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Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions
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Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions
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Journal Article
Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions
2015
Overview
The Pd–benzothiazol-2-ylidene complex I was found to be a chemoselective catalyst for the Tsuji–Trost allylation of active methylene compounds carried out under neutral conditions and using carbonates as allylating agents. The proposed protocol consists in a simplified procedure adopting an in situ prepared catalyst from Pd 2 dba 3 and 3-methylbenzothiazolium salt V as precursors. A comparison of the performance of benzothiazole carbene with phosphanes and an analogous imidazolium carbene ligand is also proposed.
Publisher
Beilstein-Institut
