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Hybrids of Fullerenes and 2D Nanomaterials
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Journal Article
Hybrids of Fullerenes and 2D Nanomaterials
2019
Overview
Fullerene has a definite 0D closed‐cage molecular structure composed of merely sp2‐hybridized carbon atoms, enabling it to serve as an important building block that is useful for constructing supramolecular assemblies and micro/nanofunctional materials. Conversely, graphene has a 2D layered structure, possessing an exceptionally large specific surface area and high carrier mobility. Likewise, other emerging graphene‐analogous 2D nanomaterials, such as graphitic carbon nitride (g‐C3N4), transition‐metal dichalcogenides (TMDs), hexagonal boron nitride (h‐BN), and black phosphorus (BP), show unique electronic, physical, and chemical properties, which, however, exist only in the form of a monolayer and are typically anisotropic, limiting their applications. Upon hybridization with fullerenes, noncovalently or covalently, the physical/chemical properties of 2D nanomaterials can be tailored and, in most cases, improved, significantly extending their functionalities and applications. Here, an exhaustive review of all types of hybrids of fullerenes and 2D nanomaterials, such as graphene, g‐C3N4, TMDs, h‐BN, and BP, including their preparations, structures, properties, and applications, is presented. Finally, the prospects of fullerene‐2D nanomaterial hybrids, especially the opportunity of creating unknown functional materials by means of hybridization, are envisioned.
An exhaustive review of the hybrids of fullerenes with 2D materials including graphene, graphitic carbon nitride, transition‐metal dichalcogenides, hexagonal boron nitride, and black phosphorus is presented, focused on their preparations, structures, properties, and applications. Upon hybridization with fullerenes noncovalently or covalently, physical/chemical properties of 2D materials can be tailored and in most cases improved, significantly extending their functionalities and applications.
Publisher
John Wiley & Sons, Inc,John Wiley and Sons Inc
