared NiFe LDH-Ci/CC emerges a superior catalytic activity for oxygen evolving reaction in alkaline media, which only demands an overpotential of 240 mV at 20 mA cm
−2
with a high stability for at least 90 h, and shows an excellent turnover frequency value of 0.323 mol O
2
s
−1
at 350 mV. Time-resolved measurements of direct emission spectra for nitrogen second positive system N
2
(C-B) were measured in the DBD microplasma discharge. And a high vibrational temperature (
T
vib
, 3100 K) and rotational temperature (
T
rot
, 340 K) were obtained, indicating a great chemical reactivity. In addition, the intermediate products of hydroxyl radicals (
·
OH) were identified and the possible synthesis mechanism was tentatively proposed.
Graphical abstract
A fast and facile approach was designed to fabricate NiFe LDH-Ci/CC by DBD microplasma.
Publisher
Springer US,Springer,Springer Nature B.V
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