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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation

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Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation
Journal Article

Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation

2021
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Overview
A fast and facile approach was designed to fabricate carbonate (Ci)-modified NiFe layered double hydroxide (LDH) nanosheets array on carbon cloth (CC) by dielectric barrier discharge (DBD) microplasma. The whole synthetic process can be completed within 1 h at ambient temperature and pressure. The prepared NiFe LDH-Ci/CC emerges a superior catalytic activity for oxygen evolving reaction in alkaline media, which only demands an overpotential of 240 mV at 20 mA cm −2 with a high stability for at least 90 h, and shows an excellent turnover frequency value of 0.323 mol O 2  s −1 at 350 mV. Time-resolved measurements of direct emission spectra for nitrogen second positive system N 2 (C-B) were measured in the DBD microplasma discharge. And a high vibrational temperature ( T vib , 3100 K) and rotational temperature ( T rot , 340 K) were obtained, indicating a great chemical reactivity. In addition, the intermediate products of hydroxyl radicals ( · OH) were identified and the possible synthesis mechanism was tentatively proposed. Graphical abstract A fast and facile approach was designed to fabricate NiFe LDH-Ci/CC by DBD microplasma.